Developing functional additive resistant to space atomic oxygen (AO) irradiation through simple molecular design and chemical synthesis to enhance the lubricating performance of multialkylated cyclopentanes (MACs) oil is a significant challenge. Herein, sulfur-containing polyhedral oligomere silsesquioxane (POSS) were synthesize via a click-chemistry reaction of octavinyl polyhedral oligomeric with alkyl sulfide. The reduce-friction (RF), anti-wear (AW) properties and anti-AO irradiation of POSS-S-R as MACs base oil additives in atmospheric and simulated space environments were systematically investigated for the first time. Results demonstrate that POSS-S-R not only possesses outstanding anti-AO irradiation capacity but also effectively improves the RF and AW of MACs in atmospheric or simulated space surroundings. This improvement is due to the excellent anti-AO irradiation properties of the POSS structure itself and the high load-carrying ability of silicon-containing and sulfur-containing compounds generated by tribo-chemical reactions, which effectively separates the direct contact of the friction interface. We believe that this synthesized POSS-S-R is a promising additive for space lubricants.

The polyionic liquid poly-PEGMA-r-METAC (PPM) with quaternary ammonium has been synthesized and evaluated as additive in aqueous lubricating fluids. The rheological behavior of aqueous lubricating fluids with PPM has been characterized to confirm PPM’s function as a viscosity modifier. The tribological behavior of aqueous lubricating fluids with PPM has been investigated on SRV-V and MTM testing machines. It was found that PPM has excellent viscosity-increasing, lubricating, and anti-wear properties as an additive for aqueous, which can be attributed to the ability of PPM to form the protective film and boundary tribofilm generated from complex tribochemical reaction on rubbing surface. The obtained PPM with dual functions of anti-corrosion additives and viscosity index improver can play an important role in diverse lubrication regimes.

A new type of lubricating material (BTA-P₄₄₄₄-Lig) was synthesized by combining lignin with tetrabutylphosphorus and benzotriazole. The tribological properties, corrosion resistance, and anti-oxidation properties of BTA-P₄₄₄₄-Lig as a lubricant were investigated. The lubricating material exhibits excellent friction reduction and wear resistance, as well as good thermal stability and excellent oxidation resistance. Mechanistic analysis reveals that the active elements N and P in the lubricating material react with the metal substrate, and the reaction film effectively blocks direct contact between the friction pairs, affording excellent friction reduction and wear resistance. At the same time, the phenolic hydroxyl group in lignin reacts with oxygen free radicals to form a resonance-stable semi-quinone free radical, which interrupts the chain reaction and affords good anti-oxidant activity.

In this study, the direct intercalation of gemini ionic liquids (ILs) with different alkyl chains into the bentonite (BT) interlayer as a high-performance lubricating additive for base oil 500SN was investigated. The purpose of modifying BT with an IL is to improve the dispersion stability and lubricity of BT in lubricating oil. The dispersibility and tribological properties of IL–BT as oil-based additives for 500SN depend on the increase in interlamellar space in BT and improve as the chain length is increased. More importantly, the IL–BT nanomaterial outperforms individual BT in improving wear resistance, owing to its sheet layers were deformed and sprawled in furrows along the metal surface, thereby resulting in low surface adhesion. Because of its excellent lubrication performance, IL-modified BT is a potential candidate for the main component of drilling fluid. It can be used as a lubricating additive in oil drilling and oil well construction to reduce equipment damage and ensure the normal operation of equipments.

A series of new halogen-free dicationic ionic liquids (ILs) with different alkyl chain lengths were prepared, and the relationship between the alkyl chain length, physicochemical and tribological properties of ILs, and their role as neat lubricant for steel-steel friction pairs, was investigated. Evaluation of stability during hydrolysis and copper strip corrosion test results show that synthetic ILs are stable and not corrosive to metal contacts, due to the halogen-free anions. The friction and wear test results indicate that ILs with long alkyl chains have excellent friction-reducing and anti-wear properties, especially at high temperatures. Based on the surface three-dimensional (3D) profiles, electrical contact resistance, scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), and the X-ray photoelectron spectrometry (XPS) analysis of the worn surfaces of steel discs, we can conclude that the efficiency of ILs is due to the formation of high quality tribofilms that consist of both tribochemical reaction and ordered absorption films.

In this study, the gelling ability and lubrication performance of N-octadecyl-D-gluconamides (NOG) in liquid paraffin (LP), pentaerythritol oleate (PE-OA), and polyethylene glycol (PEG) oils were systemically investigated. The NOG, which could gelate the investigated oils, was successfully synthesized by a one-step method. The prepared gel lubricants were completely thermoreversible and exhibited improved thermal stability, according to the thermogravimetry analysis (TGA) reports. Rheological tests confirmed that the NOG gelator could effectively regulate the rheological behavior of the base oils. Tribological evaluation suggested that NOG, as an additive in the three types of base oils, could remarkably reduce the friction and wear in steel contacts. A plausible mechanism for the improved performances was proposed based on the mechanical strength of the gels and the formation of the boundary-lubricating film on the worn surface. The results indicated that NOG is a potential gelator for preparing gel lubricants with excellent tribological properties and environment-friendly characteristics.

To enhance the lubricating and extreme pressure (EP) performance of base oils, two types of oil-soluble ionic liquids (ILs) with similar anion albeit dissimilar cations were synthesized. The physical properties of the prepared ILs were measured. The anticorrosion properties of ILs were assessed by conducting corrosion tests on steel discs and copper strips, which revealed the remarkable anticorrosion properties of the ILs in comparison with those of the commercial additive zinc dialkyldithiophosphate (ZDDP). The tribological properties of the two ILs as additives for poly-α-olefin-10 (PAO10) with various mass concentrations were investigated. The tribological test results indicate that these ILs as additives are capable of reducing friction and wear of sliding contacts remarkably as well as enhance the EP performance of blank PAO10. Under similar test conditions, these IL additives exhibit higher lubricating and anti-wear (AW) performances than those of ZDDP based additive package in PAO10. Subsequently, X-ray photoelectron spectroscopy (XPS) and energy dispersive spectrometer (EDS) were conducted to study the lubricating mechanism of the two ILs. The results indicate that the formation of tribochemical film plays the most crucial role in enhancing the lubricating and AW behavior of the mixture lubricants.