Sintering process directly affects the microstructure and properties of ceramics. BaTiO3 piezoelectric ceramic was sintered by an ultrafast-high temperature sintering method. The result was compared with that of BaTiO3 sintered by a conventional furnace sintering method. The effect of sintering current on the phase composition, microstructure and property of BaTiO3 sintered in ultrafast-high temperature sintering method was investigated. Ultrafast-high temperature sintering suppresses the grain growth. After ultrafast sintering at 180 A for 5 min, the superior property with the dielectric constant of 3450, dielectric loss of 1.89% and piezoelectric constant 283 pC·N–1 is obtained. The whole sintering time is reduced by 196 times, indicating that ultrafast-high temperature sintering is a promising densification method for functional materials.
- Article type
- Year
- Co-author
Open Access
Research Article
Issue
Simultaneously employing light and vibration energy by piezoelectric material to realize environmental remediation is an advanced oxidation method. Silver niobate (AgNbO3) is a visible light driven photocatalyst for the removal of organic pollutants. However, the high recombination rate of photo-generated electrons and holes suppresses its photocatalytic activity. Piezoelectric potential excited by vibration can facilitate the separation of light induced charges. Unfortunately, AgNbO3 is an antiferroelectric. In this work, distinct photo-/vibration-bi-catalysis has been achieved in ferroelectric (1−x)AgNbO3–xLiTaO3 solid solution. The results show that ~96% Rhodamine B (RhB) can be decomposed under the bi-excitation of ultrasound and visible light within 120 min with 0.95AgNbO3–0.05LiTaO3 catalyst. The synergy effect from efficient visible light excitation and enhanced separation of the photo-induced charges from the electric field by the mechanical strain results in the distinct decomposition performance of catalysts.
京公网安备11010802044758号