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Review Article | Open Access | Just Accepted

Insights into surface plasmon-mediated chemical reactions

Li Qiu1, Yuan Zhang2,3, Haoyu Li2, Christoph Haisch4, Zhihong Nie5, Shunping Zhang6( ), Guangchao Zheng2,3 ( ), Wei Xie1( )

1 State Key Laboratory of Advanced Chemical Power Sources, Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Tianjin Key Laboratory of Biosensing and Molecular Recognition, Haihe Laboratory of Sustainable Chemical Transformations, Academy for Advanced Interdisciplinary Studies, Frontiers Science Center for New Organic Matter, College of Chemistry, Nankai University, Tianjin 300071, China

2 Colloidal Physics Group, School of Physics, Key Laboratory of Material Physics, Ministry of Education, Zhengzhou University, Zhengzhou 450001, China

3 Institute of Quantum Materials and Physics, Henan Academy of Sciences, Zhengzhou 450046 Henan, China

4 Department of Analytical Chemistry and Water Chemistry, Technical University of Munich, Lichtenbergstraße 4, 85748 Garching, Germany

5 State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University, Shanghai 200438, China

6 School of Physics and Technology and Key Laboratory of Artificial Micro- and Nano-structures of Ministry of Education, Wuhan University, Wuhan 430072, China

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Abstract

Surface plasmon-mediated chemical reactions (SPMCRs) have emerged as a rapidly developing research area within plasmonics, where localized surface plasmons enhance light-matter interactions at the nanoscale, facilitating the efficient conversion and utilization of photon energy to drive chemical processes. SPMCRs have shown great promise for driving chemical processes under significantly milder reaction conditions that are often inaccessible using conventional thermochemistry. Over the past few decades, various reactions have been extensively studied using advanced experimental and theoretical tools. However, discerning the individual contributions within SPMCRs remains challenging. The efficient utilization of SPMCRs for practical applications continues to be a daunting task. This review summarizes recent advances in SPMCRs and proposes several strategies aimed at achieving a more comprehensive understanding of the chemical reaction systems.

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Keywords

surface plasmon resonancehot electronshybrid plasmonic nanostructurereaction mechanismhot electron transfer

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Nano Research
DOI: 10.26599/NR.2025.94908283

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Cite this article:
Qiu L, Zhang Y, Li H, et al. Insights into surface plasmon-mediated chemical reactions. Nano Research, 2025, https://doi.org/10.26599/NR.2025.94908283
Topics:
NanocatalystsPhotocatalysisRaman spectroscopy

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Received: 30 September 2025
Revised: 22 November 2025
Accepted: 25 November 2025
Available online: 25 November 2025

© The Author(s) 2025. Published by Tsinghua University Press.

This is an open access article under the terms of the Creative Commons Attribution 4.0 International License (CC BY 4.0, https://creativecommons.org/licenses/by/4.0/)