Multicomponent (Hf,Zr,Ta)C ceramics are promising candidates for ablation-resistant coating materials applied in ultrahigh-temperature environments. However, the influence of compositional variations on their ablation behavior remains insufficiently understood. In this study, the effect of Ta content on the ablation resistance of (Hf,Zr,Ta)C coatings was systematically investigated. Moderate Ta addition promotes the densification of oxide scales, whereas excessive Ta reduces the thermochemical stability of the oxide scale, leading to increased ablation damage. The optimized composition, the T15 coating, exhibits superior ablation resistance, maintaining structural integrity for 300 s under an ~2160 °C oxyacetylene flame. This enhancement is attributed to the co-formation of the (Hf,Zr,Ta)O2 and (Hf,Zr)6Ta2O17 phases. Ta5+ partially dissolves into (Hf,Zr)O2 (~5 at%), reducing the oxygen vacancy concentration and improving the oxidation resistance. Additionally, the Ta-rich liquid phase generated from the decomposition of (Hf,Zr)6Ta2O17 enhances oxide scale densification and contributes to structural stability during cooling through peritectic transformation. These results demonstrate that non-equimolar multicomponent carbides offer a feasible strategy for improving the ablation resistance of ultrahigh-temperature coatings.
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Open Access
Research Article
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Journal of Advanced Ceramics 2026, 15(1): 9221207
Published: 29 January 2026
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