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Nano Research 2024, 17(6): 5224-5232 https://doi.org/10.1007/s12274-024-6472-1
Research Article | Issue | Published: 01 February 2024

Rational cathode configuration with bilayer membranes to engineer current-collector-free high-areal-sulfur lithium-sulfur batteries

Show Author's Information Jianmei Han1( ),  Hua Zhang2,  Peng Wang2,  Ning Song2,  Xuguang An3,  Baojuan Xi2,  Shenglin Xiong2( )
College of Chemistry and Chemical Engineering, Taishan University, Tai’an 271021, China
Key Laboratory of the Colloid and Interface Chemistry, Ministry of Education, and School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China
School of Mechanical Engineering, Chengdu University, Chengdu 610106, China
Keywords:
lithium-sulfur batteries, core–shell, light-weight self-made current collector, high-areal-sulfur
Topics:
Lithium sulfur batteries
Cite this article:
Han J, Zhang H, Wang P, et al. Rational cathode configuration with bilayer membranes to engineer current-collector-free high-areal-sulfur lithium-sulfur batteries. Nano Research, 2024, 17(6): 5224-5232. https://doi.org/10.1007/s12274-024-6472-1
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Abstract Full text Electronic supplementary material About this article

The application of light-weight current collectors is preferred because of the increased energy density of the batteries. Bearing it in mind, the cathode is designed with self-made paperlike memberane as current collector coupled with another interlayer to enable the high-energy-density lithium-sulfur batteries. Via a facile and green step-by-step methodology, the hybrid membrane is finalized successfully, consisting of reduced graphene oxide sheets covering paper-derived carbon (GPC) bearing Fe@Fe2O3 and Fe1−xS@Fe2O3 core–shell nanoparticles (FeFeO/FeSFeO@GPC). The film works as the current collector and interlayer simultaneously considering the porous and conductive features. As demonstrated by the electrochemical testing, the FeFeO/FeSFeO@GPC hybrid cell exhibits attractive cycling stability and superior rate capability. The cell configuration and structural/composition merits of FeFeO/FeSFeO@GPC film facilitate the faster reaction kinetics, conducive to the improvement of capacity retention. In view of the effective cathode design, the areal sulfur loading is increased to 10.46 mg·cm−2 and a reversible capacity of 6.67 mAh·cm−2 can be retained after 60 cycles at 0.1 C.


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Abstract
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Electronic supplementary material
About this article

Rational cathode configuration with bilayer membranes to engineer current-collector-free high-areal-sulfur lithium-sulfur batteries

Show Author's information Jianmei Han1( ), Hua Zhang2, Peng Wang2, Ning Song2, Xuguang An3, Baojuan Xi2, Shenglin Xiong2( )
College of Chemistry and Chemical Engineering, Taishan University, Tai’an 271021, China
Key Laboratory of the Colloid and Interface Chemistry, Ministry of Education, and School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China
School of Mechanical Engineering, Chengdu University, Chengdu 610106, China

Abstract

The application of light-weight current collectors is preferred because of the increased energy density of the batteries. Bearing it in mind, the cathode is designed with self-made paperlike memberane as current collector coupled with another interlayer to enable the high-energy-density lithium-sulfur batteries. Via a facile and green step-by-step methodology, the hybrid membrane is finalized successfully, consisting of reduced graphene oxide sheets covering paper-derived carbon (GPC) bearing Fe@Fe2O3 and Fe1−xS@Fe2O3 core–shell nanoparticles (FeFeO/FeSFeO@GPC). The film works as the current collector and interlayer simultaneously considering the porous and conductive features. As demonstrated by the electrochemical testing, the FeFeO/FeSFeO@GPC hybrid cell exhibits attractive cycling stability and superior rate capability. The cell configuration and structural/composition merits of FeFeO/FeSFeO@GPC film facilitate the faster reaction kinetics, conducive to the improvement of capacity retention. In view of the effective cathode design, the areal sulfur loading is increased to 10.46 mg·cm−2 and a reversible capacity of 6.67 mAh·cm−2 can be retained after 60 cycles at 0.1 C.

Keywords: lithium-sulfur batteries, core–shell, light-weight self-made current collector, high-areal-sulfur

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Publication history
Copyright
Acknowledgements

Publication history

Received: 05 December 2023
Revised: 02 January 2024
Accepted: 03 January 2024
Published: 01 February 2024
Issue date: June 2024

Copyright

© Tsinghua University Press 2024

Acknowledgements

Acknowledgements

The authors gratefully acknowledge the financial supports provided by the National Natural Science Foundation of China (No. U1764258), the Taishan Scholar Project Foundation of Shandong Province (No. ts20190908), and the Natural Science Foundation of Shandong Province (No. ZR2021ZD05).

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