AI Chat Paper
Note: Please note that the following content is generated by AMiner AI. SciOpen does not take any responsibility related to this content.
{{lang === 'zh_CN' ? '文章概述' : 'Summary'}}
{{lang === 'en_US' ? '中' : 'Eng'}}
Chat more with AI
Powered by AMiner. Clicking this button will take you away from SciOpen.
Home Nano Research Article
PDF (14.4 MB)
Cite
EndNote(RIS) BibTeX
Collect
Submit Manuscript AI Chat Paper
Show Outline
Outline
Show full outline
Hide outline
Outline
Show full outline
Hide outline
Research Article | Open Access

Anomalies in the short-range local environment and atomic diffusion in single crystalline equiatomic CrMnFeCoNi high-entropy alloy

Alevtina Smekhova1( ), Daniel Gaertner2, Alexei Kuzmin3, Ana Guilherme Buzanich4, Goetz Schuck1, Ivo Zizak1, Gerhard Wilde2, Kirill V. Yusenko4, Sergiy Divinski2( )
Helmholtz-Zentrum Berlin für Materialien und Energie (HZB), D-12489 Berlin, Germany
Institute of Materials Physics, University of Münster, D-48149 Münster, Germany
Institute of Solid State Physics, University of Latvia, LV-1063 Riga, Latvia
Bundesanstalt für Materialforschung und – prüfung (BAM), D-12489 Berlin, Germany
Show Author Information

Graphical Abstract

The advanced structural characterization of the single crystalline equiatomic CrMnFeCoNi high-entropy alloy has been performed using multi-edge X-ray absorption spectroscopy combined with reverse Monte Carlo simulations as a function of the annealing temperature. The revealed anomalies in the local environment of specific principal components at the atomic scale correlate with the observed changes in the relative diffusivities of the constituents.

Abstract

Multi-edge extended X-ray absorption fine structure (EXAFS) spectroscopy combined with reverse Monte Carlo (RMC) simulations was used to probe the details of element-specific local coordinations and component-dependent structure relaxations in single crystalline equiatomic CrMnFeCoNi high-entropy alloy as a function of the annealing temperature. Two representative states, namely a high-temperature state, created by annealing at 1373 K, and a low-temperature state, produced by long-term annealing at 993 K, were compared in detail. Specific features identified in atomic configurations of particular principal components indicate variations in the local environment distortions connected to different degrees of compositional disorder at the chosen representative temperatures. The detected changes provide new atomistic insights and correlate with the existence of kinks previously observed in the Arrhenius dependencies of component diffusion rates in the CrMnFeCoNi high-entropy alloy.

Keywords

diffusionhigh-entropy alloysreverse Monte Carloextended X-ray absorption fine structure (EXAFS)short-range order

References

[1]

Cantor, B.; Chang, I. T. H.; Knight, P.; Vincent, A. J. B. Microstructural development in equiatomic multicomponent alloys. Mater. Sci. Eng. A 2004, 375–377, 213–218
Crossref Google Scholar
[2]

Yeh, J. W.; Chen, S. K.; Lin, S. J.; Gan, J. Y.; Chin, T. S.; Shun, T. T.; Tsau, C. H.; Chang, S. Y. Nanostructured high-entropy alloys with multiple principal elements: Novel alloy design concepts and outcomes. Adv. Eng. Mater. 2004, 6, 299–303.
Crossref Google Scholar
[3]

Kao, Y. F.; Chen, S. K.; Sheu, J. H.; Lin, J. T.; Lin, W. E.; Yeh, J. W.; Lin, S. J.; Liou, T. H.; Wang, C. W. Hydrogen storage properties of multi-principal-component CoFeMnTi x V y Zr z alloys. Int. J. Hyd. Energy 2010, 35, 9046–9059.
Crossref Google Scholar
[4]

Zaddach, A. J.; Niu, C.; Koch, C. C.; Irving, D. L. Mechanical properties and stacking fault energies of NiFeCrCoMn high-entropy alloy. JOM 2013, 65, 1780–1789.
Crossref Google Scholar
[5]

Gludovatz, B.; Hohenwarter, A.; Catoor, D.; Chang, E. H.; George, E. P.; Ritchie, R. O. A fracture-resistant high-entropy alloy for cryogenic applications. Science 2014, 345, 1153–1158.
Crossref Google Scholar
[6]

Schuh, B.; Mendez-Martin, F.; Völker, B.; George, E. P.; Clemens, H.; Pippan, R.; Hohenwarter, A. Mechanical properties, microstructure and thermal stability of a nanocrystalline CoCrFeMnNi high-entropy alloy after severe plastic deformation. Acta Mater. 2015, 96, 258–268.
Crossref Google Scholar
[7]

Huang, S.; Li, W.; Lu, S.; Tian, F. Y.; Shen, J.; Holmström, E.; Vitos, L. Temperature dependent stacking fault energy of FeCrCoNiMn high entropy alloy. Scr. Mater. 2015, 108, 44–47.
Crossref Google Scholar
[8]

Varvenne, C.; Luque, A.; Curtin, W. A. Theory of strengthening in fcc high entropy alloys. Acta Mater. 2016, 118, 164–176.
Crossref Google Scholar
[9]

Sahlberg, M.; Karlsson, D.; Zlotea, C.; Jansson, U. Superior hydrogen storage in high entropy alloys. Sci. Rep. 2016, 6, 36770.
Crossref Google Scholar
[10]

Wang, B. F.; Fu, A.; Huang, X. X.; Liu, B.; Liu, Y.; Li, Z. Z.; Zan, X. Mechanical properties and microstructure of the CoCrFeMnNi high entropy alloy under high strain rate compression. J. Mater. Eng. Perform. 2016, 25, 2985–2992.
Crossref Google Scholar
[11]

Zhang, Y. W.; Zhao, S. J.; Weber, W. J.; Nordlund, K.; Granberg, F.; Djurabekova, F. Atomic-level heterogeneity and defect dynamics in concentrated solid-solution alloys. Curr. Opin. Solid State Mater. Sci. 2017, 21, 221–237.
Crossref Google Scholar
[12]

Ahmad, A. S.; Su, Y.; Liu, S. Y.; Ståhl, K.; Wu, Y. D.; Hui, X. D.; Ruett, U.; Gutowski, O.; Glazyrin, K.; Liermann, H. P. et al. Structural stability of high entropy alloys under pressure and temperature. J. Appl. Phys. 2017, 121, 235901.
Crossref Google Scholar
[13]

Luo, H.; Li, Z. M.; Mingers, A. M.; Raabe, D. Corrosion behavior of an equiatomic CoCrFeMnNi high-entropy alloy compared with 304 stainless steel in sulfuric acid solution. Corros. Sci. 2018, 134, 131–139.
Crossref Google Scholar
[14]

Shi, Y. Z.; Collins, L.; Feng, R.; Zhang, C.; Balke, N.; Liaw, P. K.; Yang, B. Homogenization of Al x CoCrFeNi high-entropy alloys with improved corrosion resistance. Corros. Sci. 2018, 133, 120–131.
Crossref Google Scholar
[15]

Löffler, T.; Meyer, H.; Savan, A.; Wilde, P.; Garzón Manjón, A.; Chen, Y. T.; Ventosa, E.; Scheu, C.; Ludwig, A.; Schuhmann, W. Discovery of a multinary noble metal-free oxygen reduction catalyst. Adv. Energy Mater. 2018, 8, 1802269.
Crossref Google Scholar
[16]

Kong, K.; Hyun, J.; Kim, Y.; Kim, W.; Kim, D. Nanoporous structure synthesized by selective phase dissolution of AlCoCrFeNi high entropy alloy and its electrochemical properties as supercapacitor electrode. J. Power Sources 2019, 437, 226927.
Crossref Google Scholar
[17]

Xu, X.; Du, Y. K.; Wang, C. H.; Guo, Y.; Zou, J. W.; Zhou, K.; Zeng, Z.; Liu, Y. Y.; Li, L. Q. High-entropy alloy nanoparticles on aligned electronspun carbon nanofibers for supercapacitors. J. Alloys Compd. 2020, 822, 153642.
Crossref Google Scholar
[18]

Fang, G.; Gao, J. J.; Lv, J.; Jia, H. L.; Li, H. L.; Liu, W. H.; Xie, G. Q.; Chen, Z. H.; Huang, Y.; Yuan, Q. H. et al. Multi-component nanoporous alloy/(oxy)hydroxide for bifunctional oxygen electrocatalysis and rechargeable Zn-air batteries. Appl. Catal. B: Environ. 2020, 268, 118431.
Crossref Google Scholar
[19]

Pedersen, J. K.; Batchelor, T. A. A.; Bagger, A.; Rossmeisl, J. High-entropy alloys as catalysts for the CO2 and CO reduction reactions. ACS Catal. 2020, 10, 2169–2176.
Crossref Google Scholar
[20]

Yao, Y. G.; Huang, Z. N.; Li, T. Y.; Wang, H.; Liu, Y. F.; Stein, H. S.; Mao, Y. M.; Gao, J. L.; Jiao, M. L.; Dong, Q. et al. High-throughput, combinatorial synthesis of multimetallic nanoclusters. Proc. Natl. Acad. Sci. USA 2020, 117, 6316–6322.
Crossref Google Scholar
[21]

Pickering, E. J.; Carruthers, A. W.; Barron, P. J.; Middleburgh, S. C.; Armstrong, D. E. J.; Gandy, A. S. High-entropy alloys for advanced nuclear applications. Entropy 2021, 23, 98.
Crossref Google Scholar
[22]

Zhu, M.; Zhao, B. Z.; Yuan, Y. F.; Guo, S. Y.; Wei, G. Y. Study on corrosion behavior and mechanism of CoCrFeMnNi HEA interfered by AC current in simulated alkaline soil environment. J. Electroanal. Chem. 2021, 882, 115026.
Crossref Google Scholar
[23]

Ma, Y. J.; Ma, Y.; Wang, Q. S.; Schweidler, S.; Botros, M.; Fu, T. T.; Hahn, H.; Brezesinski, T.; Breitung, B. High-entropy energy materials: Challenges and new opportunities. Energy Environ. Sci. 2021, 14, 2883–2905.
Crossref Google Scholar
[24]

Guo, S.; Ng, C.; Lu, J.; Liu, C. T. Effect of valence electron concentration on stability of fcc or bcc phase in high entropy alloys. J. Appl. Phys. 2011, 109, 103505.
Crossref Google Scholar
[25]

Čižek, L.; Kratochvíl, P.; Smola, B. Solid solution hardening of copper crystals. J. Mater. Sci. 1974, 9, 1517–1520.
Crossref Google Scholar
[26]

Gypen, L. A.; Deruyttere, A. Multi-component solid solution hardening. J. Mater. Sci. 1977, 12, 1028–1033.
Crossref Google Scholar
[27]

Ma, D. C.; Grabowski, B.; Körmann, F.; Neugebauer, J.; Raabe, D. Ab initio thermodynamics of the CoCrFeMnNi high entropy alloy: Importance of entropy contributions beyond the configurational one. Acta Mater. 2015, 100, 90–97
Crossref Google Scholar
[28]

Okamoto, N. L.; Yuge, K.; Tanaka, K.; Inui, H.; George, E. P. Atomic displacement in the CrMnFeCoNi high-entropy alloy-A scaling factor to predict solid solution strengthening. AIP Adv. 2016, 6, 125008.
Crossref Google Scholar
[29]
Tong, Y.; Velisa, G.; Yang, T.; Jin, K.; Lu, C.; Bei, H.; Ko, J. Y. P.; Pagan, D. C.; Huang, R.; Zhang, Y. et al. Probing local lattice distortion in medium- and high-entropy alloys. 2017, arXiv: 1707.07745. arXiv.org e-Print archive. https://doi.org/10.48550/arXiv.1707.077459 (accessed Apr 1, 2022).
[30]

Zhang, F. X.; Tong, Y.; Jin, K.; Bei, H. B.; Weber, W. J.; Huq, A.; Lanzirotti, A.; Newville, M.; Pagan, D. C.; Ko, J. Y. P. et al. Chemical complexity induced local structural distortion in NiCoFeMnCr high-entropy alloy. Mater. Res. Lett. 2018, 6, 450–455.
Crossref Google Scholar
[31]

Ding, Q. Q.; Zhang, Y.; Chen, X.; Fu, X. Q.; Chen, D. K.; Chen, S. J.; Gu, L.; Wei, F.; Bei, H. B.; Gao, Y. F. et al. Tuning element distribution, structure and properties by composition in high-entropy alloys. Nature 2019, 574, 223–227.
Crossref Google Scholar
[32]

Cantor, B. Multicomponent high-entropy Cantor alloys. Prog. Mater. Sci. 2021, 120, 100754.
Crossref Google Scholar
[33]

Oh, H. S.; Odbadrakh, K.; Ikeda, Y.; Mu, S.; Körmann, F.; Sun, C. J.; Ahn, H. S.; Yoon, K. N.; Ma, D. C.; Tasan, C. C. et al. Element-resolved local lattice distortion in complex concentrated alloys: An observable signature of electronic effects. Acta Mater. 2021, 216, 117135.
Crossref Google Scholar
[34]

Billington, D.; James, A. D. N.; Harris-Lee, E. I.; Lagos, D. A.; O’Neill, D.; Tsuda, N.; Toyoki, K.; Kotani, Y.; Nakamura, T.; Bei, H. et al. Bulk and element-specific magnetism of medium-entropy and high-entropy Cantor–Wu alloys. Phys. Rev. B 2020, 102, 174405.
Crossref Google Scholar
[35]

Smekhova, A.; Kuzmin, A.; Siemensmeyer, K.; Luo, C.; Chen, K.; Radu, F.; Weschke, E.; Reinholz, U.; Buzanich, A. G.; Yusenko, K. V. Al-driven peculiarities of local coordination and magnetic properties in single-phase Al x -CrFeCoNi high-entropy alloys. Nano Res. 2022, 15, 4845–4858.
Crossref Google Scholar
[36]

Smekhova, A.; Kuzmin, A.; Siemensmeyer, K.; Luo, C.; Taylor, J.; Thakur, S.; Radu, F.; Weschke, E.; Buzanich, A. G.; Xiao, B. et al. Local structure and magnetic properties of a nanocrystalline Mn-rich Cantor alloy thin film down to the atomic scale. Nano Res. 2023, 16, 5626–5639.
Crossref Google Scholar
[37]

Oh, H. S.; Ma, D. C.; Leyson, G. P.; Grabowski, B.; Park, E. S.; Körmann, F.; Raabe, D. Lattice distortions in the FeCoNiCrMn high entropy alloy studied by theory and experiment. Entropy 2016, 18, 321.
Crossref Google Scholar
[38]

Smekhova, A.; Kuzmin, A.; Siemensmeyer, K.; Abrudan, R.; Reinholz, U.; Buzanich, A. G.; Schneider, M.; Laplanche, G.; Yusenko, K. V. Inner relaxations in equiatomic single-phase high-entropy Cantor alloy. J. Alloys Compd. 2022, 920, 165999.
Crossref Google Scholar
[39]

Wilson, J. A.; Moore, C.; Goddard, D. T.; Middleburgh, S. C. Assessing the high concentration of vacancies in refractory high entropy alloys. Materialia 2023, 28, 101764.
Crossref Google Scholar
[40]

Zhang, R. P.; Zhao, S. T.; Ding, J.; Chong, Y.; Jia, T.; Ophus, C.; Asta, M.; Ritchie, R. O.; Minor, A. M. Short-range order and its impact on the CrCoNi medium-entropy alloy. Nature 2020, 581, 283–287.
Crossref Google Scholar
[41]

He, Q. F.; Tang, P. H.; Chen, H. A.; Lan, S.; Wang, J. G.; Luan, J. H.; Du, M.; Liu, Y.; Liu, C. T.; Pao, C. W. et al. Understanding chemical short-range ordering/demixing coupled with lattice distortion in solid solution high entropy alloys. Acta Mater. 2021, 216, 117140.
Crossref Google Scholar
[42]

Bracq, G.; Laurent-Brocq, M.; Perrière, L.; Pirès, R.; Joubert, J. M.; Guillot, I. The fcc solid solution stability in the Co-Cr-Fe-Mn-Ni multi-component system. Acta Mater. 2017, 128, 327–336.
Crossref Google Scholar
[43]

Otto, F.; Dlouhý, A.; Pradeep, K. G.; Kuběnová, M.; Raabe, D.; Eggeler, G.; George, E. P. Decomposition of the single-phase high-entropy alloy CrMnFeCoNi after prolonged anneals at intermediate temperatures. Acta Mater. 2016, 112, 40–52.
Crossref Google Scholar
[44]

Tsai, K. Y.; Tsai, M. H.; Yeh, J. W. Sluggish diffusion in Co-Cr-Fe-Mn-Ni high-entropy alloys. Acta Mater. 2013, 61, 4887–4897.
Crossref Google Scholar
[45]

Dash, A.; Paul, A.; Sen, S.; Divinski, S.; Kundin, J.; Steinbach, I.; Grabowski, B.; Zhang, X. Recent advances in understanding diffusion in multiprincipal element systems. Ann. Rev. Mater. Res. 2022, 52, 383–409.
Crossref Google Scholar
[46]

Vaidya, M.; Trubel, S.; Murty, B. S.; Wilde, G.; Divinski, S. V. Ni tracer diffusion in CoCrFeNi and CoCrFeMnNi high entropy alloys. J. Alloys Compd. 2016, 688, 994–1001.
Crossref Google Scholar
[47]

Vaidya, M.; Pradeep, K. G.; Murty, B. S.; Wilde, G.; Divinski, S. V. Bulk tracer diffusion in CoCrFeNi and CoCrFeMnNi high entropy alloys. Acta Mater. 2018, 146, 211–224.
Crossref Google Scholar
[48]

Chen, W. M.; Zhang, L. J. High-throughput determination of interdiffusion coefficients for Co-Cr-Fe-Mn-Ni high-entropy alloys. J. Phase Equilib. Diffus. 2017, 38, 457–465.
Crossref Google Scholar
[49]

Kottke, J.; Utt, D.; Laurent-Brocq, M.; Fareed, A.; Gaertner, D.; Perrière, L.; Rogal, Ł.; Stukowski, A.; Albe, K.; Divinski, S. V. et al. Experimental and theoretical study of tracer diffusion in a series of (CoCrFeMn)100− x Ni x alloys. Acta Mater. 2020, 194, 236–248.
Crossref Google Scholar
[50]

Zhang, J. F.; Gadelmeier, C.; Sen, S.; Wang, R.; Zhang, X.; Zhong, Y.; Glatzel, U.; Grabowski, B.; Wilde, G.; Divinski, S. V. Zr diffusion in BCC refractory high entropy alloys: A case of ‘non-sluggish’ diffusion behavior. Acta Mater. 2022, 233, 117970.
Crossref Google Scholar
[51]

Sen, S.; Zhang, X.; Rogal, L.; Wilde, G.; Grabowski, B.; Divinski, S. V. “Anti-sluggish” Ti diffusion in HCP high-entropy alloys: Chemical complexity vs. lattice distortions. Scr. Mater. 2023, 224, 115117
Crossref Google Scholar
[52]

Zhang, F.; Zhang, C.; Chen, S. L.; Zhu, J.; Cao, W. S.; Kattner, U. R. An understanding of high entropy alloys from phase diagram calculations. Calphad 2014, 45, 1–10.
Crossref Google Scholar
[53]
Paul, A.; Laurila, T.; Vuorinen, V.; Divinski, S. V. Thermodynamics, Diffusion and the Kirkendall Effect in Solids; Springer: Cham, 2014.
[54]

Beke, D. L.; Erdélyi, G. On the diffusion in high-entropy alloys. Mater. Lett. 2016, 164, 111–113.
Crossref Google Scholar
[55]

Kucza, W.; Dąbrowa, J.; Cieślak, G.; Berent, K.; Kulik, T.; Danielewski, M. Studies of “sluggish diffusion” effect in Co-Cr-Fe-Mn-Ni, Co-Cr-Fe-Ni and Co-Fe-Mn-Ni high entropy alloys; determination of tracer diffusivities by combinatorial approach. J. Alloys Compd. 2018, 731, 920–928.
Crossref Google Scholar
[56]

Gaertner, D.; Kottke, J.; Wilde, G.; Divinski, S. V.; Chumlyakov, Y. Tracer diffusion in single crystalline CoCrFeNi and CoCrFeMnNi high entropy alloys. J. Mater. Res. 2018, 33, 3184–3191.
Crossref Google Scholar
[57]

Gaertner, D.; Kottke, J.; Chumlyakov, Y.; Hergemöller, F.; Wilde, G.; Divinski, S. V. Tracer diffusion in single crystalline CoCrFeNi and CoCrFeMnNi high-entropy alloys: Kinetic hints towards a low-temperature phase instability of the solid-solution. Scr. Mater. 2020, 187, 57–62.
Crossref Google Scholar
[58]

Dąbrowa, J.; Danielewski, M. State-of-the-Art diffusion studies in the high entropy alloys. Metals 2020, 10, 347.
Crossref Google Scholar
[59]

Ma, S. G.; Zhang, S. F.; Gao, M. C.; Liaw, P. K.; Zhang, Y. A successful synthesis of the CoCrFeNiAl0.3 single-crystal, high-entropy alloy by Bridgman solidification. JOM 2013, 65, 1751–1758.
Crossref Google Scholar
[60]

Ma, S. G.; Zhang, S. F.; Qiao, J. W.; Wang, Z. H.; Gao, M. C.; Jiao, Z. M.; Yang, H. J.; Zhang, Y. Superior high tensile elongation of a single-crystal CoCrFeNiAl0.3 high-entropy alloy by Bridgman solidification. Intermetallics 2014, 54, 104–109.
Crossref Google Scholar
[61]

Patriarca, L.; Ojha, A.; Sehitoglu, H.; Chumlyakov, Y. I. Slip nucleation in single crystal FeNiCoCrMn high entropy alloy. Scr. Mater. 2016, 112, 54–57.
Crossref Google Scholar
[62]

Abuzaid, W.; Sehitoglu, H. Critical resolved shear stress for slip and twin nucleation in single crystalline FeNiCoCrMn high entropy alloy. Mater. Charact. 2017, 129, 288–299.
Crossref Google Scholar
[63]

Moon, J.; Jang, M. J.; Bae, J. W.; Yim, D.; Park, J. M.; Lee, J.; Kim, H. S. Mechanical behavior and solid solution strengthening model for face-centered cubic single crystalline and polycrystalline high-entropy alloys. Intermetallics 2018, 98, 89–94.
Crossref Google Scholar
[64]

Feuerbacher, M.; Würtz, E.; Kovács, A.; Thomas, C. Single-crystal growth of a FeCoCrMnAl high-entropy alloy. Mater. Res. Lett. 2017, 5, 128–134.
Crossref Google Scholar
[65]

Chen, H. Q.; Yuan, X. T.; Ren, W. L.; Peng, J. C.; Ding, B.; Zheng, T. X.; Yu, J. B.; Liaw, P. K.; Zhong, Y. B. A new single crystal high entropy alloy with excellent high-temperature tensile property. Mater. Res. Express 2020, 7, 046507.
Crossref Google Scholar
[66]

Liu, C. J.; Gadelmeier, C.; Lu, S. L.; Yeh, J. W.; Yen, H. W.; Gorsse, S.; Glatzel, U.; Yeh, A. C. Tensile creep behavior of HfNbTaTiZr refractory high entropy alloy at elevated temperatures. Acta Mater. 2022, 237, 118188.
Crossref Google Scholar
[67]

Xiao, W. C.; Liu, S. F.; Zhao, Y. L.; Kai, J. J.; Liu, X. J.; Yang, T. A novel single-crystal L12-strengthened Co-rich high-entropy alloy with excellent high-temperature strength and antioxidant property. J. Mater. Res. Technol. 2023, 23, 2343–2350.
Crossref Google Scholar
[68]

Gärtner, D.; Belkacemi, L.; Esin, V. A.; Jomard, F.; Fedotov, A. A.; Schell, J.; Osinskaya, Y. V.; Pokoev, A. V.; Duhamel, C.; Paul, A. et al. Techniques of tracer diffusion measurements in metals, alloys and compounds. Diffus. Found. 2021, 29, 31–73.
Crossref Google Scholar
[69]
Mehrer, H. Diffusion in Solids: Fundamentals, Methods, Materials, Diffusion-Controlled Processes; Springer: Berlin, 2007.
[70]

Riesemeier, H.; Ecker, K.; Görner, W.; Müller, B. R.; Radtke, M.; Krumrey, M. Layout and first XRF applications of the BAMline at BESSY II. X-Ray Spectrom. 2005, 34, 160–163.
Crossref Google Scholar
[71]

Buzanich, A. G.; Radtke, M.; Yusenko, K. V.; Stawski, T.; Kulow, A.; Cakir, C. T.; Röder, B.; Naese, C.; Britzke, R.; Sintschuk, M. et al. BAMline—A real-life sample materials research beamline. J. Chem. Phys. 2023, 158, 244202.
Crossref Google Scholar
[72]

Lutz, C.; Hampel, S.; Ke, X.; Beuermann, S.; Turek, T.; Kunz, U.; Guilherme Buzanich, A.; Radtke, M.; Fittschen, U. E. A. Evidence for redox reactions during vanadium crossover inside the nanoscopic water-body of Nafion 117 using X-ray absorption near edge structure spectroscopy. J. Power Sources 2021, 483, 229176.
Crossref Google Scholar
[73]

Schuck, G.; Zisak, I. CryoEXAFS: X-ray absorption spectroscopy station with cryogenic or in-beam operando electrochemistry sample conditions at BESSY II. J. Large-Scale Res Facil. 2020, 6, A139.
Crossref Google Scholar
[74]

Zizak, I.; Gaal, P. The KMC-3 XPP beamline at BESSY II. J. Large-Scale Res Facil. 2017, 3, A123.
Crossref Google Scholar
[75]

Kuzmin, A.; Chaboy, J. EXAFS and XANES analysis of oxides at the nanoscale. IUCrJ 2014, 1, 571–589.
Crossref Google Scholar
[76]
XAESA. xaesa v0.06; GitHub: 2022 [Online]. https://github.com/aklnk/xaesa (accessed Mar 1, 2022).
[77]

Timoshenko, J.; Kuzmin, A. Wavelet data analysis of EXAFS spectra. Comput. Phys. Commun. 2009, 180, 920–925.
Crossref Google Scholar
[78]

Timoshenko, J.; Kuzmin, A.; Purans, J. Reverse Monte Carlo modeling of thermal disorder in crystalline materials from EXAFS spectra. Comput. Phys. Commun. 2012, 183, 1237–1245.
Crossref Google Scholar
[79]

Timoshenko, J.; Kuzmin, A.; Purans, J. EXAFS study of hydrogen intercalation into ReO3 using the evolutionary algorithm. J. Phys. Condens. Matter 2014, 26, 055401.
Crossref Google Scholar
[80]

Ankudinov, A. L.; Ravel, B.; Rehr, J. J.; Conradson, S. D. Real-space multiple-scattering calculation and interpretation of X-ray-absorption near-edge structure. Phys. Rev. B 1998, 58, 7565–7576.
Crossref Google Scholar
[81]

Rehr, J. J.; Albers, R. C. Theoretical approaches to X-ray absorption fine structure. Rev. Mod. Phys. 2000, 72, 621–654.
Crossref Google Scholar
[82]

Li, K. M.; Fu, C. C.; Nastar, M.; Soisson, F. Predicting atomic diffusion in concentrated magnetic alloys: The case of paramagnetic Fe-Ni. Phys. Rev. B 2023, 107, 094103.
Crossref Google Scholar
[83]

Cowley, J. M. An approximate theory of order in alloys. Phys. Rev. 1950, 77, 669–675.
Crossref Google Scholar
[84]

Cowley, J. M. Short-range order and long-range order parameters. Phys. Rev. 1965, 138, A1384–A1389.
Crossref Google Scholar
[85]

Sugita, K.; Matsuoka, N.; Mizuno, M.; Araki, H. Vacancy formation enthalpy in CoCrFeMnNi high-entropy alloy. Scr. Mater. 2020, 176, 32–35.
Crossref Google Scholar
[86]

Huang, E. W.; Chou, H. S.; Tu, K. N.; Hung, W. S.; Lam, T. N.; Tsai, C. W.; Chiang, C. Y.; Lin, B. H.; Yeh, A. C.; Chang, S. H. et al. Element effects on high-entropy alloy vacancy and heterogeneous lattice distortion subjected to quasi-equilibrium heating. Sci. Rep. 2019, 9, 14788.
Crossref Google Scholar
[87]
Ravel, B. The Athena: A User’s Guide. https://bruceravel.github.io/demeter/aug/ (accessed Jun 1, 2023).
[88]

Hobbs, D.; Hafner, J.; Spišák, D. Understanding the complex metallic element Mn. I. Crystalline and noncollinear magnetic structure of α-Mn. Phys. Rev. B 2003, 68, 014407.
Crossref Google Scholar
[89]

Oh, H. S.; Kim, S. J.; Odbadrakh, K.; Ryu, W. H.; Yoon, K. N.; Mu, S.; Körmann, F.; Ikeda, Y.; Tasan, C. C.; Raabe, D. et al. Engineering atomic-level complexity in high-entropy and complex concentrated alloys. Nat. Commun. 2019, 10, 2090.
Crossref Google Scholar
[90]

Li, Q.; Chen, W. M.; Zhong, J.; Zhang, L. J.; Chen, Q.; Liu, Z. K. On sluggish diffusion in Fcc Al-Co-Cr-Fe-Ni high-entropy alloys: An experimental and numerical study. Metals 2018, 8, 16.
Crossref Google Scholar
[91]

Jin, K.; Zhang, C.; Zhang, F.; Bei, H. B. Influence of compositional complexity on interdiffusion in Ni-containing concentrated solid-solution alloys. Mater. Res. Lett. 2018, 6, 293–299.
Crossref Google Scholar
[92]

Park, N.; Lee, B. J.; Tsuji, N. The phase stability of equiatomic CoCrFeMnNi high-entropy alloy: Comparison between experiment and calculation results. J. Alloys Compd. 2017, 719, 189–193.
Crossref Google Scholar
[93]

Ikeda, Y.; Grabowski, B.; Körmann, F. Ab initio phase stabilities and mechanical properties of multicomponent alloys: A comprehensive review for high entropy alloys and compositionally complex alloys. Mater. Charact. 2019, 147, 464–511
Crossref Google Scholar
Nano Research
Volume 17 Issue 6,
June 2024
Pages 5336-5348
DOI: 10.1007/s12274-024-6443-6
Cite this article:
Smekhova A, Gaertner D, Kuzmin A, et al. Anomalies in the short-range local environment and atomic diffusion in single crystalline equiatomic CrMnFeCoNi high-entropy alloy. Nano Research, 2024, 17(6): 5336-5348. https://doi.org/10.1007/s12274-024-6443-6
Topics:
AlloyingAlloying elementsComputation theory Crystal atomic structureMicrostructureSingle crystalsTransition metalsX-ray absorptionX-ray absorption spectroscopyX-ray crystallographyX-ray diffractionX-rays

913

Views

157

Downloads

1

Crossref

1

Web of Science

1

Scopus

0

CSCD

Altmetrics
Received: 27 September 2023
Revised: 27 November 2023
Accepted: 22 December 2023
Published: 27 February 2024
© The Author(s) 2024

Copyright: © 2023 by the author(s). This article is an open access article distributed under Creative Commons Attribution License (CC BY 4.0), visit https://creativecommons.org/licenses/by/4.0/.
Return