Several soft tissues residing in the living body have excellent hydration lubrication properties and can provide effective protection during relative motion. In order to apply this advantage of soft matters in practical applications and try to avoid its disadvantage, such as swelling and weakening in water, a design strategy of a soft/hard double network (DN) hydrogel microsphere modified ultrahigh molecular weight polyethylene (UHMWPE) composite is proposed in this study. A series of microspheres of urea-formaldehyde (UF), polyacrylamide (PAAm) hydrogel, UF/PAAm double network, and their composites were prepared. The mechanical properties, swelling, wettability, friction properties, and the lubrication mechanisms of the composites were investigated. The results show that DN microspheres can have an excellent stability and provide hydration lubrication. The performance of 75 DN-1 composite was superior to others. This finding will provide a novel strategy for the development of water-lubricated materials and have wide application in engineering fields.