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Research Article

Mn-based MXene with high lithium-ion storage capacity

Yanyan Wu1,2,3, Dongqing Liu4, Xiaonan Wang1,2, Usman Ghani3, Muhammad Asim Mushtaq3, Jinfeng Yang1,2, Huarui Sun1,2( ), Panagiotis Tsiakaras5, Xingke Cai3( )
School of Science and Ministry of Industry and Information Technology Key Laboratory of Micro-Nano Optoelectronic Information System, Harbin Institute of Technology Shenzhen, Shenzhen 518055
China Collaborative Innovation Center of Extreme Optics, Shanxi University, Taiyuan 030006, China
Institute for Advanced Study, Shenzhen University, Shenzhen 518060, China
College of Mechatronics and Control Engineering, Shenzhen University, Shenzhen 518060, China
Laboratory of Alternative Energy Conversion Systems, Department of Mechanical Engineering, School of Engineering, University of Thessaly, Pedion Areos 38834, Greece
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Graphical Abstract

Herein, we synthesized the first 3d-transition metal-based MXene, d-Mn2CTx by exfoliating the layered precursor derived from anti-perovskite bulk Mn3GaC. The prepared MXene nanosheets were employed as anode materials in lithium-ion batteries and showed a stable storage capacity of 764.7 mAh·g−1 at 0.5 C, which was much higher than that of other reported MXene materials and even other Mn-based anode materials.

Abstract

3d-transition metal (Fe, Co, Ni, and Mn)-based MXene materials have been predicted to demonstrate exceptional electrochemical performance because of their good electrical conductivity and the presence of metallic atoms with multiple charge states. However, until now, there have been no reports on MXenes based on Fe, Co, Ni, and Mn, due to the lack of 3d-metal-layered precursors. Herein, we successfully synthesized the first 3d-transition metal-based MXenes, Mn2CTx by exfoliating a layered precursor derived from the anti-perovskite bulk Mn3GaC. The as-prepared Mn2CTx MXene nanosheets were employed as anode materials in lithium-ion batteries, which exhibited stable storage capacity of 764.7 mAh·g−1 at 0.5 C, placing its storage capacities at an upper-middle level compared with other reported MXene materials as well as other Mn-based anode materials. Overall, this study opens a new avenue for MXene research by synthesizing 3d-transition metal-based MXenes for electrochemical applications.

Keywords

MXeneslithium-ion batteryanode materialsMn3GaCnegative fading capacityMn2CTx

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Nano Research
Volume 17 Issue 5,
May 2024
Pages 4181-4191
DOI: 10.1007/s12274-023-6360-0
Cite this article:
Wu Y, Liu D, Wang X, et al. Mn-based MXene with high lithium-ion storage capacity. Nano Research, 2024, 17(5): 4181-4191. https://doi.org/10.1007/s12274-023-6360-0
Topics:
EtchingLithium batteriesNanosheets

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Received: 06 August 2023
Revised: 15 November 2023
Accepted: 22 November 2023
Published: 29 December 2023
© Tsinghua University Press 2023
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