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Review Issue
Application and Durability of Basic Magnesium Sulfate Cement-Based Material
Journal of the Chinese Ceramic Society 2026, 54(4): 1490-1498
Published: 13 March 2026
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Basic magnesium sulfate cement (BMSC) is a new type of magnesium-based cementitious material modified by the chemical additive such as citric acid or boric acid on the basis of magnesium oxychloride cement. BMSC has the abundant mineral resource for the raw material, low energy consumption of production, and high utilization rate of the solid waste. BMSC has the green and environmental advantages, such as the conservation of energy, material, land, and low-carbon emissions. The systematic research on the durability of BMSC is still needed if BMSC are applied to the special environment such as the ocean and saline soil area. The main progress of the durability of BMSC material in past ten years is summarized in this paper, which includes the water resistance, carbonization and resistance of seawater, salt brine, freeze-thaw of BMSC material.and the influencing factors, the evolution law of corrosion and mechanical properties of internal steel bars, the mechanical properties of BMSC components under the natural exposure condition for 869 days. The relative dynamic modulus of the elasticity and mass change, corrosion products, and the microstructural changes of BMSC in the harsh environment is studied. The analysis of mechanism is also conducted on the durability of BMSC. The durability performance of the BMSC material is related to the composition and microstructure of BMSC. It can be found that the stable and abundant formation of 5·1·7 phase, which is the main hydration product in BMSC, is the fundamental reason for the good durability and high mechanical properties of BMSC-based material. BMSC concrete is not prone to carbonation and the internal steel reinforcement is not easily corroded in the atmospheric environment. The main changes in the microstructure of the carbonized zone on the surface of BMSCs during the carbon dioxide curing are the transformation of some hydration product Mg (OH))2 into MgCO3. The long-term retention rate of the compressive strength of BMSC concrete is closely related to its initial strength before the immersion in the seawater. The polarization resistance Rp decreases with the prolonged exposure time in the environment of seawater immersion. BMSC concrete with the compressive strength of C40 or above, BMSC mixed with KLJ rust inhibitor or the steel bar coated with epoxy resin are recommended to be used in the environment of seawater immersion. The freeze-thaw life of BMSC concrete exceeds 40 times, far exceeding that of Portland cement concrete. Compared to PCC components, the BMSC beams and columns under the coupling effects of the acid rain and freeze-thaw have less degradation of mechanical performance, lower rate of the internal steel corrosion, and higher enhancement effect of cracking load. The effective additive, suitable activity of MgO, appropriate addition of polymers, 5·1·7 crystal seed, slag (or fly ash), and solution immersion of KH2PO4 or NH4H2PO4 can optimize the composition of hydration product of BMSC, increase the stability of the 5·1·7 phase of hydration product, effectively improve the microstructure of BMSC, and enhance the durability of BMSC-based material in the harsh environment. The prospect for the application of BMSC material is discussed. Due to the advantages of BMSC, such as resistance to carbonization, salt brine corrosion, low transmission, and reinforcement protectio, it can be found that the BMSC material can be used in the area with harsh environment such as the ocean, western saline soil, and Qinghai Tibet Plateau after KLJ rust inhibitor being added. The military engineering, pavement repair of cement concrete, crack repair in the brick and stone masonry of ancient building and prefabricated construction have good application prospects in the harsh environments such as the Qinghai Tibet Plateau and saline soil area. Finally, the problems of durability are discussed as follows: the mechanism of microstructure formation and evolution of BMSC-based material under the harsh environment, the corrosion resistance of BMSC concrete to sulfate, magnesium, and chloride salt under the wet dry and freeze-thaw cycles, mechanism of corrosion resistance of 5·1·7 phase and BMSC concrete, the dynamic evolution and mechanism of intrinsic degradation of the interfacial bonding performance between BMSC repair material and the old material under the harsh service condition, the structural damage, disasters, and life extension and toughening under the interaction response of permafrost and engineering in the high-altitude environment, the stress damage, degradation of structural performance, identification of field effects and long-term performance, and design for the expected lifespan of BMSC in the harsh environment such as the ocean and saline soil, the mechanism of transport and failure of BMSC concrete in the harsh environments, the reinforcement and long-term protection system of the surface of BMSC concrete, the model of the rapid life prediction for BMSC-based material. This paper can provides the theoretical basis for the application, durability evaluation, and engineering design of BMSC in the harsh environment.

Research Article Issue
Repair Effect of Different Strengthening Agent on Restoration of Brick Carving
Journal of the Chinese Ceramic Society 2025, 53(8): 2301-2307
Published: 29 May 2025
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Introduction

The brick-carved cultural relics is a precious cultural resource. The uniqueness of brick carving causes a high requirement for the technique and materials of in-situ repair. The difficulty is to preserve the original features of brick carving while restoring its microstructure. The inorganic reinforcing agents are beneficial for maintaining the physical properties of the historical material and have been considered the optimal choice for restoring the cohesive strength of the historical material in recent years. The restoration material prepared by basic magnesium sulfate cement (BMSC) has the advantages of high tensile strength, high resistance to weather, high viscosity, early strength, and low cost. It has a good effect in reinforcing the weathered sandstone of the cultural relics. The hydraulic lime is widely used due to its waterproof and breathable properties. But it is very expensive. The Silicon-based repair material has good permeability. But it has poor stability in the environment with the changing humidity. Three types of strengthening agents are selected as the alternative options for the restoration of brick carving based on the need for the brick repair and in-situ protection of the ancient mortar during the process of the restoration of brick carving.

Methods

Three strengthening agents are Ca-based hydraulic lime, Si-based silica sol, and Mg-based BMSC. Three steps are implemented in order to select the most effective strengthening agent in the restoration of the cultural relics of brick carving. That is the preparation and research of performances of three kinds of imitation bricks, infiltration reinforcement of the ancient material, and the verification of practical engineering. The powder of green bricks is used as the main material for replica bricks. The hydraulic lime, silica sol, and BMSC-based reinforcing agent are firstly mixed with the powder of green brick to form replica bricks, which are the Ca-bricks, Si-bricks and Mg-bricks. The multiple experiments were conducted to investigate the compatibility of replica bricks. The studied properties include the composition of crystal phase, compressive strength, porosity characteristics, and the hydraulic performance of the replica bricks, and so on. WW/T 0065—2015 “Code for Investigation of Stone Cultural Relics Protection Engineering” is referenced. Secondly, the adhesive properties and infiltration reinforcement of the strengthening agents were taken into consideration to evaluate the feasibility of application of these material to the restoration of the brick-carving cultural relics. Finally, the verification of the referred BMSC-based strengthening agent used in actual engineering was conducted because the laboratory environment is different from the complex environment where the cultural relics are located.

Results and discussion

Ca-based and Si-based reinforcing agents only serve to adhere the powder of green brick. The BMSC-based reinforcement agent continues to hydrate after being added to the powder of green brick to form the replica bricks. The main hydration product is the 5⸱1⸱7 strength phase. So the BMSC-based reinforcing agent has the strongest adhesion among three types of reinforcing agents. The Mg-brick has the best performance among three kinds of replica bricks, which is similar to the green brick. But Mg-brick has the slight hydrophobicity. The properties of Ca-bricks and Si-bricks are close to the ancient bricks. The bending strength of the masonry of bonded Mg-bricks is 10 times that of the Si-bricks. Only the BMSC-based strengthening agent has no carbonization and has good aging resistance. The infiltration solution with a content of 30% BMSC-based reinforcement agent and a moisture content of 44%–50% has the best effect of reinforcement, maintaining the original physical properties of brick-carved cultural relics while restoring the original cohesion. The referred BMSC - based reinforcing agent can penetrate and bond the slag of brick carving of 9.5 times the mass of agent.

Conclusions

The BMSC-based reinforcing agent demonstrates higher penetration enhancement ability than reinforcing agents based on hydraulic lime or silica sol. The volume stability of the referred BMSC-based strengthening agent meets the requirements. It also can be found that the repair effect of the referred BMSC-based strengthening agent is good after two years. In summary, the optimal ratio of BMSC - based reinforcing agent shows good repair effect at low cost. The Mg-brick and BMSC - based reinforcing agent can be used for the restoration of brick carving.

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