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Article | Open Access

Effect of stabilizer EDTA on the thermal hazard of green synthesis process of adipic acid and development of microchannel continuous flow process

Jiangsu Key Laboratory of Hazardous Chemicals Safety and Control, College of Safety Science and Engineering, Nanjing Tech University, Nanjing 210009, China
BASF Corporation, 1609 Biddle Avenue, Wyandotte, MI 48192, USA
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Abstract

In the green synthesis reaction of adipic acid, the oxidant H2O2 undergoes exothermic decomposition easily and the high exothermic amount of the reaction can easily lead to thermal runaway. This study carries out calorimetric experiments on the green synthesis reaction of adipic acid, studies the effect of the stabilizer ethylenediaminetetraacetic acid (EDTA) on the safety of the synthesis reaction, and further explores the effect of EDTA on the Na2WO4-catalyzed decomposition reaction of H2O2 under the conditions of continuous flow, and develops the microchannel continuous flow process of green synthesis of adipic acid containing EDTA, in order to provide theoretical support for the improvement of intrinsic safety of green synthesis of adipic acid.

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Emergency Management Science and Technology
Article number: 22

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Cite this article:
He W, Li Y, Ni L, et al. Effect of stabilizer EDTA on the thermal hazard of green synthesis process of adipic acid and development of microchannel continuous flow process. Emergency Management Science and Technology, 2023, 3: 22. https://doi.org/10.48130/EMST-2023-0022

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Received: 23 November 2023
Accepted: 16 December 2023
Published: 27 December 2023
© 2023 by the author(s).

This article is an open access article distributed under Creative Commons Attribution License (CC BY 4.0), visit https://creativecommons.org/licenses/by/4.0/.