Tsinghua University and the Shanghai Institute of Satellite Engineering organized the 12th edition of the Global Trajectory Optimization Competition (GTOC12) on June 19, 2023. The problem for GTOC12, entitled "Sustainable Asteroid Mining", explores how spacecraft can be dispatched from the Earth to various asteroids for resource extraction. The primary challenge involves designing coupled trajectories for multiple spacecraft to maximize the collected mineral mass. A novel game model is introduced to encourage the mining of rarely mined asteroids. GTOC12 saw significant participation, with 102 teams registered. By the end of the competition, 28 teams provided feasible solutions, highlighting a growing interest in the field. This study describes the design process of the GTOC12 problem and presents a review and analysis of the results from the participating teams.