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Open Access Research Article Issue
Zn0.5Co0.5Mn0.5Fe0.5Al0.5Mg0.5O4 high-entropy oxide with high capacity and ultra-long life for Li-ion battery anodes
Journal of Advanced Ceramics 2023, 12 (1): 59-71
Published: 02 December 2022
Downloads:549

Owing to the robust Li-ion storage properties induced by entropy stabilization effect, transition metal (TM)-based high-entropy oxides (HEOs) are promising electrode materials for high-performance Li-ion batteries (LIBs). In this study, a six-component Zn0.5Co0.5Mn0.5Fe0.5Al0.5Mg0.5O4 spinel-structured HEO (denoted as 6M-HEO, where M = Zn, Co, Mn, Fe, Al, and Mg) was synthesized using a facile coprecipitation method. When used as an anode of the LIBs, its stable high-entropy nanostructures exhibit high specific capacity (290 mAh·g−1 at a current density of 2 A·g−1), ultra-long cycling stability (maintained 81% of the initial capacity after 5000 cycles), and outstanding rate performance. Such excellent performance can be attributed to two factors. Firstly, its high-entropy structure can reduce the stress caused by intercalation and avoid volume expansion of the HEO nanostructures. As a result, the cyclic stability was significantly enhanced. Secondly, owing to the unique element selection in this study, four active elements (Zn, Co, Mn, and Fe) were incorporated in inactive MgO and Al2O3 matrice after the first discharge process, which would allow such high-entropy materials to withstand the rapid shuttle of Li ions.

Open Access Review Issue
Progress on rare-earth doped ZnO-based varistor materials
Journal of Advanced Ceramics 2013, 2 (3): 201-212
Published: 07 September 2013
Downloads:22

Rare-earth (RE) doping can greatly enhance the voltage gradient of ZnO-based varistors, and their nonlinear coefficient, leakage current, energy absorption capability, through-current capability and residual voltage can also be improved to certain extent. In this review, the progress on RE-doped ZnO-based varistor materials in recent years was summarized. The mechanism of RE doping on the electrical performance of ZnO varistors was analyzed. The issues in exploring new ZnO-based varistor materials by RE doping were indicated, and the development trends in this area were proposed.

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