Magnesium hydride (MgH2) is a promising solid-state hydrogen storage material due to its high hydrogen content and cyclic stability. However, its practical applications are limited by slow desorption kinetics and a high dehydrogenation temperature. To address these challenges, Pt-loaded MAX fibers with oxygen vacancies (Pt@MFs) have been synthesized by using vortex and hydrothermal methods. And the effects of the Pt@MFs on the hydrogen storage properties of MgH2 are investigated. The results display that the MgH2 doped with 10wt% Pt@MFs begins dehydrogenation at 169.3 ℃ and absorbs 5.73 wt% hydrogen in just 30 s at 125 ℃ and 30 bar hydrogen pressure. After 30 cycles, the MgH2–10 wt% Pt@MFs retains 98.7% of its initial capacity, showcasing excellent cycling stability. The synergistic effect of the MAX fiber network’s active sites, oxygen vacancies, anchored Pt nanoparticles and intermetallic compounds (PtTi, Pt3Ti) in the MgH2–10 wt% Pt@MFs composite significantly enhances hydrogen storage kinetics by facilitating diffusion, optimizing electron transfer, and weakening Mg-H bonds. The design concept of this material offers a novel strategy for improving the kinetics and stability of MgH2.
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Open Access
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Journal of Magnesium and Alloys 2026, 16(C)
Published: 14 September 2025
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