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Open Access Original Paper Issue
Development and feasibility test of a fan-shaped hydrate simulator with a radius of 3 m
Petroleum Science 2025, 22(11): 4794-4808
Published: 13 October 2025
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Large-scale physical simulation is essential for advancing our understanding of natural gas hydrates exploitation mechanism. However, cylinder-shaped simulators often face challenges in balancing large volume, controllability, and comprehensive monitoring. In this study, we developed a fan column-shaped hydrate simulator (FCHS) with an internal angle of 6°, a radius of 3 m, and an inner height of 0.3 m, resulting in an effective volume of ~142 L. Moreover, the FCHS is equipped with an integrated "thermal-pressure-acoustic" sensing system, enabling in-situ monitoring of temperature, pressure, and P-wave velocity evolution during hydrate formation and dissociation process. The experimental results indicate that a pressure gradient successfully established from the reservoir center toward its boundaries during depressurization stage, and pressure propagation is relatively slow, resulting in a radial pressure difference of 3–4 MPa within a 3 m range. Once the system reaches pressure equilibrium, the pressure difference decreases to 0.3–0.4 MPa. The depressurization at the wellbore promotes hydrate dissociation in the near-well region, resulting in the radial temperature difference reaches ~1.5 ℃ along the radial direction. The acoustic data reveals that a radial gradient in hydrate saturation gradually forms from the center to the boundary during depressurization-induced gas production. The evolutions of spatio-temporal multi-fields obtained in the FCHS are consist with that of field production. The FCHS proves to be a cutting-edge platform for experimental simulation of NGH exploitation and carbon sequestration processes.

Open Access Original Paper Issue
Self-adaptive gas flow and phase change behaviors during hydrate exploitation by alternate injection of N2 and CO2
Petroleum Science 2024, 21(3): 2120-2129
Published: 11 January 2024
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Since hydrate resources play a part of the stratigraphic framework structure in sediments, establishing a safe and economic method for hydrates exploitation remains the primary challenge to this day. Among the proposed methods, the spontaneous displacement of CH4 from hydrate cages by CO2 seems to be a perfect mechanism to address gas production and CO2 storage, especially in today's strong demand for carbon reduction and replacing clean energy. After extensive lab researches, in the past decade, injecting a mixture of CO2 and small molecule gas has become a key means to enhance displacement efficiency and has great potential for application. However, there is a lack of in-depth research on gas flow in the reservoir, while the injected gas always passes through low-saturated hydrate areas with high permeability and then occurs gas channel in a short term, finally resulting in the decreases in gas production efficiency and produced gas quality. Therefore, we explored a new injection-production mode of alternate injection of N2 and CO2 in order to fully coordinate the advantages of N2 in enhanced hydrate decomposition and CO2 in solid storage and heat compensation. These alternate “taking” and “storing” processes perfectly repair the problem of the gas channel, achieving self-regulation effect of CH4 recovery and CO2 storage. The 3-D experimental results show that compared to the mixed gas injection, CH4 recovery is increased by >50% and CO2 storage is increased by >70%. Additionally, this alternate injection mode presented a better performance in CH4 concentration of produced gas and showed outstanding N2 utilization efficiency. Further, we analyzed its self-adaptive gas flow mechanism and proposed an application model of “one injection and multiple production”. We look forward to this study accelerating the application of CO2-CH4 replacement technology.

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