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Nanofiber-reinforced CoFe2O4/graphene composite aerogel as broadband electromagnetic wave absorber
Nano Research 2025, 18(2): 94907142
Published: 10 January 2025
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Graphene aerogel (GA) is a promising lightweight and high-performance material for electromagnetic wave absorption due to its ultra-light mass. However, the impedance matching and attenuation capabilities of GA are limited by its high conductivity and constrained attenuation paths. To address this limitation, magnetic materials are often combined with GA to enhance both impedance matching and attenuation performance. Nevertheless, little attention has been given to the influence of magnetic materials with varying morphologies on the electromagnetic wave absorption (EMA) properties. In this study, CoFe2O4 nanofibers were prepared via electrospinning technology as an alternative to commercial CoFe2O4 nanoparticles. Subsequently, CoFe2O4@GA composites were synthesized through a hydrothermal reaction in a graphene oxide (GO) solution. Moreover, the inclusion of ethylene glycol in the GO solution helped regulate the volume shrinkage of GA after the adding of CoFe2O4, thus preventing structural instability and fragmentation. The introduction of a small quantity of magnetic nanofibers significantly enhanced the EMA performance of the CoFe2O4@GA composite, increasing the strongest absorption from –34.5 to –53.5 dB and widening the maximum effective absorption bandwidth (EAB) from 8.0 to 8.7 GHz. Finally, the study revealed that CoFe2O4 nanofibers outperformed nanoparticles in electromagnetic wave loss mechanisms, including magnetic coupling, magnetic resonance, eddy current loss, and interface polarization. This finding provides valuable insights for the selection and optimization of magnetic component morphologies in EMA materials.

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