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Carbon-dots-mediated flexible inverse opal perovskite film featuring structural robustness and highly selective photocatalytic CO2 reduction
Nano Research 2025, 18(11): 94907745
Published: 24 October 2025
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Direct conversion of CO2 to chemical fuels by photocatalysis has emerged as a promising strategy to alleviate global warming and renewable energy shortage issues. Halide perovskites with unique photoelectronic attributes show great potential for CO2 photoreduction. However, their low photogenerated electron–hole efficiency and intrinsic structural instability in aqueous solution are still a significant challenge. In this work, we propose a universal facile strategy of robust carbon dots (CDs) mediated inverse opal perovskite (IOP) free-standing film, which is demonstrated as a uniform porous photocatalytic platform for efficient CO2 photoreduction. Due to the grain boundary passivation effect of CDs, the mechanical strength and water resistance of CDs/IOP films are greatly improved. By the synergetic effects of IO structure and CDs cocatalyst, highly selective CO evolution rate of 60.25 μmol·g−1·h−1 from photocatalytic CO2 reduction is achieved on typical CDs/CsPbBr3 IOP film, which is 15.6 times higher than that of opal CsPbBr3, since the enhanced lifetime of photogenerated electrons–holes and light/mass transfers. This work provides a new opportunity for robust and highly stable perovskite photocatalyst preparation to address the environmental and energy issues via an efficient photocatalysis process.

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