Electrical properties of Na2Pb2R2W2Ti4V4O30 (R = Dy, Pr) ceramics

Piyush R. DAS; B. N. PARIDA; R. PADHEE; R. N. P. CHOUDHARY

doi:10.1007/s40145-013-0048-y

Journal of Advanced Ceramics 2013, 2(2): 112-118 https://doi.org/10.1007/s40145-013-0048-y

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Open Access | Issue | Published: 04 June 2013

Electrical properties of Na₂Pb₂R₂W₂Ti₄V₄O₃₀ (R = Dy, Pr) ceramics

Show Author's Information Hide Author's Information Piyush R. DAS^{^*}(

), B. N. PARIDA, R. PADHEE, R. N. P. CHOUDHARY

Department of Physics, Institute of Technical Education & Research, Siksha ‘O’ Anusandahan University, Khandagiri, Bhubaneswar 751030, Odisha, India

Keywords:

microstructure, electrical properties, ferroelectricity, ceramics, impedance spectroscopy

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DAS PR, PARIDA BN, PADHEE R, et al. Electrical properties of Na₂Pb₂R₂W₂Ti₄V₄O₃₀ (R = Dy, Pr) ceramics. Journal of Advanced Ceramics, 2013, 2(2): 112-118. https://doi.org/10.1007/s40145-013-0048-y

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The polycrystalline samples of complex tungsten bronze (TB) Na₂Pb₂R₂W₂Ti₄V₄O₃₀ (R=Dy, Pr) compounds were prepared by solid-state reaction technique. Room- temperature preliminary structural studies confirm the formation of the compounds in the orthorhombic crystal system. Detailed studies of electrical properties of the materials using complex impedance spectroscopy technique exhibit that the impedance and related parameters are strongly dependent upon temperature and microstructure (bulk, grain boundary, etc). An observation of negative temperature coefficient of resistance (NTCR) suggests the materials have semiconducting properties. The variation of AC conductivity with temperature shows a typical Arrhenius behavior of the materials. Both the samples obey Jonscher’s universal power law. The existence of hopping mechanism in the electrical transport processes in the system with non-exponential type of conductivity relaxation is confirmed by electrical modulus analysis.

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Electrical properties of Na₂Pb₂R₂W₂Ti₄V₄O₃₀ (R = Dy, Pr) ceramics

Show Author's information Hide Author's Information Piyush R. DAS^{^*}(

), B. N. PARIDA, R. PADHEE, R. N. P. CHOUDHARY

Department of Physics, Institute of Technical Education & Research, Siksha ‘O’ Anusandahan University, Khandagiri, Bhubaneswar 751030, Odisha, India

Abstract

Keywords: microstructure, electrical properties, ferroelectricity, ceramics, impedance spectroscopy

References(27)

[1]

Singh AK, Choudhary RNP. Study of ferroelectric phase transition in Pb₃R₃Ti₅Nb₅O₃₀ (R = rare earth ion) ceramics. Ferroelectrics 2005, 325: 7–14.

DOI Google Scholar

[2]

Kim MS, Lee JH, Kim JJ, et al. Microstructure evolution and dielectric properties of Ba₅_-xNa_2xNb₁₀O₃₀ ceramics with different Ba–Na ratios. J Solid State Electr 2006, 10: 18–23.

DOI Google Scholar

[3]

Fang L, Zhang H, Huang TH, et al. Preparation, structural, and dielectric properties of Ba₅YZnM₉O₃₀ (M = Nb, Ta) ceramics. J Mater Sci 2005, 40: 533–535.

DOI Google Scholar

[4]

Behera B, Nayak P, Choudhary RNP. Structural, dielectric and electrical properties of NaBa₂X₅O₁₅ (X = Nb and Ta) ceramics. Mater Lett 2005, 59: 3489–3493.

DOI Google Scholar

[5]

Hornebecq V, Elissalde C, Reau JM, et al. Relaxations in new ferroelectric tantalates with tetragonal tungsten bronze structure. Ferroelectrics 2000, 238: 57–63.

DOI Google Scholar

[6]

Ganguly P, Jha AK, Deori KL. Complex impedance studies of tungsten–bronze structured Ba₅SmTi₃Nb₇O₃₀ ferroelectric ceramics. Solid State Commun 2008, 146: 472–477.

DOI Google Scholar

[7]

Neurgaonkar RR, Nelson JG, Oliver JR, et al. Ferroelectric and structural properties of the tungsten bronze system K₂Ln³⁺Nb₅O₁₅, Ln = La to Lu. Mater Res Bull 1990, 25: 959–970.

DOI Google Scholar

[8]

Fang L, Zhang H, Yang JF, et al. Preparation, characterization and dielectric properties of Ba₅LnZnTa₉O₃₀ (Ln = La, Sm) ceramics. Matet Res Bull 2004, 39: 677–682.

DOI Google Scholar

[9]

Qu YQ, Li AD, Shao QY, et al. Structure and electrical properties of strontium barium niobate ceramics. Mater Res Bull 2002, 37: 503–513.

DOI Google Scholar

[10]

Das PR, Biswal L, Behera B, et al. Structural and electrical properties of Na₂Pb₂Eu₂W₂Ti₄X₄O₃₀ (X = Nb, Ta) ferroelectric ceramics. Mater Res Bull 2009, 44: 1214–1218.

DOI Google Scholar

[11]

Das PR, Choudhary RNP, Samantray BK. Diffuse ferroelectric phase transition in Na₂Pb₂Sm₂W₂Ti₄Nb₄O₃₀ ceramics. Mater Chem Phys 2007, 101: 228–233.

DOI Google Scholar

[12]

Das PR, Choudhary RNP, Samantray BK. Diffuse ferroelectric phase transition in Na₂Pb₂Nd₂W₂Ti₄Nb₄O₃₀ ceramic. J Alloys Compd 2008, 448: 32–37.

DOI Google Scholar

[13]

Das PR, Choudhary RNP, Samantray BK. Diffuse phase transition in Na₂Pb₂R₂W₂Ti₄V₄O₃₀ (R = Gd, Eu) ferroelectric ceramics. J Phys Chem Solids 2007, 68: 516–522.

DOI Google Scholar

[14]

Das PR, Behera B, Choudhary RNP, et al. Ferroelectric properties of Na₂Pb₂R₂W₂Ti₄V₄O₃₀ (R = Dy, Pr) ceramics. Res Lett Mater Sci 2007, Article ID: 91796.

Google Scholar

[15]

Wu E. POWDMULT—An interactive powder diffraction data interpretation and indexing program, Version 2.5. Bedford Park, Australia: School of Physical Science, Finders University of South Australia.

[16]

Plocharski J, Wieczoreck W. PEO based composite solid electrolyte containing nasicon. Solid State Ionics 1988, 28–30: 979–982.

DOI Google Scholar

[17]

Behera B, Nayak P, Choudhary RNP. Structural and impedance properties of KBa₂V₅O₁₅ ceramics. Mater Res Bull 2008, 43: 401–410.

DOI Google Scholar

[18]

Jonscher AK. The ‘universal’ dielectric response. Nature 1977, 267: 673–679.

DOI Google Scholar

[19]

Suman CK, Prasad K, Choudhary RNP. Complex impedance studies on tungsten–bronze electroceramic: Pb₂Bi₃LaTi₅O₁₈. J Mater Sci 2006, 41: 369–375.

DOI Google Scholar

[20]

Sen S, Choudhary RNP, Pramanik P. Structural and electrical properties of Ca²⁺-modified PZT electroceramics. Physica B 2007, 387: 56–62.

DOI Google Scholar

[21]

Behera B, Nayak P, Choudhary RNP. Impedance spectroscopy study of NaBa₂V₅O₁₅ ceramic. J Alloys Compd 2007, 436: 226–232.

DOI Google Scholar

[22]

Das PS, Chakraborty PK, Behera B, et al. Electrical properties of Li₂BiV₅O₁₅ ceramics. Physica B 2007, 395: 98–103.

DOI Google Scholar

[23]

Sinclair DC, West AR. Impedance and modulus spectroscopy of semiconducting BaTiO₃ showing positive temperature coefficient of resistance. J Appl Phys 1989, 66: 3850–3856.

DOI Google Scholar

[24]

Hodge IM, Ingram MD, West AR. A new method for analysing the a.c. behaviour of polycrystalline solid electrolyte. J Electroanal Chem Interfacial Electroch 1975, 58: 429–432.

DOI Google Scholar

[25]

Saha S, Sihna TP. Low-temperature scaling behavior of BaFe_0.5Nb_0.5O₃. Phys Rev B 2002, 65: 134103.

Google Scholar

[26]

Jonscher AK. Universal Relaxation Law. London: Chelsea Dielectrics Press, 1996.

[27]

Funke K. Jump relaxation in solid electrolytes. Prog Solid State Ch 1993, 22: 111–195.

DOI Google Scholar

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Publication history

Received: 11 January 2013

Revised: 06 February 2013

Accepted: 16 February 2013

Published: 04 June 2013

Issue date: June 2013

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Open Access: This article is distributed under the terms of the Creative Commons Attribution Noncommercial License which permits any noncommercial use, distribution, and reproduction in any medium, provided the original author(s) and source are credited.