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Open Access Issue
Analysis of the seepage mechanism of brine-CO2 oil displacement and storage in heterogeneous porous media with carbonate coating
Experimental Technology and Management 2026, 43(4): 39-45
Published: 20 April 2026
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Objective

Carbonate reservoirs have become strategic targets for reserve expansion in China and the Middle East, driven by the dual goals of reducing carbon emissions and ensuring energy security. However, their significant heterogeneity, complex pore structures, and wettability changes present considerable challenges to the efficiency of CO2-based enhanced oil recovery (EOR). At the pore level, the interaction of capillary forces, viscous forces, and the evolution of multiphase interfaces causes unstable displacement fronts and severely limits sweep efficiency in low-permeability areas.

Methods

To tackle these issues, this study aims to reveal the pore-scale multiphase seepage mechanisms of brine–CO2 displacement in carbonate-coated heterogeneous porous media. This provides a microscopic foundation for optimizing CO2 flooding parameters and enhancing sweep performance in actual carbonate reservoirs. A heterogeneous pore network was constructed using a microfluidic chip, and calcium carbonate was coated in situ to simulate authentic carbonate reservoir surfaces and wettability. A series of visualization experiments were conducted at a controlled temperature (40 ℃). CO2 foam flooding and brine flooding at different injection rates were compared. A CCD imaging system was used to capture pore-scale evolution of oil, water, and gas phases, and gas saturation and residual oil distributions were quantified through image processing. To improve the accuracy of residual oil characterization, the ResNet152 deep neural network was trained on 2885 labeled microfluidic sub-images from CO2 flooding, CO2–water alternating flooding, and brine flooding. Using weighted cross-entropy loss, AdamW optimization, and learning rate scheduling, the model achieved high classification accuracy for dispersed, mixed, and heterogeneous residual oil.

Results

Results showed that flooding performance was strongly affected by injection rate and pore-structure heterogeneity. At moderate flow rates (0.5–3 μL·min–1), CO2 foam greatly improved sweep efficiency, nearly eliminating residual oil saturation. Foam viscosity and the Jamin effect effectively suppressed viscous fingering and prevented preferential flow through high-permeability channels, forcing the displacing phase into low-permeability areas. Conversely, at very low injection rates (0.1 μL·min–1), foam instability caused large dispersed gas bubbles, limiting gas saturation to 25%, and hindered oil droplet mobilization, resulting in a high residual oil saturation of 42%. Gas saturation displayed a parabolic relationship with flow rate, with the maximum (93%) at 1 μL·min–1, where bubble size was smallest, and foam stability was optimal. Deep-learning-based oil classification also showed that brine flooding and CO2–water alternating flooding primarily produced dispersed residual oil, whereas surfactant-assisted CO2 flooding created a mixture of dispersed (49%), mixed (36%), and heterogeneous (14%) oil, reflecting foam instability and uneven sweep in highly heterogeneous zones. The model achieved a validation accuracy of 93%, confirming its effectiveness in pore-scale residual oil identification.

Conclusions

This study clarifies the mechanisms underlying brine–CO2 displacement in carbonate-coated heterogeneous media. Calcium carbonate coating increases hydrophobicity, delays breakthrough in high-permeability pathways, and significantly enhances sweep in low-permeability zones, reducing residual oil by up to 28%. CO2 foam flooding is highly sensitive to injection rate, with moderate flow rates producing stable foam, high gas saturation, and efficient oil mobilization, whereas very low or high rates reduce displacement stability. By combining microfluidic visualization and deep-learning image analysis, this research offers microscopic insights for optimizing CO2 flooding conditions and provides technical guidance for deploying CO2-based EOR in Middle Eastern carbonate reservoirs. The findings also support international cooperation under the Belt and Road Initiative and contribute to global efforts in the low-carbon, efficient development of carbonate oilfields.

Issue
Study of the oil recovery trends by imbibition in low-permeability cores under high-pressure CO2
Petroleum Science Bulletin 2025, 10(2): 245-255
Published: 01 April 2025
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During the development of CO2 injection in low-permeability reservoirs, carbonated water formed after CO2 dissolves in water can effectively improve the imbibition effect, and thus improve the reservoir development benefit. By measuring the oil-water interfacial tension, contact angle and imbibition recovery factor, the effect of temperature and pressure on imbibition recovery in low-permeability cores under high-pressure CO2 was investigated. The results show that increasing temperature and CO2 pressure can improve oil-water interface characteristics and enhance imbibition recovery. At 8 MPa, the temperature increases from 20 ℃ to 80 ℃, the interfacial tension increases by 2.25 mN·m-1, and the contact angle decreases by 15.2°. The influence of temperature on oil-water interface characteristics is stronger than that of CO2 solubility. With the increase of temperature, CO2 solubility decreases, but the interfacial tension increases, the hydrophilicity of rock enhances, and the fluidity of crude oil increases, so the imbibition efficiency increases. At 80 ℃, the pressure increases from 4 MPa to 10 MPa, the interfacial tension decreases by 3 mN·m-1, and the contact angle decreases by 18.4°. Pressure mainly affects the oil-water interface characteristics by changing the CO2 solubility in the liquid phase. With the increase of pressure, the CO2 solubility increases, the interfacial tension decreases, the hydrophilicity of rock enhances, the fluidity of crude oil also increases, so the imbibition efficiency increases effectively. Heating and pressurization have a certain synergistic effect on improving imbibition efficiency. Under the combined action of the two, although the interfacial tension only slightly decreases, the hydrophilicity of the rock enhances significantly, which accelerates the escape of crude oil in the matrix pore throat and effectively improves the imbibition recovery in low-permeability cores. The research results enrich the imbibition production mechanism, and can provide theoretical reference for CO2 injection development in low-permeability reservoirs.

Open Access Original Paper Issue
Enhanced recovery in heavy oil reservoirs with interlayers using flue gas-assisted VH-SAGD: A 2D visualization study
Petroleum Science 2025, 22(8): 3418-3433
Published: 11 May 2025
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The potential of the vertical-horizontal well hybrid SAGD technique for developing shallow heavy oil reservoirs is gradually being realized. However, challenges remain in terms of low thermal efficiency and high carbon emissions in reservoirs with interlayers. Currently, there is limited research on the low-carbon strategy of coupling exhaust gas from steam boilers with the VH-SAGD technique. Herein, considering heterogeneity, a series of flue gas-assisted VH-SAGD experiments were conducted employing a high-performance 2D visualization model. The mechanism of enhanced recovery of flue gas in VH-SAGD and the effect of its injection methods were studied, with a focus on steam chamber development and oil saturation distribution. Crucially, the interlayer length was optimized to enhance oil recovery, providing a new perspective for well location design in heavy oil reservoirs with interlayers. The results showed that flue gas, as an additive, could fully exploit the well-type advantage of VH-SAGD. By supplementing energy at the reservoir top, flue gas effectively promoted steam chamber development, expanded the oil drainage area of VH-SAGD, and increased the oil recovery from 58.9% to 71.7%. The flow channels formed by pre-injection flue gas accelerated the early-stage expansion of the steam chamber while also inducing lateral migration of steam, slowing steam rise, and consequently increasing the heating range within the low-permeability layer. When the distance between the vertical and horizontal wells was set to twice the interlayer length, the negative effects of the interlayer were more effectively turned into advantages. Because when the lateral development distance of the steam chamber in the low-permeability layer slightly exceeds the interlayer, enhanced heating of the lower part of the reservoir occurred through vertical convection of rising steam and returning condensate. The research results contribute to reducing carbon emissions from steam-based heavy oil extraction while advancing the maturity of VH-SAGD.

Open Access Original Paper Issue
Flow characteristics and regime transition of aqueous foams in porous media over a wide range of quality, velocity, and surfactant concentration
Petroleum Science 2023, 20(2): 1044-1052
Published: 20 November 2022
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Aqueous foam is broadly applicable to enhanced oil recovery (EOR). The rheology of foam as a function of foam quality, gas and liquid velocities, and surfactant concentration constitute the foundation of its application. The great variations of the above factors can affect the effectiveness of N2 foam in EOR continuously in complex formations, which is rarely involved in previous relevant studies. This paper presents an experimental study of foam flow in porous media by injecting pre-generated N2 foam into a sand pack under the conditions of considering a wide range of gas and liquid velocities and surfactant concentrations. The results show that in a wide range of gas and liquid velocities, the pressure gradient contours are L-shaped near the coordinate axes, but V-shaped in other regions. And the surfactant concentration is a strong factor influencing the trend of pressure gradient contours. Foam flow resistance is very sensitive to the surfactant concentration in both the high- and low-foam quality regime, especially when the surfactant concentration is less than CMC. The foam quality is an important variable to the flow resistance obtained. There exists a transition point from low- to high-quality regime in a particular flow system, where has the maximum flow resistance, the corresponding foam quality is called transition foam quality, which increases as the surfactant concentration increases. The results can add to our knowledge base of foam rheology in porous media, and can provide a strong basis for the field application of foams.

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