The application of Mg-based electrochemical energy storage materials in high performance supercapacitors is an essential step to promote the exploitation and utilization of magnesium resources in the field of energy storage. Unfortunately, the inherent chemical properties of magnesium lead to poor cycling stability and electrochemical reactivity, which seriously limit the application of Mg-based materials in supercapacitors. Herein, in this review, more than 70 research papers published in recent 10 years were collected and analyzed. Some representative research works were selected, and the results of various regulative strategies to improve the electrochemical performance of Mg-based materials were discussed. The effects of various regulative strategies (such as constructing nanostructures, synthesizing composites, defect engineering, and binder-free synthesis, etc.) on the electrochemical performance and their mechanism are demonstrated using spinel-structured MgX₂O₄ and layered structured Mg-X-LDHs as examples. In addition, the application of magnesium oxide and magnesium hydroxide in electrode materials, MXene's solid spacers and hard templates are introduced. Finally, the challenges and outlooks of Mg-based electrochemical energy storage materials in high performance supercapacitors are also discussed.

Epoxy resin powder coating has been successfully applied on the corrosion protection of magnesium lithium alloys. However, poor wear resistance and microcracks formed during the solidification have limited it extensive application. There are limited approaches to exploit such anti-corrosion and mechanical properties of magnesium lithium alloys. Herein, the epoxy resin powder coating with polydopamine modified molybdenum disulfide (MoS₂@PDA-EP powder coating with 0, 0.1, 0.2, 0.5, 1.0 wt.% loading) was well prepared by melt extrusion to investigate its anticorrosion performance and wear resistance. The results revealed that the addition of MoS₂@PDA enhanced the adhesion strength between coatings and alloys, wear resistance and corrosion protection of the powder coatings. Among them, the optimum was obtained by 0.2 wt.% MoS₂@PDA-EP powder coating which could be attributed to well dispersion and efficient adhesion with coating matrix. To conclude, MoS₂@PDA-EP powder coating is meaningfully beneficial for the anticorrosive and wear performance improvement of magnesium lithium alloys.

Superhydrophobic coating has been widely studied for its great applicational potential, such as for corrosion protection of magnesium alloys while it has been restrained by expensive materials, sophisticated preparation process and infirm rough structures. In this study, the electrochemical method was adopted by using a two-electrode system for rapid hydrophobic modification to obtain superhydrophobic kaolin. By mixing the modified superhydrophobic kaolin with commercial epoxy resin and polydimethylsiloxane glue, a paint can be formed and easily used on various substrates for preparation of superhydrophobic coating via spraying method. The influence factors on wettability of the modified kaolin and the mixing ratio of each component of the coating were explored. Also, the wettability, durability and anticorrosion of the prepared coating were evaluated comprehensively. The coating was able to maintain superhydrophobic after immersed in HCl solution at pH 1, the NaOH solution at pH 14, and 3.5 wt.% NaCl solution for 16, 21, 30 days, respectively. In addition, the coating exhibited 4A grade adhesion, high hydrophobicity after abraded for 200 cycles on a 600-mesh sandpaper with 100 g weight, and 99.86% anticorrosion efficiency after soaked in 3.5 wt.% NaCl solution for 20 days, demonstrating a good robustness and anti-corrosion property. Furthermore, the coating showed good transparency, flexibility and was easy to make in a large scale by the spraying method, which is of great significance to promote the practical application of superhydrophobic coatings and the anticorrosion Mg alloys.