In the domain of gas pipeline operations, significant safety hazards prevail. This study delves into the triggering mechanisms behind gas pipeline leakage incidents, pinpoints key risk factors contributing to these occurrences, and proposes effective control measures. By classifying risk coupling forms associated with various accidents, the N-K model formula is utilized to assess the coupling degree of primary risk factors. The resultant coupling relationship is integrated into the University of California at Irvine NETwork (UCINET), forming a complex network model for quantitative analysis. Secondary risk factors' coupling degrees are measured, and the network's characteristic parameters are scrutinized. Noteworthy risk factors within the network include improper maintenance (A3), unclear or missing signage (C4), equipment aging and wear (B10), unauthorized occupation of ground space (C5), failure to implement rules and regulations (D3), and failure of electrical protection (B5). By controlling the above risk factors, disrupting the coupling process of risk factors, and blocking the transmission pathways of risk factors, the objective is to prevent leakage incidents and ensure the safe operation of gas pipelines.
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Open Access
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In the green synthesis reaction of adipic acid, the oxidant H2O2 undergoes exothermic decomposition easily and the high exothermic amount of the reaction can easily lead to thermal runaway. This study carries out calorimetric experiments on the green synthesis reaction of adipic acid, studies the effect of the stabilizer ethylenediaminetetraacetic acid (EDTA) on the safety of the synthesis reaction, and further explores the effect of EDTA on the Na2WO4-catalyzed decomposition reaction of H2O2 under the conditions of continuous flow, and develops the microchannel continuous flow process of green synthesis of adipic acid containing EDTA, in order to provide theoretical support for the improvement of intrinsic safety of green synthesis of adipic acid.
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Thermal decomposition experiment of 5-(4-Pyridyl)tetrazolate (H4-PTZ) was carried out. The heat flow curve and reaction rate data under different heating rates were obtained. The characteristic parameters were obtained. The apparent activation energy for each individual reaction was calculated by applying different methods. On this basis, the Malek method was used to predict the most probable mechanism function of thermal decomposition reaction of H4-PTZ. The thermal safety parameters, including self-accelerating decomposition temperature, hot spot fire temperature and thermal explosion critical temperature were also predicted. The activation enthalpy, activation entropy, and activation Gibbs free energy of H4-PTZ are calculated. Gaussian16 program was used to optimize the molecular structure, search the transition state and calculate the intrinsic reaction coordinates of H4-PTZ. The most probable decomposition path of H4-PTZ was found, and the activation energy calculated by experiment was compared with that calculated by the theory.
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