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Electrolytes with high-efficiency lithium-ion transfer and reliable safety are of great importance for lithium battery. Although having superior ionic conductivity (10−3–10−2 S·cm−1), traditional liquid-state electrolytes always suffer from low lithium-ion transference number (
The authors would like to acknowledge financial support from National Natural Science Foundation of China (No. U2004199), Joint Foundation for Science and Technology Research & Development Plan of Henan Province (Nos. 222301420003 and 232301420038), China Postdoctoral Science Foundation (No. 2022TQ0293), and Key Science and Technology Project of Henan Province (No. 221100240200-06). Center for advanced analysis and computational science, Zhengzhou University is also highly acknowledged.