Hypersonic vehicles are subjected to critical aerodynamic heating during flight, which poses a substantial challenge for the design of thermal protection systems (TPSs). Carbon-bonded carbon fiber (CBCF) composites are highly valuable materials for TPS in aerospace and military applications because of their lightweight structure and exceptional dimensional stability at elevated temperatures. However, these methods are constrained by a limited capacity for in-plane heat dissipation, which restricts their application under extreme thermal gradients. Therefore, incorporating enhanced in-plane directional heat-leading capabilities into CBCF composite designs represents a highly innovative approach that is expected to alleviate local thermal stress and achieve efficient thermal management. Herein, we propose a multifunctional design strategy involving the fabrication of SiBCN-modified carbon-bonded carbon fiber (CBCF/SiBCN) composites through the integration of high-efficiency in-plane heat conduction pathways with anisotropic thermal insulation structures. The preparation process, microscopic morphology, mechanical response and thermal performance of the CBCF/SiBCN composites were systematically investigated. The fabricated samples exhibited the compressive strength of 4.05–4.36 MPa in the in-plane direction and 1.30–1.36 MPa in the through-the-thickness direction, while maintaining the low density of 0.48–0.49 g·cm^-3. Notably, the in-plane thermal conductivity of CBCF/SiBCN reached 60.9–61.5 W·m⁻¹·K⁻¹ while remaining at 0.08 W·m⁻¹·K⁻¹ in the direction of thermal insulation, demonstrating typical anisotropy and indicating significant potential for effective thermal management. This paper introduces an innovative design that focuses on the development of in-plane directional heat-leading properties for thermally insulating composites, which potentially meet the critical requirements for thermal protection in aerospace applications.

The high-entropy rare-earth zirconate ((La_0.2Nd_0.2Sm_0.2Gd_0.2Yb_0.2)₂Zr₂O₇, 5RE₂Zr₂O₇ HE- REZs) ceramics were successfully prepared by a new high-speed positive grinding strategy combined with solid-state reaction method. The microstructure, crystal structure, phase composition, and thermophysical and mechanical properties of the samples were systematically investigated through various methods. Results indicate that the samples have a single-phase defect fluorite-type crystal structure with excellent high-temperature thermal stability. The as-prepared samples also demonstrate low thermal conductivity (0.9-1.72 W·m^-1·K^-1 at 273-1273 K) and high coefficient of thermal expansion (CTE, 10.9 × 10^-6 K^-1 at 1273 K), as well as outstanding mechanical properties including large Young’s modulus (E = 186-257 GPa) and high fracture toughness (K_IC). Furthermore, the formation possibility of the as-prepared samples was verified through the first-principles calculations, which suggested the feasibility to form the 5RE₂Zr₂O₇ HE-REZs in the thermodynamic direction. Therefore, in view of the excellent multifunctional properties exhibited by the as-prepared 5RE₂Zr₂O₇ HE-REZs, they have great potential applications in next-generation thermal-barrier coatings (TBCs).