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Open Access Review Issue
Recent advancements in thermal conductivity of magnesium alloys
Journal of Magnesium and Alloys 2024, 12(5): 1687-1708
Published: 11 March 2024
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As highly integrated circuits continue to advance, accompanied by a growing demand for energy efficiency and weight reduction, materials are confronted with mounting challenges pertaining to thermal conductivity and lightweight properties. By virtue of numerous intrinsic mechanisms, as a result, the thermal conductivity and mechanical properties of the Mg alloys are often inversely related, which becomes a bottleneck limiting the application of Mg alloys. Based on several effective modification methods to improve the thermal conductivity of Mg alloys, this paper describes the law of how they affect the mechanical properties, and clearly indicates that peak aging treatment is one of the best ways to simultaneously enhance an alloy's thermal conductivity and mechanical properties. As the most frequently used Mg alloy, cast alloys exhibit substantial potential for achieving high thermal conductivity. Moreover, recent reports indicate that hot deformation can significantly improve the mechanical properties while maintaining, and potentially slightly enhancing, the alloy's thermal conductivity. This presents a meaningful way to develop Mg alloys for applications in the field of small-volume heat dissipation components that require high strength. This comprehensive review begins by outlining standard testing and prediction methods, followed by the theoretical models used to predict thermal conductivity, and then explores the primary influencing factors affecting thermal conductivity. The review summarizes the current development status of Mg alloys, focusing on the quest for alloys that offer both high thermal conductivity and high strength. It concludes by providing insights into forthcoming prospects and challenges within this field.

Open Access Full Length Article Issue
Facile synthesis of a Ni3S2@C composite using cation exchange resin as an efficient catalyst to improve the kinetic properties of MgH2
Journal of Magnesium and Alloys 2022, 10(12): 3628-3640
Published: 20 May 2021
Abstract PDF (24.2 MB) Collect
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Carbon materials have excellent catalytic effects on the hydrogen storage performance of MgH2. Here, carbon-supported Ni3S2 (denoted as Ni3S2@C) was synthesized by a facile chemical route using ion exchange resin and nickel acetate tetrahydrate as raw materials and then introduced to improve the hydrogen storage properties of MgH2. The results indicated the addition of 10wt.% Ni3S2@C prepared by macroporous ion exchange resin can effectively improve the hydrogenation/dehydrogenation kinetic properties of MgH2. At 100 ℃, the dehydrogenated MgH2-Ni3S2@C-4 composite could absorb 5.68wt.% H2. Additionally, the rehydrogenated MgH2-Ni3S2@C-4 sample could release 6.35wt.% H2 at 275 ℃. The dehydrogenation/hydrogenation enthalpy changes of MgH2-Ni3S2@C-4 were calculated to be 78.5 kJ mol−1/−74.7 kJ mol−1, i.e., 11.0 kJ mol−1/7.3 kJ mol−1 lower than those of MgH2. The improvement in the kinetic properties of MgH2 was ascribed to the multi-phase catalytic action of C, Mg2Ni, and MgS, which were formed by the reaction between Ni3S2 contained in the Ni3S2@C catalyst and Mg during the first hydrogen absorption–desorption process.

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