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Nano Research 2024, 17(3): 2050-2060 https://doi.org/10.1007/s12274-023-6216-7
Research Article | Issue | Published: 18 November 2023

Polymorphic cerium-based Prussian blue derivatives with in situ growing CNT/Co heterojunctions for enhanced microwave absorption via polarization and magnetization

Show Author's Information Jixi Zhou1,§,  Xinmeng Huang1,§,  Di Lan2,  Yuhang Cheng1,  Fengyi Xue1,  Chenyu Jia1,  Guanglei Wu1( ),  Zirui Jia1,3( )
Institute of Materials for Energy and Environment, State Key Laboratory of Bio-fibers and Eco-textiles, College of Materials Science and Engineering, Qingdao University, Qingdao 266071, China
School of Materials Science and Engineering, Hubei University of Automotive Technology, Shiyan 442002, China
College of Chemistry and Chemical Engineering, Qingdao University, Qingdao 266071, China

§ Jixi Zhou and Xinmeng Huang contributed equally to this work.

Keywords:
carbon nanotubes (CNTs), electromagnetic wave absorption, CeO2/Co@CNT, solvent catalysis, Ce-Co Prussian blue analog (PBA)
Topics:
Carbon nanotubesMagnetic materials MorphologyOrganic frameworks
Cite this article:
Zhou J, Huang X, Lan D, et al. Polymorphic cerium-based Prussian blue derivatives with in situ growing CNT/Co heterojunctions for enhanced microwave absorption via polarization and magnetization. Nano Research, 2024, 17(3): 2050-2060. https://doi.org/10.1007/s12274-023-6216-7
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Abstract Full text Electronic supplementary material About this article

In this paper, the structure evolution of cerium cobaltohexanoate (Ce[Co(CN)6], Ce-Co Prussian blue analog (PBA)) has been realized by solvent catalysis at room temperature. The hexagonal bipyramidal microcrystals of Ce-Co PBA can be gradually transformed into dendrites by different proportions of ethanol (EtOH) and water. At the same time, the porous dendrites CeO2/Co@carbon nanotub (CNT) with oxygen-rich vacancies (OVs) can be obtained by annealing Ce-Co PBA at 700 °C. The microstructure study shows that carbon nanotubes will be catalyzed after annealing at high temperature, and the cobalt metal particles encapsulated in carbon nanotubes will be anchored in the matrix, regulating the impedance matching and multi-polarization suppression of the material, and its unique structure, vacancies, and strong interface effect make the material exhibit excellent electromagnetic wave (EMW) absorption performance. When the matching thickness is 2.5 mm, the minimum reflection loss (RLmin) of the composite is −51.68 dB, and the effective absorption bandwidth (RL < −10 dB) is 7.76 GHz. These results show that the prepared CeO2/Co@CNT composite has excellent EMW absorption properties. It is expected to be a candidate material for EMW absorption.


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Electronic supplementary material
About this article

Polymorphic cerium-based Prussian blue derivatives with in situ growing CNT/Co heterojunctions for enhanced microwave absorption via polarization and magnetization

Show Author's information Jixi Zhou1,§, Xinmeng Huang1,§, Di Lan2, Yuhang Cheng1, Fengyi Xue1, Chenyu Jia1, Guanglei Wu1( ), Zirui Jia1,3( )
Institute of Materials for Energy and Environment, State Key Laboratory of Bio-fibers and Eco-textiles, College of Materials Science and Engineering, Qingdao University, Qingdao 266071, China
School of Materials Science and Engineering, Hubei University of Automotive Technology, Shiyan 442002, China
College of Chemistry and Chemical Engineering, Qingdao University, Qingdao 266071, China

§ Jixi Zhou and Xinmeng Huang contributed equally to this work.

Abstract

In this paper, the structure evolution of cerium cobaltohexanoate (Ce[Co(CN)6], Ce-Co Prussian blue analog (PBA)) has been realized by solvent catalysis at room temperature. The hexagonal bipyramidal microcrystals of Ce-Co PBA can be gradually transformed into dendrites by different proportions of ethanol (EtOH) and water. At the same time, the porous dendrites CeO2/Co@carbon nanotub (CNT) with oxygen-rich vacancies (OVs) can be obtained by annealing Ce-Co PBA at 700 °C. The microstructure study shows that carbon nanotubes will be catalyzed after annealing at high temperature, and the cobalt metal particles encapsulated in carbon nanotubes will be anchored in the matrix, regulating the impedance matching and multi-polarization suppression of the material, and its unique structure, vacancies, and strong interface effect make the material exhibit excellent electromagnetic wave (EMW) absorption performance. When the matching thickness is 2.5 mm, the minimum reflection loss (RLmin) of the composite is −51.68 dB, and the effective absorption bandwidth (RL < −10 dB) is 7.76 GHz. These results show that the prepared CeO2/Co@CNT composite has excellent EMW absorption properties. It is expected to be a candidate material for EMW absorption.

Keywords: carbon nanotubes (CNTs), electromagnetic wave absorption, CeO2/Co@CNT, solvent catalysis, Ce-Co Prussian blue analog (PBA)

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Publication history
Copyright
Acknowledgements

Publication history

Received: 24 July 2023
Revised: 28 August 2023
Accepted: 18 September 2023
Published: 18 November 2023
Issue date: March 2024

Copyright

© Tsinghua University Press 2023

Acknowledgements

Acknowledgements

This work was financially supported by the National Natural Science Foundation of China (Nos. 52377026 and 52301192), the Natural Science Foundation of Shandong Province (Nos. ZR2019YQ24 and ZR2020QF084), the Taishan Scholars and Young Experts Program of Shandong Province (No. tsqn202103057), the Qingchuang Talents Induction Program of Shandong Higher Education Institution (Research and Innovation Team of Structural-Functional Polymer Composites), and the Special Financial of Shandong Province (Structural Design of High-efficiency Electromagnetic Wave-absorbing Composite Materials and Construction of Shandong Provincial Talent Teams).

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