The development of efficient near-infrared (NIR) light-driven Cu₂O-based photocatalysts and a deeper understanding of their underlying mechanisms for pollutant degradation are urgently needed. Herein, we report the rational design of oxygen vacancy-enriched Cu/Cu₂O Schottky junctions via H₂MoO₄-template-assisted liquid-phase reduction method. Under NIR irradiation, the optimized Cu/Cu₂O composite exhibits remarkable photothermal catalytic performance, achieving 85.1% degradation of tetracycline within 120 min. The enhanced activity is attributed to the synergistic effect of the Schottky junction, dual localized surface plasmon resonance (LSPR), and a unique “directional anchoring” mechanism for O₂ activation. First, the Schottky junction formed at the Cu/Cu₂O interface promotes efficient separation of photogenerated charges. Second, a dual LSPR effect, combining the intrinsic LSPR of Cu nanoparticles with the defect-state LSPR induced by oxygen vacancies, significantly enhances NIR light absorption and photothermal conversion efficiency. Most importantly, in-situ spectroscopic and density functional theory analyses reveal a unique “directional anchoring” mechanism for O₂ activation at the oxygen vacancy (OV)-Cu interface. In this process, O₂ is selectively captured at the OV–Cu dual sites, where electron transfer from the interface weakens the O–O bond, thereby facilitating the generation of reactive oxygen species. This work provides fundamental insights into the design of high-performance NIR-driven photothermal catalysts for environmental remediation.

Simultaneously integrating mesocrystalline stacking superstructures, porous nanosheets and defective oxygen vacancies (OVs) into BiOCl crystals is an available strategy to enhance the visible-light-driven photocatalytic activity. Herein, we report a facile etching agent-assisted hydrothermal approach to achieve one-pot fabrication of mesocrystalline BiOCl porous nanosheet stacking superstructures with defective OVs, which show high catalytic activities towards to the visible-light-driven degradation of organic dyes. The formation of stacking superstructure in a mesocrystalline BiOCl is responsibility for increasing the transport of charge carriers. Experimental results and theoretical calculations suggest that the presence of OVs is beneficial to tuning the energy band structure for the improvement of visible light harvesting, prolonging the lifetime and enhancing the oxidation activity of photogenerated charge carriers. Additionally, the porous morphology and thin nanosheet building block could supply abundant active sites for photocatalysis. This research might arouse in-depth investigations on the development of novel precursor-modified strategy for the synthesis of high-active BiOX (X = Cl, Br and I)-based photocatalysts.