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Nano Research 2024, 17(3): 1625-1635 https://doi.org/10.1007/s12274-023-6160-6
Research Article | Issue | Published: 04 November 2023

Self-assembly tungsten selenide hybrid ternary MOF derived magnetic alloys via multi-polarization to boost microwave absorption

Show Author's Information Tianbao Zhao1,§,  Tingting Zheng1,§,  Di Lan2,  Yan Zhang1,  Zhengshuo Sun1,  Chao Wang1( ),  Zirui Jia1,3( ),  Guanglei Wu1( )
Institute of Materials for Energy and Environment, State Key Laboratory of Bio-fibers and Eco-textiles, College of Materials Science and Engineering, Qingdao University, Qingdao 266071, China
School of Materials Science and Engineering, Hubei University of Automotive Technology, Shiyan 442002, China
College of Chemistry and Chemical Engineering, Qingdao University, Qingdao 266071, China

§ Tianbao Zhao and Tingting Zheng contributed equally to this work.

Keywords:
metal-organic framework, transition metal dichalcogenide, electromagnetic wave absorption, dielectric/magnetic loss
Topics:
Metal nanoparticlesNanostructuresOrganic frameworks Self assembly
Cite this article:
Zhao T, Zheng T, Lan D, et al. Self-assembly tungsten selenide hybrid ternary MOF derived magnetic alloys via multi-polarization to boost microwave absorption. Nano Research, 2024, 17(3): 1625-1635. https://doi.org/10.1007/s12274-023-6160-6
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Abstract Full text Electronic supplementary material About this article

Confronted with severe electromagnetic wave pollution, the development of high-performance electromagnetic wave shielding or absorbing materials is an effective way to deal with it. Notably, double transition metal alloys and transition metal dichalcogenides have attracted extensive attention in electromagnetic wave absorption, but few reports have studied the effects of these two materials on electromagnetic wave absorption at the same time. In this work, cobalt-based alloy with magnetic loss mechanism was selected for composition optimization. The ternary metal-organic framework was prepared by the one-step method, and then CoCu/C was prepared by high temperature annealing. Finally, in the hydrothermal process, ultra-thin tungsten selenide nanosheets were coated on the surface of magnetic component, and the final polyhedral WSe2/CoCu/C composites with multiple heterogeneous interfaces were obtained. The synergistic effect of dielectric and magnetic components optimizes impedance matching and allows more electromagnetic waves to enter the absorber. Subsequently, through the conduction loss of high conductivity graphitized carbon, interfacial polarization, and dipole polarization of heterogeneous interfaces between the components, the magnetic loss provided by CoCu alloy can work together to maximize the attenuation ability of electromagnetic waves. Exactly, the minimum reflection loss (RLmin) value of the composite reaches −53.43 dB when the matched thickness is 2.1 mm, while the maximum effective absorption bandwidth (EABmax) reaches 6.0 GHz at a thin thickness of 1.8 mm. This work provides some support and reference for the design of novel electromagnetic wave absorbing materials via the dielectric/magnetic loss synergistic mechanism.


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Electronic supplementary material
About this article

Self-assembly tungsten selenide hybrid ternary MOF derived magnetic alloys via multi-polarization to boost microwave absorption

Show Author's information Tianbao Zhao1,§, Tingting Zheng1,§, Di Lan2, Yan Zhang1, Zhengshuo Sun1, Chao Wang1( ), Zirui Jia1,3( ), Guanglei Wu1( )
Institute of Materials for Energy and Environment, State Key Laboratory of Bio-fibers and Eco-textiles, College of Materials Science and Engineering, Qingdao University, Qingdao 266071, China
School of Materials Science and Engineering, Hubei University of Automotive Technology, Shiyan 442002, China
College of Chemistry and Chemical Engineering, Qingdao University, Qingdao 266071, China

§ Tianbao Zhao and Tingting Zheng contributed equally to this work.

Abstract

Confronted with severe electromagnetic wave pollution, the development of high-performance electromagnetic wave shielding or absorbing materials is an effective way to deal with it. Notably, double transition metal alloys and transition metal dichalcogenides have attracted extensive attention in electromagnetic wave absorption, but few reports have studied the effects of these two materials on electromagnetic wave absorption at the same time. In this work, cobalt-based alloy with magnetic loss mechanism was selected for composition optimization. The ternary metal-organic framework was prepared by the one-step method, and then CoCu/C was prepared by high temperature annealing. Finally, in the hydrothermal process, ultra-thin tungsten selenide nanosheets were coated on the surface of magnetic component, and the final polyhedral WSe2/CoCu/C composites with multiple heterogeneous interfaces were obtained. The synergistic effect of dielectric and magnetic components optimizes impedance matching and allows more electromagnetic waves to enter the absorber. Subsequently, through the conduction loss of high conductivity graphitized carbon, interfacial polarization, and dipole polarization of heterogeneous interfaces between the components, the magnetic loss provided by CoCu alloy can work together to maximize the attenuation ability of electromagnetic waves. Exactly, the minimum reflection loss (RLmin) value of the composite reaches −53.43 dB when the matched thickness is 2.1 mm, while the maximum effective absorption bandwidth (EABmax) reaches 6.0 GHz at a thin thickness of 1.8 mm. This work provides some support and reference for the design of novel electromagnetic wave absorbing materials via the dielectric/magnetic loss synergistic mechanism.

Keywords: metal-organic framework, transition metal dichalcogenide, electromagnetic wave absorption, dielectric/magnetic loss

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Publication history
Copyright
Acknowledgements

Publication history

Received: 06 August 2023
Revised: 28 August 2023
Accepted: 04 September 2023
Published: 04 November 2023
Issue date: March 2024

Copyright

© Tsinghua University Press 2023

Acknowledgements

Acknowledgements

This work was financially supported by the National Natural Science Foundation of China (Nos. 52377026 and 52301192), the Natural Science Foundation of Shandong Province (No. ZR2019YQ24), the Taishan Scholars and Young Experts Program of Shandong Province (No. tsqn202103057), the Qingchuang Talents Induction Program of Shandong Higher Education Institution (Research and Innovation Team of Structural-Functional Polymer Composites), the Key Laboratory of Engineering Dielectrics and Its Application (Harbin University of Science and Technology), the Ministry of Education, and the Special Financial of Shandong Province (Structural Design of High-efficiency Electromagnetic Wave-absorbing Composite Materials and Construction of Shandong Provincial Talent Teams).

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