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Research Article | Open Access

Electric modulation of conduction in MAPbBr3 single crystals

Shanming KEaShangyu LUOaJinhui GONGaLiwen QIUaRenhong LIANGaYangbo ZHOUaBingcheng LUOa,bBaochang CHENGaLi WANGa( )Longlong SHUa( )
School of Materials Science and Engineering, Nanchang University, Nanchang 330031, China
State Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi’an 710072, China
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Abstract

The resistive switching (RS) mechanism of hybrid organic-inorganic perovskites has not been clearly understood until now. A switchable diode-like RS behavior in MAPbBr3 single crystals using Au (or Pt) symmetric electrodes is reported. Both the high resistance state (HRS) and low resistance state (LRS) are electrode-area dependent and light responsive. We propose an electric-field-driven inner p-n junction accompanied by a trap-controlled space-charge-limited conduction (SCLC) conduction mechanism to explain this switchable diode-like RS behavior in MAPbBr3 single crystals.

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Journal of Advanced Ceramics
Pages 320-327
Cite this article:
KE S, LUO S, GONG J, et al. Electric modulation of conduction in MAPbBr3 single crystals. Journal of Advanced Ceramics, 2021, 10(2): 320-327. https://doi.org/10.1007/s40145-020-0442-1

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Received: 27 August 2020
Revised: 24 November 2020
Accepted: 27 November 2020
Published: 24 February 2021
© The Author(s) 2020

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