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Synergistic improvement of dryland soil and maize yield by combined application of flue gas desulfurization gypsum and glutamic acid by-products
Transactions of the Chinese Society of Agricultural Engineering 2026, 42(14): 178-187
Published: 30 July 2026
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A tradeoff is often required between soil reclamation and crop productivity in sustainable agriculture. However, the critical constraints have caused soil water scarcity, nutrient impoverishment, and low hydro-thermal-nutrient use efficiency in the dryland loess regions of Northern China. This study aimed to evaluate the synergistic soil improvement via the combined application of flue gas desulfurization (FGD) gypsum and glutamic acid fermentation by-products (residue and liquid). This study aims to provide theoretical references and technical support for the green productionof maizae in dry plateau areas, the improvement of soil quality, and the efficient and green development of dryland agriculture. A systematic plot experiment was conducted in the maize field of Jinzhong dryland region, Shanxi Province, China, during an extremely arid growing season in 2024. Seven treatments included: a control (CK, without amendment), and two composite amendments at three rates (7.5, 15.0, and 22.5 t/hm2). Amendment I was formulated with 60% FGDG and 40% glutamic acid liquid, while Amendment II consisted of 60% FGD gypsum and 40% glutamic acid liquid. The parameters were then determined at the harvest stage, including key soil parameters in the 0–20 cm layer, water-soluble ion compositions, and maize agronomic traits. The results demonstrated that both composite amendments exerted significant modulating effects on soil water-salt-nutrient dynamics. In terms of hydrological properties, Amendment-II exhibited a highly stable water retention (P<0.05), with the soil water content increasing by 22.9% to 30.3% among all dosages, whereas Amendment-I shared a significant effect (25.6% increase, P<0.05) only at the highest rate (22.5 t/hm2). Furthermore, both amendments significantly mitigated alkalinity (P<0.05) in soil reaction, thus reducing pH values by 0.3 to 0.7. Specifically, Amendment-I treatment demonstrated a superior acidification potential (0.5-0.7 reduction), due to its lower raw pH (2.5) and higher residual acidity. Concurrently, soil electrical conductivity (EC) increased from a baseline of 134 μS/cm to the range of 235.0%-461.0% (Amendment-I) and 115.0%-320.0% (Amendment-II), compared with the CK. This EC enhancement was primarily attributed to the substantial input of beneficial water-soluble ions. Among them, Ca2+ concentrations increased by 314.3%-757.1% (Amendment-I), while SO42- concentrations were 18.5 to 48.5 times those in the CK. Nutrient availability was enhanced by the synergistic mechanisms of inorganic structural improvement and organic fertility supplementation. Amendment-II shared more pronounced effects on soil organic carbon (SOC) and alkali-hydrolyzable nitrogen (AN), with the increments of 47.8%-56.0% and 17.4%-26.7%, respectively. Conversely, Amendment I enhanced 113.2%-252.0% of available phosphorus (AP) in the CK, likely due to the localized dissolution of mineral phosphates and the chelation of organic acids in the fermentation residue. Maize grain yield responded dose-dependently to amendment application. Amendment I achieved the maximum yield increment of 47.0%, thereby outperforming the 30.1% increase recorded for Amendment II. Random Forest modeling was implemented to identify soil EC, with the AN, SO42-, Ca2+, SOC, AP, AK, and Mg2+ as the most influential factors for the maize yield. The EC contributed the most, with the highest relative importance (14.6%). The input of secondary-element cations (Ca2+ and Mg2+) and anions (SO42-) also served a nutritional and stress-resilience role rather than inducing salinity stress under the nutrient-limited conditions of dryland degradation. Agronomically, yield improvements were attributed largely to hundred-grain weight (up to 24.5% increase) and ear diameter, indicating optimal source-sink dynamics during the grain filling stage. In conclusion, the optimal strategy was taken as the synergetic application of Amendment-I at a rate of 22.5 t/hm2 for soil reclamation and yield enhancement in the dryland region. While substantial short-term benefits occurred under extreme drought conditions, multi-year fixed-site monitoring was essential to evaluate the long-term environmental safety, salt accumulation kinetics, and the potential bioaccumulation of trace heavy metals. This finding can provide a scientific basis for the high-value utilization of industrial by-products in dryland agriculture.

Issue
Effects of Calcium/Aluminum-Based Amendments on Saline-Alkali Soil Quality and Sunflower Yield in the Hetao Irrigation District
Scientia Agricultura Sinica 2025, 58(20): 4231-4245
Published: 16 October 2025
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【Objective】

This study aimed to investigate the effects of calcium- and/or aluminum-based soil amendments on soil quality and sunflower yield in the Hetao Irrigation District of Inner Mongolia, China, so as to provide a theoretical support and technical guidance for the comprehensive governance of saline-alkali lands in the region.

【Method】

A two-year (2022-2023) field experiment was conducted in Ordos City, Inner Mongolia, with four treatments: control (CK), calcium-based amendment (Ca-based), aluminum-based amendment (Al-based), and calcium+aluminum-based amendment (Ca+Al-based). The experiment systematically assessed soil salinity indices and nutrient content in the 0-20 cm soil layer, as well as sunflower agronomic traits and grain yield at harvest. The soil quality index (SQI) was constructed using principal component analysis, and structural equation modeling was employed to reveal the effects of the amendments on SQI and sunflower yield.

【Result】

Compared with CK, all three soil amendments improved the SQI and sunflower yield. Among the treatments, the Ca+Al-based amendment demonstrated the most promising results, specifically reducing soil pH by 0.09-0.24 units and sodium adsorption ratio by 14.3%-24.9%, and increasing soil available phosphorus by 72.7%-147.0% and nitrate nitrogen by 0.6%-89.6%. Consequently, it increased the SQI by 51.0%-58.0% and sunflower seed yield by 30.0%-51.4% compared with CK. The Ca-based treatment was less pronounced, with SQI increasing by 36.3%-51.0% and yield increasing only in 2022 (29.3%). Notably, soil electrical conductivity increased by 16.0%-70.4% under the Ca-based and Ca+Al-based treatments, primarily due to an increase in water-soluble Ca2+, Mg2+, and SO42- concentrations, and did not lead to salt damage in plants. In addition, structural equation modeling revealed that the amendments exerted their effects by directly regulating soil salinity and nutrient indices, which indirectly increased SQI and yield. Furthermore, the contribution of soil salinity reduction to yield (79.2%) was greater than that of nutrient improvement (20.8%).

【Conclusion】

The Ca+Al-based amendment demonstrated a synergistic effect in significantly improving soil quality and sunflower yield, making it a suitable option for further application in the Hetao Irrigation District of Inner Mongolia and similar ecological regions.

Issue
Applying biochar and flue gas desulfurization gypsum in the root zone to improve saline-alkali soil quality and sunflower yield
Transactions of the Chinese Society of Agricultural Engineering 2024, 40(5): 148-157
Published: 15 March 2024
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More than two-thirds of the arable land in the Hetao Irrigation District of Inner Mongolia, China, is suffering from various soil salinization and alkalization, which has seriously restricted the local agriculture and animal husbandry economy. Among them, biochar and flue gas desulfurization (FGD) gypsum have been widely used as soil amendments in the saline-alkali soils. The amendments can often be applied on the surface and then mixed with the topsoil. However, the large investment and high cost of the traditional practice cannot fully meet the large-scale production in recent years. There is a high demand to develop more effective practices in soil amendments. In this study, a field experiment was conducted in Wuyuan County, Bayannur City, Inner Mongolia Autonomous Region, China, in order to cultivate healthy and fertile soil for less soil salinization. Three treatments were designed: 1) covering the planting holes with sand (S), 2) strip application of biochar in topsoil and then covering the planting holes with sand (B+S), and 3) strip application of biochar in topsoil and then covering the planting holes with FGD gypsum (B+G). In biochar treatments, 3750 kg biochar per hectare was buried in strips at a depth of 5-10 cm below the soil surface, and 5-10 cm away from the planting strip. In coverage treatments, the planting holes were covered completely with 750 kg sand or FGD gypsum per hectare. The soil samples were collected at a depth of 0-40 cm from the sunflower planting strip after harvest. The soil quality was then determined among the three treatments, in terms of salinity, alkalinity, organic matter, and nutrient status. Meanwhile, the sunflower yield and its components were also analyzed to deduce their relationship with soil quality. The results showed that the biochar and FGD gypsum in the root zone improved the water-soluble cations composition of the 0-40 cm soil layers, resulting in a higher Ca2+ concentration, while lower Na+ concentration after the experiment. As expected, the B+S and B+G treatments significantly decreased the sodium adsorption ratio (SAR) of the 0-40 cm soil layers and the pH value of the 20-40 cm soil layer, but increased the soil desalination rate (Ds), compared with the S treatment. In addition, the B+S and B+G treatments shared the higher contents of organic matter (OM), nitrate nitrogen (NO3--N), available phosphorus and available potassium (AK) in the 0-40 cm soil layers, indicating the better soil environment for sunflower emergence and growth. The entire dataset of soil parameters showed that the soil quality index (SQI) of B+S and B+G treatments increased by 35.7% and 88.5%, respectively, compared with the S treatment. The SQI parameters (such as SAR, Ds, Ca2+, Mg2+, AK, NO3--N and OM) achieved high scores after the B+S and B+G treatments. The reason was that the higher soil quality was obtained to reduce the salinity stress for the high nutrient levels. By contrast, the B+G treatment showed better performance than the B+S treatments, resulting in a higher seed yield of sunflower. Therefore, the combination of biochar strip application and FGD gypsum covering planting holes in saline-alkali land can be expected to intensively regulate the root zone soil, for the high soil quality and sunflower yield. The findings can also provide technical support to the amelioration and utilization of saline-alkali soils in the Hetao Irrigation District.

Issue
Advances in invention patents related to flue gas desulfurization gypsum amendments for ameliorating saline-alkali soils
Journal of Tsinghua University (Science and Technology) 2024, 64(10): 1759-1770
Published: 15 October 2024
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Objective

Saline-alkali soil is an important reserve resource of cultivated land and potential granary in China, and its management and utilization are related to national food security. Therefore, innovative techniques and amendments should be developed to address these challenges in saline-alkali regions. Among these, calcium supplementation is recognized as one of the most effective methods for ameliorating saline-alkali soil. In the past two decades, gypsum from the desulfurization of flue gas (FGDG) in coal-fired power plants has become a preferred calcium source for ameliorating saline-alkali soil because of its high calcium content and economic feasibility. Given that FGDG has developed into a soil amendment and has been widely used, a profound understanding of the progress of its patents can provide technical guidance for the large-scale amelioration of saline-alkali soil.

Methods

Based on the incoPat global patent database, a bibliometric analysis was conducted on 520 invention patents in the field of using FGDG to ameliorate saline-alkali soil from 2003 to 2022. The application and authorization trends, high-yield mechanisms, operational status, substance composition, and their correlation with patents in this field were systematically analyzed. In addition, a comparative analysis was conducted on the effectiveness of 52 patents with application cases.

Results

The results showed that the annual number of patent applications for using FGDG amendments to ameliorate saline-alkali soil has a trend of first increasing and then decreasing, with a peak period of 115 patents in 2016. Most patents take 20-30 months from publication to authorization. However, the overall proportion of authorization has shown a decreasing trend. The number of patents granted by universities and research institutes is higher than that granted by enterprises, whereas the number of patents jointly granted by universities and enterprises accounts for 15.6% of the total. A total of 37 patents were converted, 7 of which were pledged, accounting for 33.3% of the total number of grants, all of which were transferred by universities to enterprises and pledged by enterprises for financing. More than 70% of patents comprised three or more substances, primarily including organic and inorganic minerals, microbial agents, and nutrient supplements. Organic materials can directly provide nutrients for the soil to make up for the shortage of FGDG in terms of nutrients, with the frequency of application as high as 95.7%, followed by inorganic minerals, which account for 44.5%; microbial agents, which account for 41.3%; and nutrient supplements, which account for 21.3%. Compared with soils with or without other types of amendments, the application of FGDG amendments significantly decreased soil pH, exchangeable sodium percentage, and salt ions that are toxic to crop growth and increased soil Ca2+, SO42-, and total/available nitrogen and phosphorus contents, which provided a better soil environment, thereby increasing crop yield.

Conclusions

Generally, research and development on FGDG amendments for saline-alkali soil amelioration have matured, and some innovative achievements have been transformed into real productivity; thus, the value of related patents has been increasingly highlighted. However, problems such as the relatively simple composition of current patents, unclear technical requirements for the amount of application and method, and serious homogeneity of patents have been encountered. In the future, we should strengthen the cooperation among schools, enterprises, universities, and research institutes, intensify research on the FGDG formula used in saline-alkali soil, and enhance the application benefits of FGDG amendments.

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