In this paper, the microspheres in flying-ash are used as sensitizer and inert additive to prepare the low detonation velocity emulsion explosives. The detonation velocity and the parameters of explosive shock wave in the air of emulsion explosives were measured by the probe method, the lead column compression method and the air explosion method, respectively. The safety of emulsion explosives was tested by the storage life experiment and thermal analysis experiment. The experimental results show that the detonation velocity, the brisance, the peak pressure, the positive impulse and the positive pressure action time of shock wave of emulsion explosives increased first and then decreased with the increase of the content of flying-ash microspheres. When the content of flying-ash microspheres was 15%, the detonation performance of emulsion explosive was the best, and when the content of flying-ash microspheres was 45% , the detonation velocity of the explosive decreased obviously. Meanwhile, the detonation velocity ranged from 2191 to 2312 m/s, which can satisfy the condition of using explosive for explosive welding. In addition, it is found that the detonation performance of emulsion explosives with D₅₀=79 μm flying-ash microspheres was higher than those of flying-ash microspheres with D₅₀=116 and 47 μm. The storage life and thermal analysis results indicate that the storage life of low detonation velocity emulsion explosives with flying-ash microspheres is significantly better than that of traditional low detonation velocity emulsion explosive with clay particles, the activation energy of thermal decomposition of the emulsion explosive with 15% flying-ash microspheres was only 0.3% higher than that of emulsion matrix. The results also show that the addition of flying-ash microspheres has no obvious effect on the thermal stability of the emulsion matrix. The research results have important reference value for green resource disposal of coal-based solid waste and formulation design of the low detonation velocity emulsion explosive.

To improve the mechanical behaviors and explosion performance of the Al/PTFE reactive materials, short-cut titanium fibers were added to Al/PTFE annular reactive materials, and subsequently assembled with RDX explosive column to form a composite charge. The effects of different titanium fiber contents on the mechanical behaviors of the annular reactive materials were investigated using a universal material testing machine and a split Hopkinson pressure bar. The influence of short-cut titanium fiber contents on the quasi-static pressure, shock wave parameters and thermal damage effects of the composite charge was studied in depth by the free-field explosion test system and spherical explosion container test system combined with the colorimetric temperature measurement technology. The temperature field of explosion flame was reconstructed by the colorimetric temperature measurement method with a high-speed camera, which was based on the gray-body radiation theory. A tungsten lamp calibrated the measurement accuracy of the temperature mapping system, and the fitting relationship between the temperatures and the gray values of the high-speed images was derived to obtain the conversion coefficient. The test results of mechanical properties showed that with the increase of titanium fiber content, the elastic modulus, yield strength and compressive strength of Al/PTFE annular reactive materials under quasi-static compression, as well as the yield strength and compressive strength under high-speed impact, all exhibited an initial increase, which were followed by a decrease, reaching the maximum values at 3% content. The experimental results of explosion performance showed that short-cut titanium fibers could significantly enhance the explosion performance of Al/PTFE-RDX composite charges. When the content of short-cut titanium fibers was 3%, the peak overpressure of the explosion shock wave, its positive phase duration and positive impulse were 37.68 kPa, 695.34 µs and 12.34 Pa·s, respectively. With 5% content of short-cut titanium fibers, the afterburning effect was the most significant. The maximum values of the explosion quasi-static pressure, average fireball temperature and fireball duration reached 70.50 kPa, 2782 K and 1668.90 µs, respectively. Analysis of solid explosion products indicated that short-cut titanium fibers could enhance the mechanical strength of the Al/PTFE matrix, delay the fragmentation time of the Al/PTFE annular reactive materials, promote the interfacial reactions, and participate in high-temperature chemical reactions, generating a synergistic effect and positive feedback to improve the mechanical toughness and energy release efficiency of the reactive materials.

In order to explore the influence of injection pressure on the deflagration characteristics of gasoline in the confined space, a 20 L spherical explosion test device was used to examine the changes of characteristic parameters, i.e., the transient flame propagation and temperature of gasoline mist deflagration under different injection pressures. The results showed that the optimum spraying time was 100 ms, and the maximum explosion pressure and maximum explosion pressure rise rate increased linearly with the increase of injection pressure, while explosion duration decreased linearly. The change of injection pressure had a more significant effect on explosion duration, and the combustion efficiency of gasoline increased significantly with the increase of injection pressure. Based on the colorimetric temperature measurement method, the flame temperature field was reconstructed. It was found that the maximum average temperature had a linear relationship with injection pressure, and the maximum average temperature increased with injection pressure. The influence of injection pressure on the deflagration characteristics of gasoline mist was analyzed through the changes of mist morphology and flame temperature during flame propagation. The outcome of this research can provide theoretical reference for the design of turbocharged direct injection internal combustion engine and the improvement of combustion efficiency and economy of gasoline internal combustion engine.