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Review Article Issue
A comprehensive review on semiconductor-based photocatalysts toward the degradation of persistent pesticides
Nano Research 2023, 16 (5): 6402-6443
Published: 21 March 2023
Downloads:125

Pesticides refer to the chemicals to regulate plant growth and control pests used in agriculture. However, the extensive use of pesticides causes serious pollution that threatens the ecological environment and human health. Photocatalytic degradation of pesticides has become a promising way to deal with pesticide pollution. In this review, pesticides are classified according to the different targets and chemical structures. The recent developments on semiconductor-based photocatalysts including metal oxides, metal oxyhalides, carbon nitrides, and metal sulfides were reviewed for degradation of pesticides. Importantly, several modification strategies to improve the photocatalytic performance are described such as doping, heterojunction construction, and defect engineering, with special emphasis on anchoring single atom catalyst. Moreover, extensive efforts should be made to in-depth understand the photodegradation mechanism by monitoring key intermediates. Our perspectives on the key challenges and future directions of developing high-performance semiconductor-based photocatalysts for pesticide degradation are elaborated.

Review Article Issue
Modulation of morphology and electronic structure on MoS2-based electrocatalysts for water splitting
Nano Research 2022, 15 (8): 6862-6887
Published: 01 July 2022
Downloads:104

Electrocatalytic water splitting into hydrogen is one of the most favorable approaches to produce renewable energy. MoS2 has received great research attention for both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) due to its unique structure and ability to be chemically modified, enabling its electrocatalytic activity to be further enhanced or made comparable to that of Pt-based materials. In this review, we discuss the important fabrication approaches of MoS2 ultrathin nanosheet (MoS2 NS) to improve the intrinsic catalytic activity of bulk MoS2. Moreover, several modification strategies involve either morphology modulation or electron structural modulation to improve the charge transfer kinetics, including doping, vacancy, and heterojunction construction or single-atom anchor. Our perspectives on the key challenges and future directions of developing high-performance MoS2-based electrocatalysts for overall water splitting are also discussed.

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