Microwave dielectric ceramics (MWDCs) are pivotal to modern wireless communication systems, with their performance governed by three key parameters: relative dielectric constant (ε_r), Q×f value (product of quality factor Q (reciprocal dielectric loss) and frequency f), and temperature coefficient of resonant frequency (τ_f). This review systematically summarizes the recent research progress of MWDCs from five interrelated aspects. In terms of performance characterization, standardized resonant methods achieve ε_r measurement errors below 1% and a tanδ detection limit as low as 10^-5. Theoretically, frameworks from complex crystal chemistry to the recently elucidated cation rattling effect enable quantitative interpretation of dielectric behavior. In processing, the cold sintering process achieves ceramic densification below 300 °C, reducing energy consumption by over 97% in comparison with conventional sintering. For applications, these materials have been widely deployed in high-performance substrates, resonators, and filters for 5G/6G communications, with device insertion loss maintained below 1 dB. Additionally, data-driven approaches, particularly machine learning, can accurately predict key dielectric properties with a coefficient of determination (R²) higher than 0.9, accelerating the exploration and development of novel MWDCs. By integrating these perspectives, this review offers a systematic insight into the state-of-the-art progress and future development directions of MWDCs research.

The rapid development of fifth-/sixth-generation telecommunication technologies has increased the demand for silicate ceramic materials with low permittivity and low dielectric loss. However, few silicate ceramics with ultrahigh Q×f values (≥ 200,000 GHz) have been developed to date. In this study, a slight substitution of Ge⁴⁺ ions in MgSi_1−xGe_xO₃ (MSGx, x = 0 to 0.6) ceramics caused a phase transition from clinoenstatite (x = 0) to orthoenstatite (x = 0.2), and the Q×f value increased from 70,600 GHz to 148,800 GHz. Following the phase transition, the cations change from a “compressed” state to a “rattle” state, and the lattice distortion continues to rise with x, resulting in the optimal microwave dielectric properties (ε_r = 7.21, Q×f  = 259,300 GHz) of the MgSi_0.5Ge_0.5O₃ ceramics. Significant discrepancies in the dielectric properties are found in the microwave and terahertz bands. There is an anomalous increase in ε_r and a decrease in the Q×f value in the terahertz band, which is due to the change in polar phonon modes revealed by the terahertz time-domain spectra. Consequently, MgSi_0.7Ge_0.3O₃ ceramics display superior dielectric properties, with ε_r = 7.02, Q×f  = 191,300 GHz in the terahertz band. These novel materials have the potential to serve as promising dielectric materials for future microwave or terahertz mobile communication systems.