Sort:
Review Article Issue
Strain engineering in electrocatalysis: Strategies, characterization, and insights
Nano Research 2024, 17 (5): 3603-3621
Published: 05 February 2024
Downloads:68

Strain engineering, as a cutting-edge method for modulating the electronic structure of catalysts, plays a crucial role in regulating the interaction between the catalytic surface and the adsorbed molecules. The electrocatalytic performance is influenced by the electronic structure, which can be achieved by introducing the external forces or stresses to adjust interatomic spacing between surface atoms. The challenges in strain engineering research lie in accurately understanding the mechanical impact of strain on performance. This paper first introduces the basic strategy for generating the strain, summarizes the different strain generation forms and their advantages and disadvantages. The progress in researching the characterization means for the lattice strains and their applications in the field of electrocatalysis is also emphasized. Finally, the challenges of strain engineering are introduced, and an outlook on the future research directions is provided.

Open Access Research Article Issue
Surface microstructure-controlled ZrO2 for highly sensitive room-temperature NO2 sensors
Nano Materials Science 2021, 3 (3): 268-275
Published: 06 March 2021
Downloads:6

The high sensitivity of room-temperature gas sensors is the key to innovation in the areas of environment, energy conservation and safety. However, metal-oxide-based sensors generally operate at high temperatures. Herein, we designed three ZrO2-based sensors and explored their NO2 sensing properties at room temperature. ZrO2 with three different morphologies and microstructure were synthesized by simple hydrothermal methods. The microstructures of sensing materials are expected to significantly affect gas sensing properties. The rod-shaped ZrO2 (ZrO2-R) displayed the advantages such as higher crystallinity, larger pore size, narrower band gap and more chemisorbed adsorbed oxygen, compared to hollow sphere-shaped ZrO2 (ZrO2-HS), stellate-shaped ZrO2 (ZrO2–S). The ZrO2-R sensor showed the highest response towards 30 ​ppm NO2 (423.8%) at room temperature, and a quite high sensitivity of 198.0% for detecting 5 ​ppm NO2. Although ZrO2-HS and ZrO2–S sensors exhibited lower response towards 30 ​ppm NO2 (232.9% and 245.1%), the response time and recovery time of these two sensors are 5 ​s/19 ​s and 4 ​s/3 ​s, respectively. This work can provide a new strategy for the development of room-temperature metal-oxide-based sensors.

total 2