The natural gas hydrate has become one of the most promising future green energy sources on the earth. The natural gas hydrates mostly exist in the sediments with porous structure, so a solid understanding of the hydrate formation and growth processes in the porous medium is of significance for the exploitation of natural gas hydrate. The micro-packed bed device is one of the efficient microfluidic devices in the engineering field, but it has been rarely used for the hydrate-based research. In this study, a transparent micro-packed bed device filled with glass beads was developed to mimic the porous condition of sediments, and used to in-situ visualize the hydrate formation and growth habits in the pore spaces under both static and dynamic conditions. For the static experiment, two types of hydrate growth patterns in porous medium were observed and identified in the micro-packed bed device, which were the grain-coating growth and pore-filling growth. For the dynamic condition, the hydrate formation, growth, distribution habits and hydrate blockage phenomena in the pore spaces were in-situ visually captured. The impacts of flowrate and subcooling on the pressure variation of the micro-packed bed and the duration of the hydrate growth under dynamic flow condition in pores were in-situ monitored and analyzed. The higher flowrate could result in the faster hydrate growth and more severe blockage in pores, but the effect of subcooling condition might be less significant at the high flowrate.

The natural gas hydrate has been regarded as an important future green energy. Significant progress on the hydrate exploitation has been made, but some challenges are still remaining. In order to enhance the hydrate exploitation efficiency, a significant understanding of the effective thermal conductivity (ETC) of the hydrate-bearing sediment has become essential, since it directly controls the heat and mass transfer behaviors, and thereby determines the stability of hydrate reservoir and production rate. In this study, the effective thermal conductivities of various hydrate-bearing sediments were in-situ measured and studied. The impacts of temperature, particle size and type of sediment were investigated. The effective thermal conductivities of the quartz sand sediments before and after hydrate formation were in-situ measured. The results show the weak negative correlation of effective thermal conductivity of the quartz sand sediment on the temperature before and after the hydrate formation. The effective thermal conductivity of the hydrate-bearing sediment decreases with the increase of particle size of the sediment. The dominant effect of the type of porous medium on the characteristics of the effective thermal conductivity of hydrate-bearing sediment was highlighted. The results indicate that both the effective thermal conductivities of hydrate-bearing quartz sand sediment and hydrate-bearing silicon carbide sediment are weakly negatively correlated with temperature, but the effective thermal conductivity of hydrate-bearing clay sediment is weakly positively dependent on the temperature. In addition, the values of the effective thermal conductivities of various hydrate-bearing sediments are in the order of hydrate-bearing silicon carbide sediment > hydrate-bearing quartz sand sediment > hydrate-bearing clay sediment. These findings could suggest that the intrinsic thermal conductivity of porous medium could control the characteristics of effective thermal conductivity of hydrate-bearing sediment.