In order to study the effect of 1-methylcyclopropene (1-MCP) combined with konjac glucomannan/κ-carrageenan (KGM/KC) coating treatment on the preservation of pears, ‘Sucui 1’ pears subjected to one of four treatments: water (control), 1-MCP, KGM/KC coating, and 1-MCP + KGM/KC coating was evaluated for quality and reactive oxygen species metabolism during shelf life. The results showed that both 1-MCP and KGM/KC coating treatments delayed the decline in the quality of ‘Sucui 1’ pears. Compared with the single treatments, 1-MCP + KGM/KC coating treatment reduced the postharvest respiration intensity and ethylene release rate, and improved the activities of antioxidant enzymes such as superoxide dismutase (SOD), peroxidase (POD) and catalase (CAT). Furthermore, it significantly inhibited the production rate of superoxide anion radical, reduced the accumulation of H₂O₂ and malondialdehyde (MDA), and delayed the decrease in the hardness and the contents of ascorbic acid, soluble sugar and titrable acid in pear fruits. In conclusion, KGM/KC treatment could maintain the quality of ‘Sucui 1’ pears during shelf life, and 1-MCP + KGM/KC coating treatment could more effectively delay the quality decline and extend the shelf life of ‘Sucui 1’ pears, providing a reference for its application in post-harvest preservation of pears.