Stable and efficient single atom catalysts (SACs) are highly desirable yet challenging in catalyzing acidic oxygen evolution reaction (OER). Herein, we report a novel iridium single atom catalyst structure, with atomic Ir doped in tetragonal PdO matrix (Ir_SAs-PdO) via a lattice-confined strategy. The optimized Ir_SAs-PdO-0.10 exhibited remarkable OER activity with an overpotential of 277 mV at 10 mA·cm⁻² and long-term stability of 1000 h in 0.5 M H₂SO₄. Furthermore, the turnover frequency attains 1.6 s⁻¹ at an overpotential of 300 mV with a 24-fold increase in the intrinsic activity. The high activity originates from isolated iridium sites with low valence states and decreased Ir–O bonding covalency, and the excellent stability is a result of the effective confinement of iridium sites by Ir–O–Pd motifs. Moreover, we demonstrated for the first time that SACs have great potential in realizing ultralow loading of iridium (as low as microgram per square center meter level) in a practical water electrolyzer.

The reactant concentration at the catalytic interface holds the key to the activity of electrocatalytic hydrogen evolution reaction (HER), mainly referring to the capacity of adsorbing hydrogen and electron accessibility. With hydrogen adsorption free energy (ΔG_H) as a reactivity descriptor, the volcano curve based on Sabatier principle is established to evaluate the hydrogen evolution activity of catalysts. However, the role of electron as reactant received insufficient attention, especially for noble metal-free compound catalysts with poor conductivity, leading to cognitive gap between electronic conductivity and apparent catalytic activity. Herein we successfully construct a series of catalyst models with gradient conductivities by regulating molybdenum disulfide (MoS₂) electronic bandgap via a simple solvothermal method. We demonstrate that the conductivity of catalysts greatly affects the overall catalytic activity. We further elucidate the key role of intrinsic conductivity of catalyst towards water electrolysis, mainly concentrating on the electron transport from electrode to catalyst, the electron accumulation process at the catalyst layer, and the charge transfer progress from catalyst to reactant. Theoretical and experimental evidence demonstrates that, with the enhancement in electron accessibility at the catalytic interface, the dominant parameter governing overall HER activity gradually converts from electron accessibility to combination of electron accessibility and hydrogen adsorbing energy. Our results provide the insight from various perspective for developing noble metal-free catalysts in electrocatalysis beyond HER.

The scale-up deployment of ruthenium (Ru)-based oxygen evolution reaction (OER) electrocatalysts in proton exchange membrane water electrolysis (PEMWE) is greatly restricted by the poor stability. As the lattice-oxygen-mediated mechanism (LOM) has been identified as the major contributor to the fast performance degradation, impeding lattice oxygen diffusion to inhibit lattice oxygen participation is imperative, yet remains challenging due to the lack of efficient approaches. Herein, we strategically regulate the bonding nature of Ru–O towards suppressed LOM via Ru-based high-entropy oxide (HEO) construction. The lattice disorder in HEOs is believed to increase migration energy barrier of lattice oxygen. As a result, the screened Ti₂₃Nb₉Hf₁₃W₁₂Ru₄₃O_x exhibits 11.7 times slower lattice oxygen diffusion rate, 84% reduction in LOM ratio, and 29 times lifespan extension compared with the state-of-the-art RuO₂ catalyst. Our work opens up a feasible avenue to constructing stabilized Ru-based OER catalysts towards scalable application.

The development of cost-effective, robust, and durable electrocatalysts to replace the expensive Pt-based catalysts towards oxygen reduction reaction (ORR) is the trending frontier research topic in renewable energy and electrocatalysis. Particular attention has been paid to metal-nitrogen-carbon (M-N-C) single atom catalysts (SACs) due to their maximized atom utilization efficiency, biomimetic active site, and distinct electronic structure. More importantly, their catalytic properties can be further tailored by rationally regulating the microenvironment of active sites (i.e., M–N coordination number, heteroatom doping and substitution. Herein, we present a comprehensive summary of the recent advancement in the microenvironment regulation of M-N-C SACs towards improved ORR performance. The coordination environment manipulation regarding central metal and coordinated atoms is first discussed, focusing on the structure–function relationship. Apart from the near-range coordination, long-range substrate modulation including heteroatom doping, defect engineering is discussed as well. Besides, the synergy mechanism of nanoparticles and single atom sites to tune the electron cloud density at the active sites is summarized. Finally, we provide the challenges and outlook of the development of M-N-C SACs.

Designing feasible electrocatalysts towards oxygen reduction reaction (ORR) requires advancement in both activity and stability, where attaining high stability is of extreme importance as the catalysts are expected to work efficiently under frequent start-up/shut down circumstances for at least several thousand hours. Alloying platinum with early transition metals (i.e., Pt–La alloy) is revealed as efficient catalysts construction strategy to potentially satisfy these demands. Here we report a Pt₅La intermetallic compound synthesized by a novel and facile strategy. Due to the strong electronic interactions between Pt and La, the resultant Pt₅La alloy catalyst exhibits enhanced activity with half wave of 0.92 V and mass activity of 0.49 A·mg_Pt⁻¹, which strictly follows the 4e transfer pathway. More importantly, the catalyst performs superior stability during 30,000 cycles of accelerated stressed test (AST) with mass activity retention of 93.9%. This study provides new opportunities for future applications of Pt-rare earth metal alloy with excellent electrocatalytic properties.

Single atom catalysts (SACs) were reported to demonstrate exciting catalytic features for a number of reactions, including hydrogen evolution reaction (HER). However, the true role of these single atom sites in catalysts remains elusive, particularly for those prepared via pyrolysis, where the formation of active nanoparticle counterparts is often unavoidable. Here we report a Ru based catalyst (Ru embedded in N doped carbon spheres (Ru/NPCS)) comprising of both Ru nanoclusters and Ru single sites, who demonstrates activity exceeding Pt catalyst and mass activity among the best of the Ru based catalysts under acidic conditions. The integration of proton exchange membrane water electrolysis with Ru/NPCS as a cathode exhibited an excellent hydrogen generation activity and extraordinary stability (during 120 h of electrolysis) with a 1/48 Ru loading (16.5 µg_Ru·cm⁻²) of a commercial 20% Pt/C catalyst. Through precisely tailoring the dispersion status of the catalysts, we reveal that while ruthenium nanoclusters actively catalyze HER via Volmer–Tafel mechanism, the Ru SACs barely catalyze HER, with H* adsorption difficult to occur. Moreover, no synergy between Ru SACs and Ru cluster is revealed, meaning the Ru SACs act as a spectator rather than active species during H₂ evolution.

The high price of state-of-the-art Pt electrocatalysts has plagued the acidic water electrolysis technique for decades. As a cheaper alternative to Pt, ruthenium is considered an inferior hydrogen evolution reaction (HER) catalyst than Pt due to its high susceptibility to oxidation and loss of activity. Herein, we reveal that the HER activity on Ru based catalysts could surpass Pt via tuning Ru oxidation state. Specifically, RuP clusters encapsulated in few layers of N, P-doped carbon (RuP@NPC) display a minimum over potential of 15.6 mV to deliver 10 mA·cm⁻². Moreover, we for the first time show that a Ru based catalyst could afford current density up to 4 A·cm⁻² in a practical water electrolysis cell, with voltage even lower than the Pt/C-based cell, as well as high robustness during 200 h operation. Using a combination of experiment probing and calculation, we postulate that the suitably charged Ru (~ +2.4) catalytic center is the origin for its superior catalytic behavior. While the moderately charged Ru is empowered with optimized H adsorption behavior, the carbon encapsulation layers protect RuP clusters from over oxidation, thereby conferring the catalyst with high robustness.

In this study, phosphorus doped graphene supported PtNiP nanocluster electrocatalyst (PtNiP/P-graphene) was successfully prepared via a simple hypophosphite-assisted co-reduction method. The improved anchoring force and increased anchoring sites of graphene support result from phosphorus doping as well as size-confined growth effect of NaH₂PO₂ leads to uniform dispersion of ultrafine PtNiP nanoclusters. Doped P also promotes the removal of CO-like intermediate by adjusting Pt electronic structure combining with alloyed Ni via electronic effects. As a result, the as-prepared PtNiP/P-graphene catalyst with more exposed active sites and optimized electronic structure of Pt alloy shows excellent electrocatalytic performances for methanol oxidation reaction (MOR) both in activity and durability in an acidic medium.

Fe/N/C material is the most competitive alternative to precious-metal catalysts for oxygen reduction. In view of the present consensus on active centers, further effort is directed at maximizing the density of single Fe atoms. Here, the imperfections in commonly used doping strategy of Fe for the synthesis of zeolitic imidazolateframework (ZIF)-derived Fe/N/C catalysts are revealed. More importantly, a strikingly improved catalyst is obtained by a 'second pyrolysis’ method and delivers a half-wave potential of 0.825 V (vs. RHE) in acidic media. The strong confinement effect of carbonaceous host accounts for the formation of dense single-atom sites and thus the high activity. Our findings will potentially facilitate future improvement of M/N/C catalysts.