Nanostructure photodetectors, as the core component of optoelectronic devices, are mainly focused on the precise preparation of mixed-component nano-heterostructures and the realization of zero power consumption devices. Herein, we successfully fabricated n-GaN/p-ZnTe core/shell nanopillar array and realized self-power ultraviolet/violet photodetection. The radial heterojunction nanodevice reveals high light-dark current ratio of 10⁴ at 0 V bias, indicating effective carriers’ separation. And more, by integrating plasmonic effect, the responsivity and detectivity of the Au nanoparticles decorated device are increased from 3.85 to 148.83 mA/W and 4.45×10¹¹ to 2.33 × 10¹² Jones under 325 nm UV light irradiation. While the rise and the fall time are decreased 1.3 times and 6.8 times under 520 nm visible light irradiation at 0 V bias. The high photocurrent gain is derived from that the oscillating high-energy hot electrons in Au nanoparticles spontaneously inject into the ZnTe conduction band to involve the photodetection process. This work presents an effective route to prepare high-performance self-power photodetector and provides a promising blueprint to realize different functional photoelectronic devices based on core/shell nanostructure.

van der Waals heterostructures (vdWHs) based on two-dimensional (2D) materials without the crystal lattice matching constraint have great potential for high-performance optoelectronic devices. Herein, a WS₂/InSe vdWH photodiode is proposed and fabricated by precisely stacking InSe and WS₂ flakes through an all-dry transfer method. The WS₂/InSe vdWH forms an n–n heterojunction with strong built-in electric field due to their intrinsic n-type semiconductor characteristics and energy-band alignments with a large Fermi level offset between WS₂ and InSe. As a result, the device displays excellent photovoltaic behavior with a large open voltage of 0.47 V and a short-circuit current of 11.7 nA under 520 nm light illumination. Significantly, a fast rising/decay time of 63/76 μs, a large light on/off ratio of 10⁵, a responsivity of 61 mA/W, a high detectivity of 2.5 × 10¹¹ Jones, and a broadband photoresponse ranging from ultraviolet to near-infrared (325–980 nm) are achieved at zero bias. This study provides a strategy for developing high-performance self-powered broadband photodetectors based on 2D materials.