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Open Access Research Article Issue
Fabrication and microstructure evolution of Csf/ZrB2-SiC composites via direct ink writing and reactive melt infiltration
Journal of Advanced Ceramics 2021, 10 (6): 1371-1380
Published: 30 September 2021
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Fiber damage and uniform interphase preparation are the main challenges in conventional short fiber reinforced ceramic matrix composites. In this work, we develop a novel processing route in fabrication of short carbon fiber reinforced ZrB2-SiC composites (Csf/ZrB2-SiC) overcoming the above two issues. At first, Csf preforms with oriented designation and uniform PyC/SiC interphase are fabricated via direct ink writing (DIW) of short carbon fiber paste followed by chemical vapor infiltration. After that, ZrB2 and SiC are introduced into the preforms by slurry impregnation and reactive melt infiltration, respectively. Microstructure evolution and optimization of the composites during fabrication are investigated in detail. The as-fabricated Csf/ZrB2-SiC composites have a bulk density of 2.47 g/cm3, with uniform weak interphase and without serious fiber damage. Consequently, non-brittle fracture occurs in the Csf/ZrB2-SiC composites with widespread toughening mechanisms such as crack deflection and bridging, interphase debonding, and fiber pull-out. This work provides a new opportunity to the material design and selection of short fiber reinforced composites.

Open Access Research Article Issue
Microstructure and mechanical properties of 3D Cf/SiBCN composites fabricated by polymer infiltration and pyrolysis
Journal of Advanced Ceramics 2021, 10 (1): 28-38
Published: 24 November 2020
Abstract PDF (5.1 MB) Collect
Downloads:277

In this work, three-dimensional (3D) Cf/SiBCN composites were fabricated by polymer infiltration and pyrolysis (PIP) with poly(methylvinyl)borosilazane as SiBCN precursor. The 3D microstructure evolution process of the composites was investigated by an advanced X-ray computed tomography (XCT). The effect of dicumyl peroxide (DCP) initiator addition on the crosslinking process, microstructure evolution, and mechanical properties of the composites were uncovered. With the addition of a DCP initiator, the liquid precursor can cross-linking to solid-state at 120 ℃. Moreover, DCP addition decreases the release of small molecule gas during pyrolysis, leading to an improved ceramic yield 4.67 times higher than that without DCP addition. After 7 PIP cycles, density and open porosity of the final Cf/SiBCN composite with DCP addition are 1.73 g·cm-3 and ~10%, respectively, which are 143.0% higher and 30.3% lower compared with the composites without DCP addition. As a result, the flexural strength and elastic modulus of Cf/SiBCN composites with DCP addition (371 MPa and 31 GPa) are 1.74 and 1.60 times higher than that without DCP addition (213 MPa and 19.4 GPa), respectively.

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