Novoselov, K. S.; Geim, A. K.; Morozov, S. V.; Jiang, D.; Zhang, Y.; Dubonos, S. V.; Grigorieva, I. V.; Firsov, A. A. Electric field effect in atomically thin carbon films. Science 2004, 306, 666–669.

Wilson, J. A.; Di Salvo, F. J.; Mahajan, S. Charge-density waves and superlattices in the metallic layered transition metal dichalcogenides. Adv. Phys. 1975, 24, 117–201.

Liu, C. S.; Chen, H. W.; Wang, S. Y.; Liu, Q.; Jiang, Y. G.; Zhang, D. W.; Liu, M.; Zhou, P. Two-dimensional materials for next-generation computing technologies. Nat. Nanotechnol. 2020, 15, 545–557.

Tan, T.; Jiang, X. T.; Wang, C.; Yao, B. C.; Zhang, H. 2D material optoelectronics for information functional device applications: Status and challenges. Adv. Sci. 2020, 7, 2000058.

Zheng, L.; Wang, X. W.; Jiang, H. J.; Xu, M. Z.; Huang, W.; Liu, Z. Recent progress of flexible electronics by 2D transition metal dichalcogenides. Nano Res. 2022, 15, 2413–2432.

Nardekar, S. S.; Krishnamoorthy, K.; Manoharan, S.; Pazhamalai, P.; Kim, S. J. Two faces under a hood: Unravelling the energy harnessing and storage properties of 1T-MoS₂ quantum sheets for next-generation stand-alone energy systems. ACS Nano 2022, 16, 3723–3734.

Voiry, D.; Yang, J.; Chhowalla, M. Recent strategies for improving the catalytic activity of 2D TMD nanosheets toward the hydrogen evolution reaction. Adv. Mater. 2016, 28, 6197–6206.

Lin, L. X.; Sherrell, P.; Liu, Y. Q.; Lei, W.; Zhang, S. W.; Zhang, H. J.; Wallace, G. G.; Chen, J. Engineered 2D transition metal dichalcogenides—A vision of viable hydrogen evolution reaction catalysis. Adv. Energy Mater. 2020, 10, 1903870.

Lu, Q. P.; Yu, Y. F.; Ma, Q. L.; Chen, B.; Zhang, H. 2D transition-metal-dichalcogenide-nanosheet-based composites for photocatalytic and electrocatalytic hydrogen evolution reactions. Adv. Mater 2016, 28, 1917–1933.

Tan, C. L.; Cao, X. H.; Wu, X. J.; He, Q. Y.; Yang, J.; Zhang, X.; Chen, J. Z.; Zhao, W.; Han, S. K.; Nam, G. H. et al. Recent advances in ultrathin two-dimensional nanomaterials. Chem. Rev. 2017, 117, 6225–6331.

Yang, L. S.; Chen, W. J.; Yu, Q. M.; Liu, B. L. Mass production of two-dimensional materials beyond graphene and their applications. Nano Res. 2021, 14, 1583–1597.

Deng, J.; Li, H. B.; Xiao, J. P.; Tu, Y. C.; Deng, D. H.; Yang, H. X.; Tian, H. F.; Li, J. Q.; Ren, P. J.; Bao, X. H. Triggering the electrocatalytic hydrogen evolution activity of the inert two-dimensional MoS₂ surface via single-atom metal doping. Energy Environ. Sci. 2015, 8, 1594–1601.

Liu, L. N.; Wu, J. X.; Wu, L. Y.; Ye, M.; Liu, X. Z.; Wang, Q.; Hou, S. Y.; Lu, P. F.; Sun, L. F.; Zheng, J. Y. et al. Phase-selective synthesis of 1T' MoS₂ monolayers and heterophase bilayers. Nat. Mater. 2018, 17, 1108–1114.

Lee, J. S.; Choi, S. H.; Yun, S. J.; Kim, Y. I.; Boandoh, S.; Park, J. H.; Shin, B. G.; Ko, H.; Lee, S. H.; Kim, Y. M. et al. Wafer-scale single-crystal hexagonal boron nitride film via self-collimated grain formation. Science 2018, 362, 817–821.

Choi, S. H.; Kim, H. J.; Song, B.; Kim, Y. I.; Han, G.; Nguyen, H. T. T.; Ko, H.; Boandoh, S.; Choi, J. H.; Oh, C. S. et al. Epitaxial single-crystal growth of transition metal dichalcogenide monolayers via the atomic sawtooth Au surface. Adv. Mater. 2021, 33, 2006601.

Liu, Z. Q.; Nie, K. K.; Qu, X. Y.; Li, X. H.; Li, B. J.; Yuan, Y. L.; Chong, S. K.; Liu, P.; Li, Y. G.; Yin, Z. Y. et al. General bottom-up colloidal synthesis of nano-monolayer transition-metal dichalcogenides with high 1T′-phase purity. J. Am. Chem. Soc. 2022, 144, 4863–4873.

Xu, X. M.; Guo, T. C.; Kim, H.; Hota, M. K.; Alsaadi, R. S.; Lanza, M.; Zhang, X. X.; Alshareef, H. N. Growth of 2D materials at the wafer scale. Adv. Mater. 2022, 34, 2108258.

Pei, Y. P.; Chen, R.; Xu, H.; He, D.; Jiang, C. Z.; Li, W. Q.; Xiao, X. H. Recent progress about 2D metal dichalcogenides: Synthesis and application in photodetectors. Nano Res. 2021, 14, 1819–1839.

Sun, L. Z.; Yuan, G. W.; Gao, L. B.; Yang, J.; Chhowalla, M.; Gharahcheshmeh, M. H.; Gleason, K. K.; Choi, Y. S.; Hong, B. H.; Liu, Z. F. Chemical vapour deposition. Nat. Rev. Methods Primers 2021, 1, 5.

Novoselov, K. S.; Jiang, D.; Schedin, F.; Booth, T. J.; Khotkevich, V. V.; Morozov, S. V.; Geim, A. K. Two-dimensional atomic crystals. Proc. Natl. Acad. Sci. USA 2005, 102, 10451–10453.

Wang, Y.; Xiao, J.; Zhu, H. Y.; Li, Y.; Alsaid, Y.; Fong, K. Y.; Zhou, Y.; Wang, S. Q.; Shi, W.; Wang, Y. et al. Structural phase transition in monolayer MoTe₂ driven by electrostatic doping. Nature 2017, 550, 487–491.

Zhang, J. S.; Yang, A. K.; Wu, X.; van de Groep, J.; Tang, P. Z.; Li, S. R.; Liu, B. F.; Shi, F. F.; Wan, J. Y.; Li, Q. T. et al. Reversible and selective ion intercalation through the top surface of few-layer MoS₂. Nat. Commun. 2018, 9, 5289.

Xi, X. X.; Wang, Z. F.; Zhao, W. W.; Park, J. H.; Law, K. T.; Berger, H.; Forró, L.; Shan, J.; Mak, K. F. Ising pairing in superconducting NbSe₂ atomic layers. Nat. Phys. 2016, 12, 139–143.

Wu, F. L.; Liu, Z. T.; Hawthorne, N.; Chandross, M.; Moore, Q.; Argibay, N.; Curry, J. F.; Batteas, J. D. Formation of coherent 1H-1T heterostructures in single-layer MoS₂ on Au(111). ACS Nano 2020, 14, 16939–16950.

Coleman, J. N.; Lotya, M.; O'Neill, A.; Bergin, S. D.; King, P. J.; Khan, U.; Young, K.; Gaucher, A.; De, S.; Smith, R. J. et al. Two-dimensional nanosheets produced by liquid exfoliation of layered materials. Science 2011, 331, 568–571.

Kim, J.; Kwon, S.; Cho, D. H.; Kang, B.; Kwon, H.; Kim, Y.; Park, S. O.; Jung, G. Y.; Shin, E.; Kim, W. G. et al. Direct exfoliation and dispersion of two-dimensional materials in pure water via temperature control. Nat. Commun. 2015, 6, 8294.

Bang, G. S.; Nam, K. W.; Kim, J. Y.; Shin, J.; Choi, J. W.; Choi, S. Y. Effective liquid-phase exfoliation and sodium ion battery application of MoS₂ nanosheets. ACS Appl. Mater. Interfaces 2014, 6, 7084–7089.

Puglia, M. K.; Malhotra, M.; Chivukula, A.; Kumar, C. V. “Simple-stir” heterolayered MoS₂/graphene nanosheets for Zn-air batteries. ACS Appl. Nano Mater. 2021, 4, 10389–10398.

Zhang, C.; Wang, L. D.; Zhou, Y. C.; Lu, H. J.; Wageh, S.; Al-Hartomy, O. A.; Al-Sehemi, A. G.; Wang, H. C.; Yu, C. T.; Zhang, H. et al. Two-dimensional alloyed Mo_0.5W_0.5S₂ nanosheets for photoelectrochemical photodetection. ACS Appl. Nano Mater. 2022, 5, 14824–14832.

Huo, C. X.; Yan, Z.; Song, X. F.; Zeng, H. B. 2D materials via liquid exfoliation: A review on fabrication and applications. Sci. Bull. 2015, 60, 1994–2008.

Smith, R. J.; King, P. J.; Lotya, M.; Wirtz, C.; Khan, U.; De, S.; O'Neill, A.; Duesberg, G. S.; Grunlan, J. C.; Moriarty, G. et al. Large-scale exfoliation of inorganic layered compounds in aqueous surfactant solutions. Adv. Mater. 2011, 23, 3944–3948.

Paton, K. R.; Varrla, E.; Backes, C.; Smith, R. J.; Khan, U.; O’Neill, A.; Boland, C.; Lotya, M.; Istrate, O. M.; King, P. et al. Scalable production of large quantities of defect-free few-layer graphene by shear exfoliation in liquids. Nat. Mater. 2014, 13, 624–630.

Cunningham, G.; Lotya, M.; Cucinotta, C. S.; Sanvito, S.; Bergin, S. D.; Menzel, R.; Shaffer, M. S. P.; Coleman, J. N. Solvent exfoliation of transition metal dichalcogenides: Dispersibility of exfoliated nanosheets varies only weakly between compounds. ACS Nano 2012, 6, 3468–3480.

Backes, C.; Higgins, T. M.; Kelly, A.; Boland, C.; Harvey, A.; Hanlon, D.; Coleman, J. N. Guidelines for exfoliation, characterization and processing of layered materials produced by liquid exfoliation. Chem. Mater. 2017, 29, 243–255.

Wang, H. L.; Shi, J.; Zhang, J. Y.; Tao, Z. H.; Wang, H. G.; Yang, Q. Q.; van Aken, P. A.; Chen, R. F. Pectin-assisted one-pot synthesis of MoS₂ nanocomposites for resistive switching memory application. Nanoscale 2022, 14, 12129–12135.

Yang, R. J.; Mei, L.; Zhang, Q. Y.; Fan, Y. Y.; Shin, H. S.; Voiry, D.; Zeng, Z. Y. High-yield production of mono- or few-layer transition metal dichalcogenide nanosheets by an electrochemical lithium ion intercalation-based exfoliation method. Nat. Protoc. 2022, 17, 358–377.

Zhou, J. Y.; Lin, Z. Y.; Ren, H. Y.; Duan, X. D.; Shakir, I.; Huang, Y.; Duan, X. F. Layered intercalation materials. Adv. Mater. 2021, 33, 2004557.

Rajapakse, M.; Karki, B.; Abu, U. O.; Pishgar, S.; Musa, R. K.; Riyadh, S. M. S.; Yu, M.; Sumanasekera, G.; Jasinski, J. B. Intercalation as a versatile tool for fabrication, property tuning, and phase transitions in 2D materials. npj 2D Mater. Appl. 2021, 5, 30.

Lin, Z. Y.; Liu, Y.; Halim, U.; Ding, M. N.; Liu, Y. Y.; Wang, Y. L.; Jia, C. C.; Chen, P.; Duan, X. D.; Wang, C. et al. Solution-processable 2D semiconductors for high-performance large-area electronics. Nature 2018, 562, 254–258.

Hernandez, Y.; Nicolosi, V.; Lotya, M.; Blighe, F. M.; Sun, Z. Y.; De, S.; McGovern, I. T.; Holland, B.; Byrne, M.; Gun'Ko, Y. K. et al. High-yield production of graphene by liquid-phase exfoliation of graphite. Nat. Nanotechnol. 2008, 3, 563–568.

Yang, S.; Lohe, M. R.; Müllen, K.; Feng, X. L. New-generation graphene from electrochemical approaches: Production and applications. Adv. Mater. 2016, 28, 6213–6221.

Yang, S.; Zhang, P. P.; Nia, A. S.; Feng, X. L. Emerging 2D materials produced via electrochemistry. Adv. Mater. 2020, 32, 1907857.

Abdelkader, A. M.; Cooper, A. J.; Dryfe, R. A. W.; Kinloch, I. A. How to get between the sheets: A review of recent works on the electrochemical exfoliation of graphene materials from bulk graphite. Nanoscale 2015, 7, 6944–6956.

Brisebois, P. P.; Siaj, M. Harvesting graphene oxide—years 1859 to 2019: A review of its structure, synthesis, properties and exfoliation. J. Mater. Chem. C 2020, 8, 1517–1547.

Zhao, S. Y. F.; Elbaz, G. A.; Bediako, D. K.; Yu, C.; Efetov, D. K.; Guo, Y. S.; Ravichandran, J.; Min, K. A.; Hong, S.; Taniguchi, T. et al. Controlled electrochemical intercalation of graphene/h-BN van der Waals heterostructures. Nano Lett. 2018, 18, 460–466.

Erande, M. B.; Pawar, M. S.; Late, D. J. Humidity sensing and photodetection behavior of electrochemically exfoliated atomically thin-layered black phosphorus nanosheets. ACS Appl. Mater. Interfaces 2016, 8, 11548–11556.

Li, J.; Chen, C.; Liu, S. L.; Lu, J. P.; Goh, W. P.; Fang, H. Y.; Qiu, Z. Z.; Tian, B. B.; Chen, Z. X.; Yao, C. H. et al. Ultrafast electrochemical expansion of black phosphorus toward high-yield synthesis of few-layer phosphorene. Chem. Mater. 2018, 30, 2742–2749.

Jeon, Y.; Rhee, D.; Wu, B.; Mazanek, V.; Kim, I. S.; Son, D.; Sofer, Z.; Kang, J. Electrochemically exfoliated phosphorene nanosheet thin films for wafer-scale near-infrared phototransistor array. npj 2D Mater. Appl. 2022, 6, 82.

Wang, Y.; Sofer, Z.; Luxa, J.; Pumera, M. Lithium exfoliated vanadium dichalcogenides (VS₂, VSe₂, VTe₂) exhibit dramatically different properties from their bulk counterparts. Adv. Mater. Interfaces 2016, 3, 1600433.

Zeng, Z. Y.; Yin, Z. Y.; Huang, X.; Li, H.; He, Q. Y.; Lu, G.; Boey, F.; Zhang, H. Single-layer semiconducting nanosheets: High-yield preparation and device fabrication. Angew. Chem. 2011, 123, 11289–11293.

Rasamani, K. D.; Alimohammadi, F.; Sun, Y. G. Interlayer-expanded MoS₂. Mater. Today 2017, 20, 83–91.

Lipatov, A.; Chaudhary, P.; Guan, Z.; Lu, H. D.; Li, G.; Crégut, O.; Dorkenoo, K. D.; Proksch, R.; Cherifi-Hertel, S.; Shao, D. F. et al. Direct observation of ferroelectricity in two-dimensional MoS₂. npj 2D Mater. Appl. 2022, 6, 18.

Wang, M. J.; Kumar, A.; Dong, H.; Woods, J. M.; Pondick, J. V.; Xu, S. Y.; Hynek, D. J.; Guo, P. J.; Qiu, D. Y.; Cha, J. J. A gapped phase in semimetallic T_d-WTe₂ induced by lithium intercalation. Adv. Mater. 2022, 34, 2200861.

Wang, H. T.; Lu, Z. Y.; Kong, D. S.; Sun, J.; Hymel, T. M.; Cui, Y. Electrochemical tuning of MoS₂ nanoparticles on three-dimensional substrate for efficient hydrogen evolution. ACS Nano 2014, 8, 4940–4947.

Wang, H. T.; Lu, Z. Y.; Xu, S. C.; Kong, D. S.; Cha, J. J.; Zheng, G. Y.; Hsu, P. C.; Yan, K.; Bradshaw, D.; Prinz, F. B. et al. Electrochemical tuning of vertically aligned MoS₂ nanofilms and its application in improving hydrogen evolution reaction. Proc. Natl. Acad. Sci. USA 2013, 110, 19701–19706.

Chhowalla, M.; Shin, H. S.; Eda, G.; Li, L. J.; Loh, K. P.; Zhang, H. The chemistry of two-dimensional layered transition metal dichalcogenide nanosheets. Nat. Chem. 2013, 5, 263–275.

Zak, A.; Feldman, Y.; Lyakhovitskaya, V.; Leitus, G.; Popovitz-Biro, R.; Wachtel, E.; Cohen, H.; Reich, S.; Tenne, R. Alkali metal intercalated fullerene-like MS₂ (M = W, Mo) nanoparticles and their properties. J. Am. Chem. Soc. 2002, 124, 4747–4758.

Eda, G.; Yamaguchi, H.; Voiry, D.; Fujita, T.; Chen, M. W.; Chhowalla, M. Photoluminescence from chemically exfoliated MoS₂. Nano Lett. 2011, 11, 5111–5116.

Py, M. A.; Haering, R. R. Structural destabilization induced by lithium intercalation in MoS₂ and related compounds. Can. J. Phys. 1983, 61, 76–84.

Mulhern, P. J. Lithium intercalation in crystalline Li_xMoS₂. Can. J. Phys. 1989, 67, 1049–1052.

Kappera, R.; Voiry, D.; Yalcin, S. E.; Branch, B.; Gupta, G.; Mohite, A. D.; Chhowalla, M. Phase-engineered low-resistance contacts for ultrathin MoS₂ transistors. Nat. Mater. 2014, 13, 1128–1134.

Acerce, M.; Voiry, D.; Chhowalla, M. Metallic 1T phase MoS₂ nanosheets as supercapacitor electrode materials. Nat. Nanotechnol. 2015, 10, 313–318.

Wu, Y. C.; Li, D. F.; Wu, C. L.; Hwang, H. Y.; Cui, Y. Electrostatic gating and intercalation in 2D materials. Nat. Rev. Mater. 2023, 8, 41–53.

Lukowski, M. A.; Daniel, A. S.; Meng, F.; Forticaux, A.; Li, L. S.; Jin, S. Enhanced hydrogen evolution catalysis from chemically exfoliated metallic MoS₂ nanosheets. J. Am. Chem. Soc. 2013, 135, 10274–10277.

Mahler, B.; Hoepfner, V.; Liao, K.; Ozin, G. A. Colloidal synthesis of 1T-WS₂ and 2H-WS₂ nanosheets: Applications for photocatalytic hydrogen evolution. J. Am. Chem. Soc. 2014, 136, 14121–14127.

Yin, Y.; Zhang, Y. M.; Gao, T. L.; Yao, T.; Zhang, X. H.; Han, J. C.; Wang, X. J.; Zhang, Z. H.; Xu, P.; Zhang, P. et al. Synergistic phase and disorder engineering in 1T-MoSe₂ nanosheets for enhanced hydrogen-evolution reaction. Adv. Mater. 2017, 29, 1700311.

Wang, L. F.; Xu, Z.; Wang, W. L.; Bai, X. D. Atomic mechanism of dynamic electrochemical lithiation processes of MoS₂ nanosheets. J. Am. Chem. Soc. 2014, 136, 6693–6697.

Cheng, Y. C.; Nie, A. M.; Zhang, Q. Y.; Gan, L. Y.; Shahbazian-Yassar, R.; Schwingenschlogl, U. Origin of the phase transition in lithiated molybdenum disulfide. ACS Nano 2014, 8, 11447–11453.

Voiry, D.; Mohite, A.; Chhowalla, M. Phase engineering of transition metal dichalcogenides. Chem. Soc. Rev. 2015, 44, 2702–2712.

Enyashin, A. N.; Yadgarov, L.; Houben, L.; Popov, I.; Weidenbach, M.; Tenne, R.; Bar-Sadan, M.; Seifert, G. New route for stabilization of 1T-WS₂ and MoS₂ phases. J. Phys. Chem. C 2011, 115, 24586–24591.

Niu, S. W.; Cai, J. Y.; Wang, G. M. Two-dimensional MoS₂ for hydrogen evolution reaction catalysis: The electronic structure regulation. Nano Res. 2021, 14, 1985–2002.

Lu, T. L.; Wang, Y. N.; Cai, G. H.; Jia, H. X.; Liu, X. X.; Zhang, C.; Meng, S.; Liu, M. Synthesizability of transition-metal dichalcogenides: A systematic first-principles evaluation. Mater. Futures 2023, 2, 015001.

Nguyen, T. P.; Sohn, W.; Oh, J. H.; Jang, H. W.; Kim, S. Y. Size-dependent properties of two-dimensional MoS₂ and WS₂. J. Phys. Chem. C 2016, 120, 10078–10085.

Mak, K. F.; Lee, C.; Hone, J.; Shan, J.; Heinz, T. F. Atomically thin MoS₂: A new direct-gap semiconductor. Phys. Rev. Lett. 2010, 105, 136805.

Varma, S. J.; Kumar, J.; Liu, Y.; Layne, K.; Wu, J. J.; Liang, C. L.; Nakanishi, Y.; Aliyan, A.; Yang, W.; Ajayan, P. M. et al. 2D TiS₂ layers:A superior nonlinear optical limiting material. Adv. Opt. Mater. 2017, 5, 1700713.

Wei, X.; Lin, C. C.; Wu, C. W.; Qaiser, N.; Cai, Y. C.; Lu, A. Y.; Qi, K.; Fu, J. H.; Chiang, Y. H.; Yang, Z. et al. Three-dimensional hierarchically porous MoS₂ foam as high-rate and stable lithium-ion battery anode. Nat. Commun. 2022, 13, 6006.

Chen, Y. C.; Lu, A. Y.; Lu, P.; Yang, X. L.; Jiang, C. M.; Mariano, M.; Kaehr, B.; Lin, O.; Taylor, A.; Sharp, I. D. et al. Structurally deformed MoS₂ for electrochemically stable, thermally resistant, and highly efficient hydrogen evolution reaction. Adv. Mater. 2017, 29, 1703863.

Li, F. X.; Zou, J. L.; Cao, L. J.; Li, Z. Q.; Gu, S.; Liu, Y.; Zhang, J. Q.; Liu, H. T.; Lu, Z. G. In situ study of K⁺ electrochemical intercalating into MoS₂ flakes. J. Phys. Chem. C 2019, 123, 5067–5072.

Lam, D.; Lebedev, D.; Kuo, L.; Sangwan, V. K.; Szydłowska, B. M.; Ferraresi, F.; Söll, A.; Sofer, Z.; Hersam, M. C. Liquid-phase exfoliation of magnetically and optoelectronically active ruthenium trichloride nanosheets. ACS Nano 2022, 16, 11315–11324.

Zhang, Q. C.; Xu, D. Y.; Liang, J. M.; Lin, Q. Q.; Peng, W. C.; Li, Y.; Zhang, F. B.; Fan, X. B. Surfactant-free synthesis of ultrafine Pt nanoparticles on MoS₂ nanosheets as bifunctional catalysts for the hydrodeoxygenation of bio-oil. Langmuir 2020, 36, 14710–14716.

Liu, X. C.; Zhao, S. Y.; Sun, X. P.; Deng, L. Z.; Zou, X. L.; Hu, Y. C.; Wang, Y. X.; Chu, C. W.; Li, J.; Wu, J. J. et al. Spontaneous self-intercalation of copper atoms into transition metal dichalcogenides. Sci. Adv. 2020, 6, eaay4092.

Li, Y.; Yan, H.; Xu, B.; Zhen, L.; Xu, C. Y. Electrochemical intercalation in atomically thin van der Waals materials for structural phase transition and device applications. Adv. Mater. 2021, 33, 2000581.

Joensen, P.; Frindt, R. F.; Morrison, S. R. Single-layer MoS₂. Mater. Res. Bull. 1986, 21, 457–461.

Voiry, D.; Yamaguchi, H.; Li, J. W.; Silva, R.; Alves, D. C. B.; Fujita, T.; Chen, M. W.; Asefa, T.; Shenoy, V. B.; Eda, G. et al. Enhanced catalytic activity in strained chemically exfoliated WS₂ nanosheets for hydrogen evolution. Nat. Mater. 2013, 12, 850–855.

Gong, Y. J.; Yuan, H. T.; Wu, C. L.; Tang, P. Z.; Yang, S. Z.; Yang, A. K.; Li, G. D.; Liu, B. F.; van de Groep, J.; Brongersma, M. L. et al. Spatially controlled doping of two-dimensional SnS₂ through intercalation for electronics. Nat. Nanotechnol. 2018, 13, 294–299.

Zhu, L.; Li, Q. Y.; Lv, Y. Y.; Li, S. C.; Zhu, X. Y.; Jia, Z. Y.; Chen, Y. B.; Wen, J. S.; Li, S. C. Superconductivity in potassium-intercalated T_d-WTe₂. Nano Lett. 2018, 18, 6585–6590.

Huang, H. H.; Cui, Y.; Li, Q.; Dun, C. C.; Zhou, W.; Huang, W. X.; Chen, L.; Hewitt, C. A.; Carroll, D. L. Metallic 1T phase MoS₂ nanosheets for high-performance thermoelectric energy harvesting. Nano Energy 2016, 26, 172–179.

Ries, L.; Petit, E.; Michel, T.; Diogo, C. C.; Gervais, C.; Salameh, C.; Bechelany, M.; Balme, S.; Miele, P.; Onofrio, N. et al. Enhanced sieving from exfoliated MoS₂ membranes via covalent functionalization. Nat. Mater. 2019, 18, 1112–1117.

Ambrosi, A.; Sofer, Z.; Pumera, M. Lithium intercalation compound dramatically influences the electrochemical properties of exfoliated MoS₂. Small 2015, 11, 605–612.

Tan, C. L.; Luo, Z. M.; Chaturvedi, A.; Cai, Y. Q.; Du, Y. H.; Gong, Y.; Huang, Y.; Lai, Z. C.; Zhang, X.; Zheng, L. R. et al. Preparation of high-percentage 1T-phase transition metal dichalcogenide nanodots for electrochemical hydrogen evolution. Adv. Mater. 2018, 30, 1705509.

Koski, K. J.; Cha, J. J.; Reed, B. W.; Wessells, C. D.; Kong, D.; Cui, Y. High-density chemical intercalation of zero-valent copper into Bi₂Se₃ nanoribbons. J. Am. Chem. Soc. 2012, 134, 7584–7587.

Stern, C.; Twitto, A.; Snitkoff, R. Z.; Fleger, Y.; Saha, S.; Boddapati, L.; Jain, A.; Wang, M. J.; Koski, K. J.; Deepak, F. L. et al. Enhancing light-matter interactions in MoS₂ by copper intercalation. Adv. Mater. 2021, 33, 2008779.

Wang, M. J.; Williams, D.; Lahti, G.; Teshima, S.; Aguilar, D. D.; Perry, R.; Koski, K. J. Chemical intercalation of heavy metal, semimetal, and semiconductor atoms into 2D layered chalcogenides. 2D Mater. 2018, 5, 045005.

Koski, K. J.; Wessells, C. D.; Reed, B. W.; Cha, J. J.; Kong, D.; Cui, Y. Chemical intercalation of zerovalent metals into 2D layered Bi₂Se₃ nanoribbons. J. Am. Chem. Soc. 2012, 134, 13773–13779.

Zhang, R. Y.; Tsai, I. L.; Chapman, J.; Khestanova, E.; Waters, J.; Grigorieva, I. V. Superconductivity in potassium-doped metallic polymorphs of MoS₂. Nano Lett. 2016, 16, 629–636.

Bruce, P. G.; Krok, F.; Nowinski, J.; Gibson, V. C.; Tavakkoli, K. Chemical intercalation of magnesium into solid hosts. J. Mater. Chem. 1991, 1, 705–706.

Tan, S. M.; Sofer, Z.; Luxa, J.; Pumera, M. Aromatic-exfoliated transition metal dichalcogenides: Implications for inherent electrochemistry and hydrogen evolution. ACS Catal. 2016, 6, 4594–4607.

Murphy, D. W.; Di Salvo, F. J.; Hull, G. W. Jr; Waszczak, J. V. Convenient preparation and physical properties of lithium intercalation compounds of Group 4B and 5B layered transition metal dichalcogenides. Inorg. Chem. 1976, 15, 17–21.

Zheng, J.; Zhang, H.; Dong, S. H.; Liu, Y. P.; Nai, C. T.; Shin, H. S.; Jeong, H. Y.; Liu, B.; Loh, K. P. High yield exfoliation of two-dimensional chalcogenides using sodium naphthalenide. Nat. Commun. 2014, 5, 2995.

Zhu, X. L.; Su, Z. P.; Wu, C.; Cong, H. J.; Ai, X. P.; Yang, H. X.; Qian, J. F. Exfoliation of MoS₂ nanosheets enabled by a redox-potential-matched chemical lithiation reaction. Nano Lett. 2022, 22, 2956–2963.

Eda, G.; Fujita, T.; Yamaguchi, H.; Voiry, D.; Chen, M. W.; Chhowalla, M. Coherent atomic and electronic heterostructures of single-layer MoS₂. ACS Nano 2012, 6, 7311–7317.

Eng, A. Y. S.; Ambrosi, A.; Sofer, Z.; Šimek, P.; Pumera, M. Electrochemistry of transition metal dichalcogenides: Strong dependence on the metal-to-chalcogen composition and exfoliation method. ACS Nano 2014, 8, 12185–12198.

Mayorga-Martinez, C. C.; Ambrosi, A.; Eng, A. Y. S.; Sofer, Z.; Pumera, M. Transition metal dichalcogenides (MoS₂, MoSe₂, WS₂ and WSe₂) exfoliation technique has strong influence upon their capacitance. Electrochem. Commun. 2015, 56, 24–28.

Mayorga-Martinez, C. C.; Ambrosi, A.; Eng, A. Y. S.; Sofer, Z.; Pumera, M. Metallic 1T-WS₂ for selective impedimetric vapor sensing. Adv. Funct. Mater. 2015, 25, 5611–5616.

Rahmanian, E.; Mayorga-Martinez, C. C.; Malekfar, R.; Luxa, J.; Sofer, Z.; Pumera, M. 1T-phase tungsten chalcogenides (WS₂, WSe₂, WTe₂) decorated with TiO₂ nanoplatelets with enhanced electron transfer activity for biosensing applications. ACS Appl. Nano Mater. 2018, 1, 7006–7015.

Xing, F.; Li, T.; Li, J. Y.; Zhu, H. R.; Wang, N.; Cao, X. Chemically exfoliated MoS₂ for capacitive deionization of saline water. Nano Energy 2017, 31, 590–595.

Fan, X. B.; Xu, P. T.; Zhou, D. K.; Sun, Y. F.; Li, Y. C.; Nguyen, M. A. T.; Terrones, M.; Mallouk, T. E. Fast and efficient preparation of exfoliated 2H MoS₂ nanosheets by sonication-assisted lithium intercalation and infrared laser-induced 1T to 2H phase reversion. Nano Lett. 2015, 15, 5956–5960.

Guo, Y. B.; Chen, Q.; Nie, A. M.; Yang, H.; Wang, W. B.; Su, J. W.; Wang, S. Z.; Liu, Y. W.; Wang, S.; Li, H. Q. et al. 2D hybrid superlattice-based on-chip electrocatalytic microdevice for in situ revealing enhanced catalytic activity. ACS Nano 2020, 14, 1635–1644.

Feng, N.; Meng, R. J.; Zu, L. H.; Feng, Y. T.; Peng, C. X.; Huang, J. M.; Liu, G. L.; Chen, B. J.; Yang, J. H. A polymer-direct-intercalation strategy for MoS₂/carbon-derived heteroaerogels with ultrahigh pseudocapacitance. Nat. Commun. 2019, 10, 1372.

Samaras, I.; Saikh, S. I.; Julien, C.; Balkanski, M. Lithium insertion in layered materials as battery cathodes. Mater. Sci. Eng. B 1989, 3, 209–214.

Zeng, Z. Y.; Sun, T.; Zhu, J. X.; Huang, X.; Yin, Z. Y.; Lu, G.; Fan, Z. X.; Yan, Q. Y.; Hng, H. H.; Zhang, H. An effective method for the fabrication of few-layer-thick inorganic nanosheets. Angew. Chem., Int. Ed. 2012, 51, 9052–9056.

Liu, Z.; Han, T.; Liu, M. Q.; Huang, S. T.; Zhang, Z. Y.; Long, M. S.; Hou, X. Y.; Shan, L. Protonation enhanced superconductivity in PdTe₂. J. Phys. :Condens. Matter 2022, 34, 335603.

Zhu, G. H.; Liu, J.; Zheng, Q. Y.; Zhang, R. G.; Li, D. Y.; Banerjee, D.; Cahill, D. G. Tuning thermal conductivity in molybdenum disulfide by electrochemical intercalation. Nat. Commun. 2016, 7, 13211.

Weng, C. C.; Luo, Y. Y.; Wang, B. F.; Shi, J. P.; Gao, L.; Cao, Z. Y.; Duan, G. T. Layer-dependent SERS enhancement of TiS₂ prepared by simple electrochemical intercalation. J. Mater. Chem. C 2020, 8, 14138–14145.

Wang, L. L.; Liu, X.; Zhang, Q. F.; Zhou, G.; Pei, Y.; Chen, S. H.; Wang, J.; Rao, A. M.; Yang, H. G.; Lu, B. A. Quasi-one-dimensional Mo chains for efficient hydrogen evolution reaction. Nano Energy 2019, 61, 194–200.

García-Dalí, S.; Paredes, J. I.; Munuera, J. M.; Villar-Rodil, S.; Adawy, A.; Martínez-Alonso, A.; Tascón, J. M. D. Aqueous cathodic exfoliation strategy toward solution-processable and phase-preserved MoS₂ nanosheets for energy storage and catalytic applications. ACS Appl. Mater. Interfaces 2019, 11, 36991–37003.

Zhang, P. P.; Yang, S.; Pineda-Gómez, R.; Ibarlucea, B.; Ma, J.; Lohe, M. R.; Akbar, T. F.; Baraban, L.; Cuniberti, G.; Feng, X. L. Electrochemically exfoliated high-quality 2H-MoS₂ for multiflake thin film flexible biosensors. Small 2019, 15, 1901265.

Carey, T.; Cassidy, O.; Synnatschke, K.; Caffrey, E.; Garcia, J.; Liu, S. X.; Kaur, H.; Kelly, A. G.; Munuera, J.; Gabbett, C. et al. High-mobility flexible transistors with low-temperature solution-processed tungsten dichalcogenides. ACS Nano 2023, 17, 2912–2922.

Lu, Z. Y.; Jiang, K.; Chen, G. X.; Wang, H. T.; Cui, Y. Lithium electrochemical tuning for electrocatalysis. Adv. Mater. 2018, 30, 1800978.

Wang, X. F.; Shen, X.; Wang, Z. X.; Yu, R. C.; Chen, L. Q. Atomic-scale clarification of structural transition of MoS₂ upon sodium intercalation. ACS Nano 2014, 8, 11394–11400.

Xiong, F.; Wang, H. T.; Liu, X. G.; Sun, J.; Brongersma, M.; Pop, E.; Cui, Y. Li intercalation in MoS₂: In situ observation of its dynamics and tuning optical and electrical properties. Nano Lett. 2015, 15, 6777–6784.

Azhagurajan, M.; Kajita, T.; Itoh, T.; Kim, Y. G.; Itaya, K. In situ visualization of lithium ion intercalation into MoS₂ single crystals using differential optical microscopy with atomic layer resolution. J. Am. Chem. Soc. 2016, 138, 3355–3361.

Wang, C.; He, Q. Y.; Halim, U.; Liu, Y. Y.; Zhu, E.; Lin, Z. Y.; Xiao, H.; Duan, X. D.; Feng, Z. Y.; Cheng, R. et al. Monolayer atomic crystal molecular superlattices. Nature 2018, 555, 231–236.

He, Q. Y.; Lin, Z. Y.; Ding, M. N.; Yin, A. X.; Halim, U.; Wang, C.; Liu, Y.; Cheng, H. C.; Huang, Y.; Duan, X. F. In situ probing molecular intercalation in two-dimensional layered semiconductors. Nano Lett. 2019, 19, 6819–6826.

Qian, Q.; Ren, H. Y.; Zhou, J. Y.; Wan, Z.; Zhou, J. X.; Yan, X. X.; Cai, J.; Wang, P. Q.; Li, B. L.; Sofer, Z. et al. Chiral molecular intercalation superlattices. Nature 2022, 606, 902–908.

Wells, R. A.; Zhang, M.; Chen, T. H.; Boureau, V.; Caretti, M.; Liu, Y. P.; Yum, J. H.; Johnson, H.; Kinge, S.; Radenovic, A. et al. High performance semiconducting nanosheets via a scalable powder-based electrochemical exfoliation technique. ACS Nano 2022, 16, 5719–5730.

Kuo, L.; Sangwan, V. K.; Rangnekar, S. V.; Chu, T. C.; Lam, D.; Zhu, Z. H.; Richter, L. J.; Li, R. P.; Szydłowska, B. M.; Downing, J. R. et al. All-printed ultrahigh-responsivity MoS₂ nanosheet photodetectors enabled by megasonic exfoliation. Adv. Mater. 2022, 34, 2203772.

Yu, W.; Li, J.; Herng, T. S.; Wang, Z. S.; Zhao, X. X.; Chi, X.; Fu, W.; Abdelwahab, I.; Zhou, J.; Dan, J. D. et al. Chemically exfoliated VSe₂ monolayers with room-temperature ferromagnetism. Adv. Mater. 2019, 31, 1903779.

Liu, N.; Kim, P.; Kim, J. H.; Ye, J. H.; Kim, S.; Lee, C. J. Large-area atomically thin MoS₂ nanosheets prepared using electrochemical exfoliation. ACS Nano 2014, 8, 6902–6910.

You, X. Q.; Liu, N.; Lee, C. J.; Pak, J. J. An electrochemical route to MoS₂ nanosheets for device applications. Mater. Lett. 2014, 121, 31–35.

Zhuang, Z. C.; Wang, F. F.; Naidu, R.; Chen, Z. L. Biosynthesis of Pd-Au alloys on carbon fiber paper: Towards an eco-friendly solution for catalysts fabrication. J. Power Sources 2015, 291, 132–137.

Zhu, H.; Sun, S. H.; Hao, J. C.; Zhuang, Z. C.; Zhang, S. G.; Wang, T. D.; Kang, Q.; Lu, S. L.; Wang, X. F.; Lai, F. L. et al. A high-entropy atomic environment converts inactive to active sites for electrocatalysis. Energy Environ. Sci. 2023, 16, 619–628.

Liu, Z. H.; Du, Y.; Yu, R. H.; Zheng, M. B.; Hu, R.; Wu, J. S.; Xia, Y. Y.; Zhuang, Z. C.; Wang, D. S. Tuning mass transport in electrocatalysis down to sub-5 nm through nanoscale grade separation. Angew. Chem., Int. Ed. 2023, 62, e202212653.

Liu, R. X.; Li, X. L.; Jia, Z. D.; Wang, Y. Y.; Peng, Y. L.; Tang, C. M.; Chen, Z.; Dong, L. Sulfur vacancy-rich MoS₂-catalyzed hydrodeoxygenation of lactic acid to biopropionic acid. ACS Sustainable Chem. Eng. 2022, 10, 5463–5475.

Liu, G. L.; Robertson, A. W.; Li, M. M. J.; Kuo, W. C. H.; Darby, M. T.; Muhieddine, M. H.; Lin, Y. C.; Suenaga, K.; Stamatakis, M.; Warner, J. H. et al. MoS₂ monolayer catalyst doped with isolated Co atoms for the hydrodeoxygenation reaction. Nat. Chem. 2017, 9, 810–816.

Chou, S. S.; Sai, N.; Lu, P.; Coker, E. N.; Liu, S.; Artyushkova, K.; Luk, T. S.; Kaehr, B.; Brinker, C. J. Understanding catalysis in a multiphasic two-dimensional transition metal dichalcogenide. Nat. Commun. 2015, 6, 8311.

Chen, Z. X.; Leng, K.; Zhao, X. X.; Malkhandi, S.; Tang, W.; Tian, B. B.; Dong, L.; Zheng, L. R.; Lin, M.; Yeo, B. S. et al. Interface confined hydrogen evolution reaction in zero valent metal nanoparticles-intercalated molybdenum disulfide. Nat. Commun. 2017, 8, 14548.

Jaramillo, T. F.; Jørgensen, K. P.; Bonde, J.; Nielsen, J. H.; Horch, S.; Chorkendorff, I. Identification of active edge sites for electrochemical H₂ evolution from MoS₂ nanocatalysts. Science 2007, 317, 100–102.

Hinnemann, B.; Moses, P. G.; Bonde, J.; Jørgensen, K. P.; Nielsen, J. H.; Horch, S.; Chorkendorff, I.; Nørskov, J. K. Biomimetic hydrogen evolution: MoS₂ nanoparticles as catalyst for hydrogen evolution. J. Am. Chem. Soc. 2005, 127, 5308–5309.

Li, Y. G.; Wang, H. L.; Xie, L. M.; Liang, Y. Y.; Hong, G. S.; Dai, H. J. MoS₂ nanoparticles grown on graphene: An advanced catalyst for the hydrogen evolution reaction. J. Am. Chem. Soc. 2011, 133, 7296–7299.

Chang, K.; Mei, Z. W.; Wang, T.; Kang, Q.; Ouyang, S. X.; Ye, J. H. MoS₂/graphene cocatalyst for efficient photocatalytic H₂ evolution under visible light irradiation. ACS Nano 2014, 8, 7078–7087.

Zhuang, Z. C.; Li, Y.; Huang, J. Z.; Li, Z. L.; Zhao, K. N.; Zhao, Y. L.; Xu, L.; Zhou, L.; Moskaleva, L. V.; Mai, L. Q. Sisyphus effects in hydrogen electrochemistry on metal silicides enabled by silicene subunit edge. Sci. Bull. 2019, 64, 617–624.

Ye, G. L.; Gong, Y. J.; Lin, J. H.; Li, B.; He, Y. M.; Pantelides, S. T.; Zhou, W.; Vajtai, R.; Ajayan, P. M. Defects engineered monolayer MoS₂ for improved hydrogen evolution reaction. Nano Lett. 2016, 16, 1097–1103.

Li, H.; Tsai, C.; Koh, A. L.; Cai, L. L.; Contryman, A. W.; Fragapane, A. H.; Zhao, J. H.; Han, H. S.; Manoharan, H. C.; Abild-Pedersen, F. et al. Activating and optimizing MoS₂ basal planes for hydrogen evolution through the formation of strained sulphur vacancies. Nat. Mater. 2016, 15, 48–53.

Voiry, D.; Fullon, R.; Yang, J.; de Carvalho Castro e Silva, C.; Kappera, R.; Bozkurt, I.; Kaplan, D.; Lagos, M. J.; Batson, P. E.; Gupta, G. et al. The role of electronic coupling between substrate and 2D MoS₂ nanosheets in electrocatalytic production of hydrogen. Nat. Mater. 2016, 15, 1003–1009.

Tsai, C.; Li, H.; Park, S.; Park, J.; Han, H. S.; Nørskov, J. K.; Zheng, X. L.; Abild-Pedersen, F. Electrochemical generation of sulfur vacancies in the basal plane of MoS₂ for hydrogen evolution. Nat. Commun. 2017, 8, 15113.

Chou, S. S.; De, M.; Kim, J.; Byun, S.; Dykstra, C.; Yu, J.; Huang, J. X.; Dravid, V. P. Ligand conjugation of chemically exfoliated MoS₂. J. Am. Chem. Soc. 2013, 135, 4584–4587.

Yu, Z. H.; Pan, Y. M.; Shen, Y. T.; Wang, Z. L.; Ong, Z. Y.; Xu, T.; Xin, R.; Pan, L. J.; Wang, B. G.; Sun, L. T. et al. Towards intrinsic charge transport in monolayer molybdenum disulfide by defect and interface engineering. Nat. Commun. 2014, 5, 5290.

Zhuang, Z. C.; Li, Y. H.; Yu, R. H.; Xia, L. X.; Yang, J. R.; Lang, Z. Q.; Zhu, J. X.; Huang, J. Z.; Wang, J. O.; Wang, Y. et al. Reversely trapping atoms from a perovskite surface for high-performance and durable fuel cell cathodes. Nat. Catal. 2022, 5, 300–310.

Jin, C. Y.; Fan, S. J.; Zhuang, Z. C.; Zhou, Y. S. Single-atom nanozymes: From bench to bedside. Nano Res. 2023, 16, 1992–2002.

Zhuang, Z. C.; Li, Y.; Li, Y. H.; Huang, J. Z.; Wei, B.; Sun, R.; Ren, Y. J.; Ding, J.; Zhu, J. X.; Lang, Z. Q. et al. Atomically dispersed nonmagnetic electron traps improve oxygen reduction activity of perovskite oxides. Energy Environ. Sci. 2021, 14, 1016–1028.

Zhuang, Z. C.; Xia, L. X.; Huang, J. Z.; Zhu, P.; Li, Y.; Ye, C. L.; Xia, M. G.; Yu, R. H.; Lang, Z. Q.; Zhu, J. X. et al. Continuous modulation of electrocatalytic oxygen reduction activities of single-atom catalysts through p-n junction rectification. Angew. Chem., Int. Ed. 2023, 62, e202212335.

Fang, H.; Tosun, M.; Seol, G.; Chang, T. C.; Takei, K.; Guo, J.; Javey, A. Degenerate n-doping of few-layer transition metal dichalcogenides by potassium. Nano Lett. 2013, 13, 1991–1995.

Tsai, C.; Chan, K.; Nørskov, J. K.; Abild-Pedersen, F. Theoretical insights into the hydrogen evolution activity of layered transition metal dichalcogenides. Surf. Sci. 2015, 640, 133–140.

Voiry, D.; Salehi, M.; Silva, R.; Fujita, T.; Chen, M. W.; Asefa, T.; Shenoy, V. B.; Eda, G.; Chhowalla, M. Conducting MoS₂ nanosheets as catalysts for hydrogen evolution reaction. Nano Lett. 2013, 13, 6222–6227.

Sun, Z. M.; Lin, L.; Yuan, M. W.; Yao, H. Y.; Deng, Y. J.; Huang, B. B.; Li, H. F.; Sun, G. B.; Zhu, J. Mott-Schottky heterostructure induce the interfacial electron redistribution of MoS₂ for boosting pH-universal hydrogen evolution with Pt-like activity. Nano Energy 2022, 101, 107563.

Li, S. D.; Zhuang, Z. C.; Xia, L. X.; Zhu, J. X.; Liu, Z. A.; He, R. H.; Luo, W.; Huang, W. Z.; Shi, C. W.; Zhao, Y. et al. Improving the electrophilicity of nitrogen on nitrogen-doped carbon triggers oxygen reduction by introducing covalent vanadium nitride. Sci. China Mater. 2023, 66, 160–168.

Wu, L. F.; Dzade, N. Y.; Yu, M.; Mezari, B.; van Hoof, A. J. F.; Friedrich, H.; de Leeuw, N. H.; Hensen, E. J. M.; Hofmann, J. P. Unraveling the role of lithium in enhancing the hydrogen evolution activity of MoS₂: Intercalation versus adsorption. ACS Energy Lett. 2019, 4, 1733–1740.

Attanayake, N. H.; Thenuwara, A. C.; Patra, A.; Aulin, Y. V.; Tran, T. M.; Chakraborty, H.; Borguet, E.; Klein, M. L.; Perdew, J. P.; Strongin, D. R. Effect of intercalated metals on the electrocatalytic activity of 1T-MoS₂ for the hydrogen evolution reaction. ACS Energy Lett. 2018, 3, 7–13.

Luo, Y. T.; Li, X.; Cai, X. K.; Zou, X. L.; Kang, F. Y.; Cheng, H. M.; Liu, B. L. Two-dimensional MoS₂ confined Co(OH)₂ electrocatalysts for hydrogen evolution in alkaline electrolytes. ACS Nano 2018, 12, 4565–4573.

Liu, Z. H.; Du, Y.; Zhang, P. F.; Zhuang, Z. C.; Wang, D. S. Bringing catalytic order out of chaos with nitrogen-doped ordered mesoporous carbon. Matter 2021, 4, 3161–3194.

Gogotsi, Y.; Simon, P. True performance metrics in electrochemical energy storage. Science 2011, 334, 917–918.

Lin, T. Q.; Chen, I. W.; Liu, F. X.; Yang, C. Y.; Bi, H.; Xu, F. F.; Huang, F. Q. Nitrogen-doped mesoporous carbon of extraordinary capacitance for electrochemical energy storage. Science 2015, 350, 1508–1513.

Simon, P.; Gogotsi, Y. Perspectives for electrochemical capacitors and related devices. Nat. Mater. 2020, 19, 1151–1163.

Yun, Q. B.; Li, L. X.; Hu, Z. N.; Lu, Q. P.; Chen, B.; Zhang, H. Layered transition metal dichalcogenide-based nanomaterials for electrochemical energy storage. Adv. Mater. 2020, 32, 1903826.

Huang, C. C.; Liu, Y. W.; Zheng, R. T.; Yang, Z. W.; Miao, Z. H.; Zhang, J. W.; Cai, X. H.; Yu, H. X.; Zhang, L. Y.; Shu, J. Interlayer gap widened TiS₂ for highly efficient sodium-ion storage. J. Mater. Sci. Technol. 2022, 107, 64–69.

Chen, W. S.; Gu, J. J.; Liu, Q. L.; Yang, M. Z.; Zhan, C.; Zang, X. N.; Pham, T. A.; Liu, G. X.; Zhang, W.; Zhang, D. et al. Two-dimensional quantum-sheet films with sub-1.2 nm channels for ultrahigh-rate electrochemical capacitance. Nat. Nanotechnol. 2022, 17, 153–158.

Shuai, H. L.; Li, J. Y.; Jiang, F.; Zhang, X. N.; Xu, L. Q.; Hu, J. G.; Hou, H. S.; Zou, G. Q.; Sun, W.; Duan, H. G. et al. Electrochemically intercalated intermediate induced exfoliation of few-layer MoS₂ from molybdenite for long-life sodium storage. Sci. China Mater. 2021, 64, 115–127.

Li, Z. N.; Sami, I.; Yang, J.; Li, J. T.; Kumar, R. V.; Chhowalla, M. Lithiated metallic molybdenum disulfide nanosheets for high-performance lithium-sulfur batteries. Nature Energy 2023, 8, 84–93.

Inta, H. R.; Biswas, T.; Ghosh, S.; Kumar, R.; Jana, S. K.; Mahalingam, V. Ionic liquid-intercalated metallic MoS₂ as a superior electrode for energy storage applications. ChemNanoMat 2020, 6, 685–695.

Yao, Z. Y.; Zhang, W.; Ren, X. C.; Yin, Y. R.; Zhao, Y. X.; Ren, Z. G.; Sun, Y. H.; Lei, Q.; Wang, J.; Wang, L. H. et al. A volume self-regulation MoS₂ superstructure cathode for stable and high mass-loaded Zn-ion storage. ACS Nano 2022, 16, 12095–12106.

Wang, L.; Zhang, X.; Xu, Y. N.; Li, C.; Liu, W. J.; Yi, S.; Wang, K.; Sun, X. Z.; Wu, Z. S.; Ma, Y. W. Tetrabutylammonium-intercalated 1T-MoS₂ nanosheets with expanded interlayer spacing vertically coupled on 2D delaminated MXene for high-performance lithium-ion capacitors. Adv. Funct. Mater. 2021, 31, 2104286.

Du, G. D.; Guo, Z. P.; Wang, S. Q.; Zeng, R.; Chen, Z. X.; Liu, H. K. Superior stability and high capacity of restacked molybdenum disulfide as anode material for lithium ion batteries. Chem. Commun. 2010, 46, 1106–1108.

Yoo, H. D.; Li, Y. F.; Liang, Y. L.; Lan, Y. C.; Wang, F.; Yao, Y. Intercalation pseudocapacitance of exfoliated molybdenum disulfide for ultrafast energy storage. ChemNanoMat 2016, 2, 688–691.

Li, S. W.; Huang, C.; Gao, L.; Shen, Q. Y.; Li, P.; Qu, X. H.; Jiao, L. F.; Liu, Y. C. Unveiling the “proton lubricant” chemistry in aqueous zinc-MoS₂ batteries. Angew. Chem., Int. Ed. 2022, 61, e202211478.

Cheng, C.; Iyengar, S. A.; Karnik, R. Molecular size-dependent subcontinuum solvent permeation and ultrafast nanofiltration across nanoporous graphene membranes. Nat. Nanotechnol. 2021, 16, 989–995.

Chen, L.; Shi, G. S.; Shen, J.; Peng, B. Q.; Zhang, B. W.; Wang, Y. Z.; Bian, F. G.; Wang, J. J.; Li, D. Y.; Qian, Z. et al. Ion sieving in graphene oxide membranes via cationic control of interlayer spacing. Nature 2017, 550, 380–383.

Yeh, C. N.; Raidongia, K.; Shao, J. J.; Yang, Q. H.; Huang, J. X. On the origin of the stability of graphene oxide membranes in water. Nat. Chem. 2015, 7, 166–170.

Heiranian, M.; Farimani, A. B.; Aluru, N. R. Water desalination with a single-layer MoS₂ nanopore. Nat. Commun. 2015, 6, 8616.

Hirunpinyopas, W.; Prestat, E.; Worrall, S. D.; Haigh, S. J.; Dryfe, R. A. W.; Bissett, M. A. Desalination and nanofiltration through functionalized laminar MoS₂ membranes. ACS Nano 2017, 11, 11082–11090.

Wang, Z. Y.; Tu, Q. S.; Zheng, S. X.; Urban, J. J.; Li, S. F.; Mi, B. X. Understanding the aqueous stability and filtration capability of MoS₂ membranes. Nano Lett. 2017, 17, 7289–7298.

Sun, L. W.; Huang, H. B.; Peng, X. S. Laminar MoS₂ membranes for molecule separation. Chem. Commun. 2013, 49, 10718–10720.

Deng, M. M.; Kwac, K.; Li, M.; Jung, Y.; Park, H. G. Stability, molecular sieving, and ion diffusion selectivity of a lamellar membrane from two-dimensional molybdenum disulfide. Nano Lett. 2017, 17, 2342–2348.

Mei, L.; Cao, Z. L.; Ying, T.; Yang, R. J.; Peng, H. R.; Wang, G.; Zheng, L.; Chen, Y.; Tang, C. Y.; Voiry, D. et al. Simultaneous electrochemical exfoliation and covalent functionalization of MoS₂ membrane for ion sieving. Adv. Mater. 2022, 34, 2201416.

Wang, W. S.; Onofrio, N.; Petit, E.; Karamoko, B. A.; Wu, H. L.; Liu, J. F.; Li, J.; Qi, K.; Zhang, Y.; Gervais, C. et al. High-surface-area functionalized nanolaminated membranes for energy-efficient nanofiltration and desalination in forward osmosis. Nat. Water 2023, 1, 187–197.

Hoenig, E.; Strong, S. E.; Wang, M. Z.; Radhakrishnan, J. M.; Zaluzec, N. J.; Skinner, J. L.; Liu, C. Controlling the structure of MoS₂ membranes via covalent functionalization with molecular spacers. Nano Lett. 2020, 20, 7844–7851.

Das, S.; Sebastian, A.; Pop, E.; McClellan, C. J.; Franklin, A. D.; Grasser, T.; Knobloch, T.; Illarionov, Y.; Penumatcha, A. V.; Appenzeller, J. et al. Transistors based on two-dimensional materials for future integrated circuits. Nat. Electron. 2021, 4, 786–799.

Luo, Z. Z.; Peng, B. Y.; Zeng, J. P.; Yu, Z. H.; Zhao, Y.; Xie, J.; Lan, R. F.; Ma, Z.; Pan, L. J.; Cao, K. et al. Sub-thermionic, ultra-high-gain organic transistors and circuits. Nat. Commun. 2021, 12, 1928.

Radisavljevic, B.; Radenovic, A.; Brivio, J.; Giacometti, V.; Kis, A. Single-layer MoS₂ transistors. Nat. Nanotechnol. 2011, 6, 147–150.

Luo, Z. Z.; Song, X. X.; Liu, X. L.; Lu, X. Q.; Yao, Y.; Zeng, J. P.; Li, Y. T.; He, D. W.; Zhao, H. J.; Gao, L. et al. Revealing the key role of molecular packing on interface spin polarization at two-dimensional limit in spintronic devices. Sci. Adv. 2023, 9, eade9126.

Zhuo, F. L.; Wu, J.; Li, B. H.; Li, M. Y.; Tan, C. L.; Luo, Z. Z.; Sun, H. B.; Xu, Y.; Yu, Z. H. Modifying the power and performance of 2-dimensional MoS₂ field effect transistors. Research 2023, 6, 0057.

Song, O.; Rhee, D.; Kim, J.; Jeon, Y.; Mazánek, V.; Söll, A.; Kwon, Y. A.; Cho, J. H.; Kim, Y. H.; Sofer, Z. et al. All inkjet-printed electronics based on electrochemically exfoliated two-dimensional metal, semiconductor, and dielectric. npj 2D Mater. Appl. 2022, 6, 64.

Diao, M. J.; Li, H.; Gao, X. Y.; Hou, R. P.; Cheng, Q.; Yu, Z. Y.; Huang, Z. P.; Zhang, C. Giant nonlinear optical absorption of ion-intercalated tin disulfide associated with abundant in-gap defects. Adv. Funct. Mater. 2021, 31, 2106930.

Yu, Y. J.; Yang, F. Y.; Lu, X. F.; Yan, Y. J.; Cho, Y. H.; Ma, L. G.; Niu, X. H.; Kim, S.; Son, Y. W.; Feng, D. L. et al. Gate-tunable phase transitions in thin flakes of 1T-TaS₂. Nat. Nanotechnol. 2015, 10, 270–276.

Kelly, A. G.; O’Suilleabhain, D.; Gabbett, C.; Coleman, J. N. The electrical conductivity of solution-processed nanosheet networks. Nat. Rev. Mater. 2022, 7, 217–234.

Wang, S. Z.; Yang, X.; Hou, L. X.; Cui, X. P.; Zheng, X. H.; Zheng, J. Organic covalent modification to improve thermoelectric properties of TaS₂. Nat. Commun. 2022, 13, 4401.

Wan, C. L.; Gu, X. K.; Dang, F.; Itoh, T.; Wang, Y. F.; Sasaki, H.; Kondo, M.; Koga, K.; Yabuki, K.; Snyder, G. J. et al. Flexible n-type thermoelectric materials by organic intercalation of layered transition metal dichalcogenide TiS₂. Nat. Mater. 2015, 14, 622–627.

Wan, C. L.; Tian, R. M.; Kondou, M.; Yang, R. G.; Zong, P. A.; Koumoto, K. Ultrahigh thermoelectric power factor in flexible hybrid inorganic-organic superlattice. Nat. Commun. 2017, 8, 1024.

Li, J.; Song, P.; Zhao, J. P.; Vaklinova, K.; Zhao, X. X.; Li, Z. J.; Qiu, Z. Z.; Wang, Z. H.; Lin, L.; Zhao, M. et al. Printable two-dimensional superconducting monolayers. Nat. Mater. 2021, 20, 181–187.

Zhang, H. X.; Rousuli, A.; Zhang, K. N.; Luo, L. P.; Guo, C. G.; Cong, X.; Lin, Z. Z.; Bao, C. H.; Zhang, H. Y.; Xu, S. N. et al. Tailored Ising superconductivity in intercalated bulk NbSe₂. Nat. Phys. 2022, 18, 1425–1430.

Fatemi, V.; Wu, S. F.; Cao, Y.; Bretheau, L.; Gibson, Q. D.; Watanabe, K.; Taniguchi, T.; Cava, R. J.; Jarillo-Herrero, P. Electrically tunable low-density superconductivity in a monolayer topological insulator. Science 2018, 362, 926–929.

Sajadi, E.; Palomaki, T.; Fei, Z. Y.; Zhao, W. J.; Bement, P.; Olsen, C.; Luescher, S.; Xu, X. D.; Folk, J. A.; Cobden, D. H. Gate-induced superconductivity in a monolayer topological insulator. Science 2018, 362, 922–925.

Qian, Q.; Wan, Z.; Duan, X. F. Boosting superconductivity in organic-inorganic superlattices. Sci. Bull. 2020, 65, 177–178.

Zhang, H. X.; Rousuli, A.; Shen, S. C.; Zhang, K. N.; Wang, C.; Luo, L. P.; Wang, J. Z.; Wu, Y.; Xu, Y.; Duan, W. H. et al. Enhancement of superconductivity in organic-inorganic hybrid topological materials. Sci. Bull. 2020, 65, 188–193.

Rousuli, A.; Zhang, H. X.; Zhang, K. N.; Zhong, H. Y.; Feng, R. F.; Wu, Y.; Yu, P.; Zhou, S. Y. Induced anisotropic superconductivity in ionic liquid cation intercalated 1T-SnSe₂. 2D Mater. 2021, 8, 015024.

Mounet, N.; Gibertini, M.; Schwaller, P.; Campi, D.; Merkys, A.; Marrazzo, A.; Sohier, T.; Castelli, I. E.; Cepellotti, A.; Pizzi, G. et al. Two-dimensional materials from high-throughput computational exfoliation of experimentally known compounds. Nat. Nanotechnol. 2018, 13, 246–252.

Wu, J. J.; Peng, J.; Sun, H. F.; Guo, Y. Q.; Liu, H. F.; Wu, C. Z.; Xie, Y. Host–guest intercalation chemistry for the synthesis and modification of two-dimensional transition metal dichalcogenides. Adv. Mater. 2022, 34, 2200425.

Choi, S. H.; Yun, S. J.; Won, Y. S.; Oh, C. S.; Kim, S. M.; Kim, K. K.; Lee, Y. H. Large-scale synthesis of graphene and other 2D materials towards industrialization. Nat. Commun. 2022, 13, 1484.

Ding, Y. J.; Chen, Y. P.; Zhang, X. L.; Chen, L.; Dong, Z. H.; Jiang, H. L.; Xu, H. X.; Zhou, H. C. Controlled intercalation and chemical exfoliation of layered metal-organic frameworks using a chemically labile intercalating agent. J. Am. Chem. Soc. 2017, 139, 9136–9139.

Bediako, D. K.; Rezaee, M.; Yoo, H.; Larson, D. T.; Zhao, S. Y. F.; Taniguchi, T.; Watanabe, K.; Brower-Thomas, T. L.; Kaxiras, E.; Kim, P. Heterointerface effects in the electrointercalation of van der Waals heterostructures. Nature 2018, 558, 425–429.

Majed, A.; Kothakonda, M.; Wang, F.; Tseng, E. N.; Prenger, K.; Zhang, X. D.; Persson, P. O. Å.; Wei, J.; Sun, J. W.; Naguib, M. Transition metal carbo-chalcogenide “TMCC: ” A new family of 2D materials. Adv. Mater. 2022, 34, 2200574.