To develop an objective evaluation method for meat flavors, electronic nose responses were employed as objective evaluation measures to compensate for the disadvantages of traditional sensory evaluation, such as strong randomness as well as poor repeatability and stability. In this study, Maillard reaction was used to prepare two meat flavors: barbecue-like and broth-like, and the correlation between sensory evaluation and electronic nose responses was established by using grey correlation degree, principal component analysis (PCA), and analysis of variance (ANOVA). The results showed that through Maillard reaction with 10.00 g/100 mL of glutamic acid, a strong broth-like flavor was obtained, and the sensors W5S, W6S, W1S, W1W, and W2S had higher response values to the broth-like flavor, and their correlation coefficients with the sensory evaluation scores were 0.738, 0.803, 0.822, 0.825 and 0.864, respectively; when 3.33 g/100 mL of glutamic acid was added to the reaction system, a strong barbecue-like flavor was obtained, and the sensors W5S, W6S, W1S, and W1W had higher response values to the barbecue-like flavor, and their correlation coefficients with the sensory evaluation scores were 0.744, 0.835, 0.847, and 0.854, respectively. On this basis, a regression model was developed between the correlation coefficients of the sensor response values with higher grey correlation degree and the sensory scores, which had excellent goodness of fit.