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Research Article Issue
Combustion Characteristics of Silicon Carbide Porous Ceramics Based on Hexahedral Cell Structure
Journal of the Chinese Ceramic Society 2025, 53(9): 2675-2686
Published: 13 August 2025
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Introduction

To solve the problems that the porosity is difficult to accurately control and the pore structure uniformity is insufficient in the traditional process of replicating polyurethane foam with ceramic slurry, a biclinic body design method based on regular hexahedron cell structure was introduced to prepare porous ceramic parts for high-performance porous media burner. The influence of parameters (i.e., cell edge length, pore rib diameter and array layer number) on the strength and combustion characteristics of porous ceramic materials was investigated.

Methods

The model was firstly designed by a software named ANSYS Spaceclaim modeling, and then the samples were prepared by 3D printing. The compressive strength of porous ceramic structures was tested by a model TSE104B universal material testing machine at a loading rate of 0.5 mm/min. A circular loading plate with a diameter of 100 mm was used to apply pressure to the samples, and the maximum compressive strength σs of each sample was calculated by recording the failure load. Combustion performance testing was conducted in a porous media combustion platform, and the composition and temperature of the flue gas were monitored by a model testo 350 flue gas analyzer. The temperature changes were recorded by an infrared thermal imager.

The stress distribution and internal combustion mechanism of the porous ceramic under uniaxial compression were analyzed by numerical simulation methods. Among them, ANSYS Static Structural module was used for stress distribution analysis, and ANSYS Fluent module was used for finite element analysis of the flow field of porous media, thus evaluating the effect of porosity on gas disturbance, heat transfer behavior, fluid pressure drop, and heat exchange efficiency.

Results and discussion

In a high porosity range (i.e., ε≥90%), extending the residence time of premixed gas and enhancing turbulence effects can effectively promote gas mixing and combustion, thereby improving the overall combustion performance. Moderately reducing porosity (i.e., from 93% to 86%) improves the compressive strength of the material (approximately 100%) although this leads to a decrease in the maximum surface temperature (about 18.4 ℃) and an increase in CO emissions (about 8.75 mg/m3). This indicates that a moderate reduction in porosity sacrifices combustion efficiency at a high porosity can enhance the strength. In contrast, the structure in a low porosity range (ε<90%) restricts the free flow of gas flow, resulting in uneven velocity distribution and reduced turbulence, hindering effective gas mixing and combustion, thereby reducing combustion efficiency. This indicates that it is difficult to simultaneously improve combustion efficiency and strength at a low porosity. It is thus possible to balance combustion efficiency and strength via finely adjusting the porosity in the high porosity range (i.e., ε≥90%), achieving a synergistic effect.

Conclusions

The strength of SiC porous ceramic structures could be effectively improved via reducing the cell edge length a, increasing the number of layers n, and pore reinforcement diameter d. The pore reinforcement diameter d had a more significant impact on the strength of SiC porous ceramic structures. There was a certain enhancement effect on the maximum surface temperature of SiC porous ceramic structure via increasing a and decreasing n and d. At a high porosity, a and n had a more significant impact on the maximum surface temperature of SiC porous ceramic structure. At a low porosity, d had a more significant impact on CO emissions from SiC porous ceramic structures.

Research Article Issue
Effect of Calcium Hexaluminate Aggregate Content on Mechanical Properties and Fracture Behavior of Corundum–Calcium Hexaluminate Castables
Journal of the Chinese Ceramic Society 2022, 50(12): 3293-3304
Published: 14 November 2022
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Calcium aluminate cement bond reacts with matrix to form flake calcium hexaluminate phase at a high temperature, thus effectively improving the thermal shock resistance of the material. However, too much cement will produce a large volume expansion that affects the properties of the material. In this paper, calcium hexaluminate aggregate was used to partially or completely replace the tabular corundum aggregate to prepare castable, and the effect of aggregate porosity on the mechanical properties of castable after curing and high-temperature treatment was investigated, and the fracture behavior of castable was analyzed via wedge splitting experiment. The results show that at 25 ℃, compared with tabular corundum, water absorption and release effect of pores in calcium hexaluminate aggregate promote the formation of more hydration products around the aggregate, accelerate the hydration reaction of cement, and favor the interface meshing between aggregate and matrix. After heat-treatment at 1600 ℃, the hydration product is transformed into a secondary phase CA6, which improves the interface strength of aggregate and matrix, and increases the proportion of crack propagation in aggregate during material fracture. The castable with 30%CA6 aggregate has an optimum crack propagation resistance.

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