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The main problem faced by ethanol oxidation reaction (EOR) includes low activity, poor selectivity, and durability. In the study, we found that polysulfide modified on the surface of PtCu intermetallic (IM)/C can simultaneously enrich hydroxyl and ethanol, which could effectively improve the catalytic activity, CO2 selectivity, and durability of catalyst. The mass activity and the specific activity of the product in 1 M KOH electrolyte reached 17.83 A·mgPt−1 and 24.67 mA·cm−2. The CO2 selectivity of polysulfide modified product achieved 93.5%, which was 30 folds higher than Pt/C. In addition, the catalyst showed high catalytic stability. The mechanism study demonstrates that the surface modified polysulfide could significantly boost the enrichment effect of ethanol and hydroxyl species, accelerating C–C bond cleavage and CO oxidation.
This work was supported by the National Natural Science Foundation of China (Nos. 22001143, 21971132, and 52072197), Youth Innovation and Technology Foundation of Shandong Higher Education Institutions, China (No. 2019KJC004), Outstanding Youth Foundation of Shandong Province, China (No. ZR2019JQ14), Taishan Scholar Young Talent Program (Nos. tsqn201909114 and tsqn201909123), Natural Science Foundation of Shandong Province (Nos. ZR2020YQ34 and ZR2019MB042), Major Scientific and Technological Innovation Project (No. 2019JZZY020405), Major Basic Research Program of Natural Science Foundation of Shandong Province (No. ZR2020ZD09), and the National Natural Science Foundation of China (No. 22002083).