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Inhibiting creep in fine-grained Mg–Al alloys through grain boundary stabilization
Journal of Magnesium and Alloys 2025, 13(5): 2072-2083
Published: 28 May 2024
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The limited creep resistance of wrought Mg–Al alloys restricts their lightweight applications at intermediate temperatures due to the softening effect of discontinuous precipitation (DP) on the dislocation-controlled creep. Here, we developed a creep-resistant wrought Mg–Al alloy through microalloying of Y and Ca. The resulting alloy exhibited an order of magnitude enhancement in the creep resistance at 125 ℃/50–100 MPa. In contrast to the grain boundary instabilities by DP in the previously reported wrought Mg–Al alloys, we show that the addition of 0.21Y+0.15Ca wt% produces a (Zn+Ca) co-segregation at the grain boundaries as a result of their segregation energy and the activation energy of grain boundary migration, thereby stabilizing the grain boundaries. The (Zn+Ca) co-segregation inhibits the dynamic DP and promotes the formation of intragranular Al-enriched clusters, which favorthe formation of Al2Y, Mg17Al12 nano precipitates, thereby impeding intragranular dislocation motion during creep. Furthermore, the addition of 0.21Y+0.15Ca wt% facilitates the formation of a fine and uniform recrystallization structure in the microalloyed alloys compared to AZ80 due to the high activation energy of mobility for the (Zn+Ca) segregated grain boundary. Therefore, the microalloyed alloys exhibit good tensile properties with 380 MPa tensile strength and 18% elongation. Our constitutive analysis revealed that the (Y+Ca) microalloying decreased the creep stress exponent by 29% and increased the creep resistance in the medium to high-stress range. Microalloying provides a promising way to develop low-cost creep-resistant wrought Mg–Al alloys.

Research Article Issue
Achieving room-temperature M2-phase VO2 nanowires for superior thermal actuation
Nano Research 2021, 14(11): 4146-4153
Published: 24 March 2021
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Vanadium dioxide (VO2) has emerged as a promising micro-actuator material for its large amplitude and high work density across the transition between the insulating (M1 and M2) and metallic (R) phase. Even though M2–R transition offers about 70% higher transformation stress than M1–R structural phase transition, the application of the M2 phase in the micro-actuators is hindered by the fact that previously, M2 phase can only stay stable under tensile stress. In this work, we propose and verify that by synthesizing the VO2 nanowires under optimized oxygen-rich conditions, stoichiometry change can be introduced into the nanowires (NWs) which in turn yield a large number free-standing single-crystalline M2-phase NWs stable at room temperature. In addition, we demonstrate that the output stress of the M2-phase NWs is about 65% higher than that of the M1-phase NWs during their transition to R phase, quite close to the theoretical prediction. Our findings open new avenues towards enhancing the performance of VO2-based actuators by using M2–R transition.

Research Article Issue
Ultrafast shape change and joining of small-volume materials using nanoscale electrical discharge
Nano Research 2015, 8(7): 2143-2151
Published: 17 July 2015
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Using nanoscale electrical-discharge-induced rapid Joule heating, we developed a method for ultrafast shape change and joining of small-volume materials. Shape change is dominated by surface-tension-driven convection in the transient liquid melt, giving an extremely high strain rate of ~106 s–1. In addition, the heat can be dissipated in small volumes within a few microseconds through thermal conduction, quenching the melt back to the solid state with cooling rates up to 108 K·s-1. We demonstrate that this approach can be utilized for the ultrafast welding of small-volume crystalline Mo (a refractory metal) and amorphous Cu49Zr51 without introducing obvious microstructural changes, distinguishing the process from bulk welding.

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