Photocatalytic green hydrogen (H₂) production technology, as a clean technology that replaces traditional fossil fuel-based H₂ production, has emerged as a research focus in addressing energy shortages and environmental pollution due to its unique advantage of being driven by solar energy. In recent years, remarkable advancements have been made in the design of photocatalysts and the investigation of reaction mechanisms, but the restricted light absorption range, high recombination rate of photogenerated carriers, and insufficient stability are still serious constraints on the increase in energy conversion efficiency. The development of high-performance photocatalysts is crucial for achieving efficient solar-to-hydrogen (STH) conversion. This review deeply analyzes the fundamental principles of photocatalytic green H₂ production from three dimensions: optimization of light absorption performance, regulation of charge dynamics, and enhancement of surface reaction kinetics. It systematically reviews the recent research achievements in this field and deeply deconstructs the design strategies of photocatalysts, aiming to provide references for the rational design of ideal photocatalysts and more in-depth mechanism analysis. Finally, future research directions and potential breakthroughs are discussed, with the aim of accelerating the development and practical application of solar-driven green H₂ production technology.

The Symmetric Solid Oxide Fuel Cell (SSOFC) with identical electrode materials improves the resistance to coking and sulfur poisoning of the anode by periodic switching of the cathode and anode. The advantages and disadvantages of the available symmetrical electrodes are summed up by classifying and collating the symmetrical electrodes in recent years. A comprehensive analysis shows that it is necessary to discover single-phase stable oxide symmetrical electrodes applicable to electrolytes other than La_0.8Sr_0.2Ga_0.8Mg_0.2O_3-δ (LSGM) or to develop new symmetrical electrode materials.