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Recent advances in carbon dioxide capture and utilization with amines and ionic liquids
Green Chemical Engineering 2020, 1(1): 16-32
Published: 21 September 2020
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Global warming and climate change due to anthropogenic carbon dioxide (CO2) have aroused significant concerns at the global scale due to rapid economic growth in industries and other fields. Therefore, CO2 capture, use, and storage have become particularly important. In this review, general background and methods for CO2 capture and separation, in particular, on ionic liquids (ILs)-based solvents and materials, are discussed. Comprehensive surveys of ILs for CO2 absorption are presented, which focused mainly on experimental researches, and then the concept is extended to functionalized absorbents and recent developments for CO2 capture. Major advantages and disadvantages of amines-based and ILs-based absorbents are discussed in this review. Solutions of traditional amines (MEA, MDEA, DEA, AMP, PZ, etc.) and ILs (conventional ILs, functionalized ILs, etc.) are summarized. Moreover, research progresses on CO2 separation are also introduced focusing mainly on amines and ILs-based membranes (e.g. supported amines membranes, SILMs). Futhermore, the fixation of CO2 into cyclic carbonates catalyzed by ILs (pure ILs, complex catalyst system with ILs, supported ILs, etc.) is summarized, clearly explaining the mechanism of CO2 fixation with ILs. Finally, exploration of some recent studies about CO2 capture and conversion by ILs and challenges for further progress are presented and related suggestions are put forward.

Issue
Preparation and Characterization of Polymeric Micelles from Poly(D, L-lactide) and Methoxypolyethylene Glycol Block Copolymers as Potential Drug Carriers
Tsinghua Science and Technology 2007, 12(4): 493-496
Published: 01 August 2007
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Amphiphilic diblock copolymers composed of methoxy polyethylene glycol (MePEG) and poly(D,L-lactide) (PDLLA) were prepared for the preparation of polymeric micelles. The use of MePEG-PDLLA as drug carriers has been reported in the open literature, but there are only few data on the application of a series of MePEG-PDLLA copolymers with different lengths in the medical field. The shape of the polymeric micelles is also important in drug delivery. Studies on in vitro drug release profiles require a good sink condition. The critical micelle concentration of a series of MePEG-PDLLA has a significant role in drug release. To estimate their feasibility as a drug carrier, polymeric micelles made of MePEG-PDLLA block copolymer were prepared by the oil in water (O/W) emulsion method. From dynamic light scattering (DLS) measurements, the size of the micelle formed was less than 200 nm. The critical micelle concentration of polymeric micelles with various compositions was determined using pyrene as a fluorescence probe. The critical micelle concentration decreased with increasing number of hydrophobic segments. MePEG-PDLLA micelles have a considerably low critical micelle concentration (0.4-0.5 µg/mL), which is apparently an advantage in utilizing these micelles as drug carriers. The morphology of the polymeric micelles was observed using scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The micelles were found to be nearly spherical. The yield of the polymeric micelles obtained from the O/W method is as high as 85%.

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