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Progress in the Application of Isotope Tracing in Ceramic Archaeometry
Journal of Ceramics 2025, 46(5): 905-917
Published: 01 October 2025
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Significance

At present, scientific research on ancient ceramics mainly focuses on aspects such as material sources, manufacturing techniques, chronology, burial and preservation conditions. Among these, determining the types of ceramic raw materials and their places of origin is of utmost importance. Since the raw materials for ancient porcelain production were all naturally-formed minerals and rocks in nature, which are closely related to geoscience, the research methods of geoscience have also been widely applied to the field of ceramic archaeology. In recent years, due to the rapid development of mass spectrometry technology, especially the extensive use of multi-collector inductively coupled plasma mass spectrometry, a series of analytical methods for isotope systems have been successively established. Scholars at home and abroad have gradually become aware of the tracer applications of some isotope systems to the raw materials, origins, and manufacturing processes of ancient ceramics, and have carried out useful experiments and explorations. The basic concept of the cross-application of isotope tracing in the scientific archaeology of ceramics is to compare the isotope composition of ancient ceramics with that of the geological bodies of the raw materials, so as to identify the sources or compositions of the raw materials.

Progress

Sr isotope ratio analysis is primarily employed for tracing the origin of ancient ceramics. It aids in uncovering the geographical origin of ceramic raw materials and their technological features. Simultaneously, it also plays a significant role in researching ancient glazing techniques and raw material compositions. Pb isotope analysis, through the study of the body of lead-glazed pottery, offers further information regarding the origin of ancient ceramics and their production techniques. Ca isotope tracing technology is relatively novel in the realm of ancient ceramic research, yet it has gradually started to be applied to the study of glazing raw materials and their proportions, assisting in revealing the mineral sources and their chemical characteristics utilized in the ceramic-making process. With the continuous deepening of relevant research, some scholars have also adopted a multi-isotope analysis method combining Sr isotopes with Nd isotopes and Pb isotopes to study the origin of ancient ceramics and the composition of glaze formulas. Besides the common Sr and Pb isotopes, there are also sporadic studies in ceramic archaeology applying some other isotopes. For instance, δ13C and δ8O values are used as supplements to explore the types and sources of tempering materials in the pottery-making process. The application of isotopes of new elements has opened up entirely new perspectives for ceramic archaeology. By precisely applying different isotope systems to the level of raw material sources, the origin of the body and glaze of ancient ceramics can be accurately pinpointed based on isotope characteristics, thus clarifying the resource distribution of ancient ceramic production.

Conclusions and prospects

With the continuous advancement of isotope analysis technology, methods combining multiple isotope systems have emerged to study the origin of ancient ceramics and the composition of glaze formulas. The precision and accuracy of such methods will be further enhanced, holding the promise of determining the origin of ceramics and their glaze formulas with even greater precision. In the future, with the continuous advancement of isotope analysis techniques, the combined application of multi-isotope systems, and the development of non-/micro-destructive testing methods, it is expected that the origin of ceramics and the glaze formulas can be determined more precisely. This will provide a more reliable basis for studying ancient ceramic trade and cultural exchanges. At the same time, it will also contribute to the restoration of the entire process of ancient porcelain-making techniques.

Issue
Effect of Artificial Irradiation on Thermoluminescence Pre-dose Method for Porcelain
Journal of Ceramics 2024, 45(1): 166-172
Published: 01 February 2024
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Thermoluminescence technology can be used to estimate the age of porcelain by measuring the amount of radiation that has accumulated since the porcelain was fired. However, artificial irradiation may affect the thermoluminescence dating, because the “age” of the porcelain could be increased due to the addition more radiation. The effects of different sources of artificial irradiation were examined, such as security scanners in high-speed rail stations, laboratory irradiation and X-ray fluorescence spectrometer. Firstly, the security scanners in high-speed railway stations and other places do not have a significant impact on the thermoluminescence age of the porcelain. Secondly, the normal XRF testing time does not affect the porcelain dating either. Thirdly, the laboratory irradiation can increase the thermoluminescence age of the porcelain in a linear way, depending on the radiation dose. The porcelain will undergo radiation decay if it is exposed to artificial irradiation in the laboratory for too long time.

Issue
Impact of Thermal Treatment on Thermoluminescence Pre-dose Dating of Ancient Porcelains
Journal of Ceramics 2024, 45(5): 1039-1047
Published: 01 October 2024
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Thermoluminescence dating is an important means to identify the authenticity and dating of ancient ceramics, while the sum of the environmental background radiation energy received by the porcelain after high-temperature firing can be judged by measuring the photon energy released by porcelain, so as to estimate the time elapsed from high-temperature firing to the present. However, if the porcelain is subjected to a high temperature event during preservation, the thermoluminescence energy accumulated by the crystals inside the porcelain will be released in whole or in part, resulting in an age that may not be the actual one of the porcelain. In this study, ancient porcelain samples were subjected to heat treatment at different temperatures, while the cumulative radiation dose was measured by using thermoluminescence pre-dose technology to explore the effect of heating temperature on the results of thermoluminescence dating. It is showed that heating temperature below 300 ℃ had no significant effect on the dating results. When the temperature exceeded 400 ℃, the dating results decreased with increasing temperature. When the temperature was higher than 600 ℃, the thermoluminescence signal disappears completely. Therefore, in order to ensure the accuracy of thermoluminescence dating, it is necessary to understand the heating history of ancient porcelain in detail. When the background level (S0) of the sample is abnormally high, it should be considered whether the sample has experienced an excessively high temperature event. If heat treatment is required during the preservation and restoration of ancient porcelain, the temperature should be strictly controlled below 300 ℃ to avoid interference with the thermoluminescence signal. This discovery has important practical guiding significance for the identification and protection of ancient porcelain.

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