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Research Article | Open Access

Electric modulation of conduction in MAPbBr3 single crystals

Shanming KEaShangyu LUOaJinhui GONGaLiwen QIUaRenhong LIANGaYangbo ZHOUaBingcheng LUOa,bBaochang CHENGaLi WANGa( )Longlong SHUa( )
School of Materials Science and Engineering, Nanchang University, Nanchang 330031, China
State Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi’an 710072, China
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The resistive switching (RS) mechanism of hybrid organic-inorganic perovskites has not been clearly understood until now. A switchable diode-like RS behavior in MAPbBr3 single crystals using Au (or Pt) symmetric electrodes is reported. Both the high resistance state (HRS) and low resistance state (LRS) are electrode-area dependent and light responsive. We propose an electric-field-driven inner p-n junction accompanied by a trap-controlled space-charge-limited conduction (SCLC) conduction mechanism to explain this switchable diode-like RS behavior in MAPbBr3 single crystals.

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C Huang, P Lin, NQ Fu, et al. Facile fabrication of highly efficient ETL-free perovskite solar cells with 20% efficiency by defect passivation and interface engineering. Chem Commun 2019, 55: 2777-2780.
H Kim, JS Han, J Choi, et al. Halide perovskites for applications beyond photovoltaics. Small Methods 2018, 2: 1700310.
H Kim, KA Huynh, SY Kim, et al. 2D and quasi-2D halide perovskites: Applications and progress. Phys Status Solidi-R 2020, 14: 1900435.
HM Zhu, YP Fu, F Meng, et al. Lead halide perovskite nanowire lasers with low lasing thresholds and high quality factors. Nat Mater 2015, 14: 636-642.
MZ Long, TK Zhang, Y Chai, et al. Nonstoichiometric acid-base reaction as reliable synthetic route to highly stable CH3NH3PbI3 perovskite film. Nat Commun 2016, 7: 13503.
Y Rakita, O Bar-Elli, E Meirzadeh, et al. Tetragonal CH3NH3PbI3 is ferroelectric. Proc Natl Acad Sci USA 2017, 114: E5504-E5512.
HJ Snaith, A Abate, JM Ball, et al. Anomalous hysteresis in perovskite solar cells. J Phys Chem Lett 2014, 5: 1511-1515.
JM Azpiroz, E Mosconi, J Bisquert, et al. Defect migration in methylammonium lead iodide and its role in perovskite solar cell operation. Energy Environ Sci 2015, 8: 2118-2127.
EJ Yoo, MQ Lyu, JH Yun, et al. Resistive switching behavior in organic-inorganic hybrid CH3NH3PbI3-xClx perovskite for resistive random access memory devices. Adv Mater 2015, 27: 6170-6175.
XW Guan, WJ Hu, MA Haque, et al. Light-responsive ion-redistribution-induced resistive switching in hybrid perovskite Schottky junctions. Adv Funct Mater 2018, 28: 1704665.
C Gu, JS Lee. Flexible hybrid organic-inorganic perovskite memory. ACS Nano 2016, 10: 5413-5418.
J Choi, S Park, J Lee, et al. Organolead halide perovskites for low operating voltage multilevel resistive switching. Adv Mater 2016, 28: 6562-6567.
B Hwang, JS Lee. Metal halide perovskites: A strategy to design high-density nanoscale devices utilizing vapor deposition of metal halide perovskite materials. Adv Mater 2017, 29: 1701048.
J Choi, QV Le, K Hong, et al. Enhanced endurance organolead halide perovskite resistive switching memories operable under an extremely low bending radius. ACS Appl Mater Interfaces 2017, 9: 30764-30771.
E Yoo, MQ Lyu, JH Yun, et al. Bifunctional resistive switching behavior in an organolead halide perovskite based Ag/CH3NH3PbI3-xClx/FTO structure. J Mater Chem C 2016, 4: 7824-7830.
FC Zhou, YH Liu, XP Shen, et al. Low-voltage, optoelectronic CH3NH3PbI3-xClx memory with integrated sensing and logic operations. Adv Funct Mater 2018, 28: 1800080.
JJ Tian, HJ Wu, Z Fan, et al. Nanoscale topotactic phase transformation in SrFeOx epitaxial thin films for high-density resistive switching memory. Adv Mater 2019, 31: 1903679.
H Kim, JS Han, SG Kim, et al. Halide perovskites for resistive random-access memories. J Mater Chem C 2019, 7: 5226-5234.
Z Hong, J Zhao, SJ Li, et al. Tunable hysteresis behaviour related to trap filling dependence of surface barrier in an individual CH3NH3PbI3 micro/nanowire. Nanoscale 2019, 11: 3360-3369.
H Kim, MJ Choi, JM Suh, et al. Quasi-2D halide perovskites for resistive switching devices with ON/OFF ratios above 109. NPG Asia Mater 2020, 12: 21.
S Lee, H Kim, DH Kim, et al. Tailored 2D/3D halide perovskite heterointerface for substantially enhanced endurance in conducting bridge resistive switching memory. ACS Appl Mater Interfaces 2020, 12: 17039-17045.
D Shi, V Adinolfi, R Comin, et al. Low trap-state density and long carrier diffusion in organolead trihalide perovskite single crystals. Science 2015, 347: 519-522.
Y Liu, Z Yang, D Cui, et al. Two-inch-sized perovskite CH3NH3PbX3 (X = Cl, Br, I) crystals: growth and characterization. Adv Mater 2015, 27: 5176-5183.
HH Fang, S Adjokatse, HT Wei, et al. Ultrahigh sensitivity of methylammonium lead tribromide perovskite single crystals to environmental gases. Sci Adv 2016, 2: e1600534.
J Tian, Z Tan, Z Fan, et al. Depolarization-field-induced retention loss in ferroelectric diodes. Phys Rev Appl 2019, 11: 024058.
ZG Xiao, YB Yuan, YC Shao, et al. Giant switchable photovoltaic effect in organometal trihalide perovskite devices. Nat Mater 2015, 14: 193-198.
MA Lampert, P Mark. Current Injection in Solids. New York, USA: Academic Press, 1970.
OS Game, GJ Buchsbaum, YY Zhou, et al. Ions matter: Description of the anomalous electronic behavior in methylammonium lead halide perovskite devices. Adv Funct Mater 2017, 27: 1606584.
YB Yuan, J Chae, YC Shao, et al. Photovoltaic switching mechanism in lateral structure hybrid perovskite solar cells. Adv Energy Mater 2015, 5: 1500615.
S Bagdzevicius, K Maas, M Boudard, et al. Interface-type resistive switching in perovskite materials. J Electroceram 2017, 39: 157-184.
MI Saidaminov, V Adinolfi, R Comin, et al. Planar-integrated single-crystalline perovskite photodetectors. Nat Commun 2015, 6: 8724.
ZP Lian, QF Yan, TT Gao, et al. Perovskite CH3NH3PbI3(Cl) single crystals: Rapid solution growth, unparalleled crystalline quality, and low trap density toward 108 cm-3. J Am Chem Soc 2016, 138: 9409-9412.
Z Xiong, W Hu, Y She, et al. Air-stable lead-free perovskite thin film based on CsBi3I10 and its application in resistive switching devices. ACS Appl Mater Interfaces 2019, 11: 30037-30044.
Journal of Advanced Ceramics
Pages 320-327
Cite this article:
KE S, LUO S, GONG J, et al. Electric modulation of conduction in MAPbBr3 single crystals. Journal of Advanced Ceramics, 2021, 10(2): 320-327.








Web of Science






Received: 27 August 2020
Revised: 24 November 2020
Accepted: 27 November 2020
Published: 24 February 2021
© The Author(s) 2020

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