Wearable electronics devices face dual challenges of thermal failure and electromagnetic interference (EMI). While phase change materials (PCMs) offer efficient thermal management material, their inherent limitations-low thermal conductivity, rigidity, and limited electromagnetic loss hinder practical applications. Flexible composite PCMs (FCPCMs) with multifunctional integration present a promising solution. Herein, mimicking the lamellar “brick-and-mortar” architecture of natural nacre, a flexible phase-change composite film featuring a multidimensional hierarchical encapsulation structure is ingeniously engineered for synchronous thermal management and microwave absorption. This bioinspired design incorporates polyethylene glycol (PEG) within a robust scaffold of one-dimensional (1D) aramid nanofibers (ANFs), zero-dimensional (0D) nanodiamonds (NDs), and two-dimensional (2D) single-layer graphene (SG), bonded by waterborne polyurethane (WPU). The resulting nacre-mimetic, multidimensional architecture ensures exceptional encapsulation of PEG, effectively suppressing leakage while maintaining high phase-change cycling stability (> 300 cycles). The optimized composite achieves synergistic performance: enhances thermal conductivity (1.13 W/(m·K)), strong microwave absorption performance (−41.36 dB), high phase-change enthalpy (104 J/g), and mechanical performance (tensile strength: 15.10 MPa). This work provides a platform for next-generation smart thermal-regulation systems and anti-interference electronics.

High-entropy ceramics have exhibited promising application prospects in aerospace, electronic devices, and extreme environment protection. Current powder sintering routes for preparing high-entropy ceramics are hindered by stringent powder requirements, reliance on long-term high-temperature and high-pressure synthesis, as well as compositional inhomogeneity and coarse grains. In this work, the low-temperature glass crystallization method was innovatively introduced into the preparation of high-entropy ceramics. Using garnet-structured rare-earth aluminates (RE₃Al₅O₁₂, RE is rare-earth elements) as a model system, a series of single-phase RE₃Al₅O₁₂ ceramics with entropy gradients were successfully synthesized through the glass crystallization method at a low temperature (1000 ℃). Notably, the as-prepared (Eu_0.2Gd_0.2Y_0.2Yb_0.2Lu_0.2)₃Al₅O₁₂ (HEC) samples exhibited a low thermal conductivity of 3.58 W m⁻¹ K⁻¹ (at 300 K) and a high thermal expansion coefficient (TEC) of 10.85 × 10⁻⁶ K⁻¹, representing a 21% reduction in thermal conductivity and a 32% increase in TEC compared to reported Yb₃Al₅O₁₂ ceramics. The HEC samples also exhibited superior mechanical properties compared to most existing high-entropy ceramics, with a hardness of 22.08 GPa and a Young’s modulus of 311.6 GPa. The exceptional comprehensive properties of the HEC samples make them a promising candidate material for thermal barrier coatings (TBCs) and high-temperature structural applications. This investigation confirms that high-entropy ceramics with outstanding properties can be successfully prepared using a glass crystallization method, providing a novel strategy for the low-temperature and pressureless controllable synthesis of single-phase high-entropy ceramics.

Ce doped Lu₃Al₅O₁₂ (Ce:LuAG) transparent ceramics are considered as promising color converters for solid-state lighting because of their excellent luminous efficiency, high thermal quenching temperature, and good thermal stability. However, Ce:LuAG ceramics mainly emit green light. The shortage of red light as well as the expensive price of Lu compounds are hindering their application for white lighting. In this work, transparent (Lu,Gd)₃Al₅O₁₂–Al₂O₃ (LuGAG–Al₂O₃) nanoceramics with different replacing contents of Gd³⁺ (10%–50%) were successfully elaborated via a glass-crystallization method. The obtained ceramics with full nanoscale grains are composed of the main LuGAG crystalline phase and secondary Al₂O₃ phase, exhibiting eminent transparency of 81.0%@780 nm. After doping by Ce³⁺, the Ce:LuGAG–Al₂O₃ nanoceramics show a significant red shift (510 nm→550 nm) and make up for the deficiency of red light component in the emission spectrum. The Ce:LuAG–Al₂O₃ nanoceramics with 20% Gd³⁺ show high internal quantum efficiency (81.5% in internal quantum efficiency (IQE), 96.7% of Ce:LuAG–Al₂O₃ nanoceramics) and good thermal stability (only 9% loss in IQE at 150 ℃). When combined with blue LED chips (10 W), 0.3%Ce:LuGAG–Al₂O₃ nanoceramics with 20% Gd³⁺ successfully realize the high-quality warm white LED lighting with a color coordinate of (0.3566, 0.435), a color temperature of 4347 K, CRI of 67.7, and a luminous efficiency of 175.8 lm·W⁻¹. When the transparent 0.3%Ce:LuGAG–Al₂O₃ nanoceramics are excited by blue laser (5 W·mm⁻²), the emission peak position redshifts from 517 to 570 nm, the emitted light exhibits a continuous change from green light to yellow light, and then to orange-yellow light, and the maximum luminous efficiency is up to 234.49 lm·W⁻¹ (20% Gd³⁺). Taking into account the high quantum efficiency, good thermal stability, and excellent and adjustable luminous properties, the transparent Ce:LuGAG–Al₂O₃ nanoceramics with different Gd³⁺ substitution contents in this paper are believed to be promising candidates for high-power white LED/LD lighting.

Transparent Ce:lutetium aluminum garnet (Ce:Lu₃Al₅O₁₂, Ce:LuAG) ceramics have been regarded as potential scintillator materials due to their relatively high density and atomic number (Z_eff). However, the current Ce:LuAG ceramics exhibit a light yield much lower than the expected theoretical value due to the inevitable presence of Lu_Al antisite defects at high sintering temperatures. This work demonstrates a low-temperature (1100 ℃) synthetic strategy for elaborating transparent LuAG–Al₂O₃ nanoceramics through the crystallization of 72 mol% Al₂O₃–28 mol% Lu₂O₃ (ALu28) bulk glass. The biphasic nanostructure composed of LuAG and Al₂O₃ nanocrystals makes up the whole ceramic materials. Most of Al₂O₃ is distributed among LuAG grains, and the rest is present inside the LuAG grains. Fully dense biphasic LuAG–Al₂O₃ nanoceramics are highly transparent from the visible region to mid-infrared (MIR) region, and particularly the transmittance reaches 82% at 780 nm. Moreover, Lu_Al antisite defect-related centers are completely undetectable in X-ray excited luminescence (XEL) spectra of Ce:LuAG–Al₂O₃ nanoceramics with 0.3–1.0 at% Ce. The light yield of 0.3 at% Ce:LuAG–Al₂O₃ nanoceramics is estimated to be 20,000 ph/MeV with short 1 μs shaping time, which is far superior to that of commercial Bi₄Ge₃O₁₂ (BGO) single crystals. These results show that a low-temperature glass crystallization route provides an alternative approach for eliminating the antisite defects in LuAG-based ceramics, and is promising to produce garnet-based ceramic materials with excellent properties, thereby meeting the demands of advanced scintillation applications.