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Ultralow friction polymer composites were prepared by adding oil-loaded microcapsules into epoxy (EP) resin. Mono-dispersed polystyrene (PS)/poly alpha olefin (PAO) microcapsules with a diameter of ~2 μm and a shell thickness of ~30 nm were prepared by solvent evaporation method in an oil-in-water emulsion. The lubrication behaviors of the EP resin composites with oil-loaded microcapsules have been investigated under different loads and sliding speeds. As compared with the pure EP resin, the friction coefficient of the composite could be reduced to 4% (from 0.71 to 0.028) and the wear rate could be decreased up to two orders of magnitude. It was demonstrated that the released PAO oil from the microcapsules during the friction process produced a boundary lubricating film, which could prevent the direct contact of two rubbing surfaces, and thus leading to an extremely low friction coefficient and wear rate. Moreover, the composites with microcapsules could achieve comparable lubrication properties to the case under the external lubrication condition, while the former case could effectively minimize the lubricant leakage and improve the lubrication efficiency.


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Ultralow friction polymer composites incorporated with mono-dispersed oil microcapsules

Show Author's information Lin ZHANG1Guoxin XIE1( )Shuai WU1Shiguang PENG1Xiaoqing ZHANG2Dan GUO1Shizhu WEN1Jianbin LUO1( )
State Key Laboratory of Tribology, Department of Mechanical Engineering, Tsinghua University, Beijing 100084, China
School of Materials Science and Mechanical Engineering, Beijing Technology and Business University, Beijing 100048, China

Abstract

Ultralow friction polymer composites were prepared by adding oil-loaded microcapsules into epoxy (EP) resin. Mono-dispersed polystyrene (PS)/poly alpha olefin (PAO) microcapsules with a diameter of ~2 μm and a shell thickness of ~30 nm were prepared by solvent evaporation method in an oil-in-water emulsion. The lubrication behaviors of the EP resin composites with oil-loaded microcapsules have been investigated under different loads and sliding speeds. As compared with the pure EP resin, the friction coefficient of the composite could be reduced to 4% (from 0.71 to 0.028) and the wear rate could be decreased up to two orders of magnitude. It was demonstrated that the released PAO oil from the microcapsules during the friction process produced a boundary lubricating film, which could prevent the direct contact of two rubbing surfaces, and thus leading to an extremely low friction coefficient and wear rate. Moreover, the composites with microcapsules could achieve comparable lubrication properties to the case under the external lubrication condition, while the former case could effectively minimize the lubricant leakage and improve the lubrication efficiency.

Keywords: polymer composite, microcapsules, solvent evaporation, ultralow friction, boundary lubrication

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Publication history

Received: 15 April 2019
Revised: 18 June 2019
Accepted: 01 July 2019
Published: 09 September 2019
Issue date: February 2021

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© The author(s) 2019

Acknowledgements

This work was supported by the National Natural Science Foundation of China (Grant Nos. 51822505, 51811530014, and 51605008) and Beijing Natural Science Foundation of China (Grant No. 3182010).

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