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Effect of alcohol-treated CO2 on interfacial tension between CO2 and oil, and oil swelling
Advances in Geo-Energy Research 2021, 5(4): 407-421
Published: 29 October 2021
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This paper investigates the extent to which alcohol-treated carbon dioxide (CO2), a mixture of alcohol and CO2 equilibrated at experimental pressure and temperature, can lead to greater interfacial tension reduction and greater oil swelling than can pure CO2. Experimental measurements of interfacial tension and swelling behavior are made using a high-pressure, high-temperature visual cell at 70 °C. Two sets of fluid pairs are used: pure CO2 and oil, and alcohol-treated CO2 and oil. Two types of oil are used: a mixture of 35% hexane and 65% decane (C 6-C 10 mixture), and pure decane (pure C 10). Ethanol and methanol are used to prepare alcohol-treated CO2. Numerical simulations are used to estimate a reduction in the minimum miscibility pressure when using alcohol-treated CO2. Interfacial tension between alcohol-treated CO2 and oil is found to be 0.02 to 2.2 mN/m less than that between pure CO2 and oil. Simulation results suggest that alcohol-treated CO2 yields 0.2 to 1.2 MPa lower minimum miscibility pressure compared to pure CO2. Alcohol-treated CO2 also is found to cause 6% to 43% more swelling of oil than does pure CO2. Interfacial tension and swelling results suggest that alcohol-treated CO2 yields better miscibility with oil compared to pure CO2.

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