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Nano Research 2023, 16(5): 6402-6443 https://doi.org/10.1007/s12274-023-5428-6
Review Article | Issue | Published: 21 March 2023

A comprehensive review on semiconductor-based photocatalysts toward the degradation of persistent pesticides

Show Author's Information Jing Zhu1,§,  Min Liao1,§,  Chen Zhao1,§,  Mengmeng Liu1,  Ali Han2( ),  Chunna Zhu1,  Yujia Sun1,  Meng Zhao1,  Sheng Ye1( ),  Haiqun Cao1( )
College of Science & School of Plant Protection, Anhui Province Engineering Laboratory for Green Pesticide Development and Application, and Anhui Province Key Laboratory of Crop Integrated Pest Management, Anhui Agricultural University, Hefei 230036, China
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China

§ Jing Zhu, Min Liao, and Chen Zhao contributed equally to this work.

Keywords:
photocatalysis, degradation, semiconductor, pesticide
Topics:
Photocatalysis
Cite this article:
Zhu J, Liao M, Zhao C, et al. A comprehensive review on semiconductor-based photocatalysts toward the degradation of persistent pesticides. Nano Research, 2023, 16(5): 6402-6443. https://doi.org/10.1007/s12274-023-5428-6
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Abstract Full text About this article

Pesticides refer to the chemicals to regulate plant growth and control pests used in agriculture. However, the extensive use of pesticides causes serious pollution that threatens the ecological environment and human health. Photocatalytic degradation of pesticides has become a promising way to deal with pesticide pollution. In this review, pesticides are classified according to the different targets and chemical structures. The recent developments on semiconductor-based photocatalysts including metal oxides, metal oxyhalides, carbon nitrides, and metal sulfides were reviewed for degradation of pesticides. Importantly, several modification strategies to improve the photocatalytic performance are described such as doping, heterojunction construction, and defect engineering, with special emphasis on anchoring single atom catalyst. Moreover, extensive efforts should be made to in-depth understand the photodegradation mechanism by monitoring key intermediates. Our perspectives on the key challenges and future directions of developing high-performance semiconductor-based photocatalysts for pesticide degradation are elaborated.


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About this article

A comprehensive review on semiconductor-based photocatalysts toward the degradation of persistent pesticides

Show Author's information Jing Zhu1,§, Min Liao1,§, Chen Zhao1,§, Mengmeng Liu1, Ali Han2( ), Chunna Zhu1, Yujia Sun1, Meng Zhao1, Sheng Ye1( ), Haiqun Cao1( )
College of Science & School of Plant Protection, Anhui Province Engineering Laboratory for Green Pesticide Development and Application, and Anhui Province Key Laboratory of Crop Integrated Pest Management, Anhui Agricultural University, Hefei 230036, China
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China

§ Jing Zhu, Min Liao, and Chen Zhao contributed equally to this work.

Abstract

Pesticides refer to the chemicals to regulate plant growth and control pests used in agriculture. However, the extensive use of pesticides causes serious pollution that threatens the ecological environment and human health. Photocatalytic degradation of pesticides has become a promising way to deal with pesticide pollution. In this review, pesticides are classified according to the different targets and chemical structures. The recent developments on semiconductor-based photocatalysts including metal oxides, metal oxyhalides, carbon nitrides, and metal sulfides were reviewed for degradation of pesticides. Importantly, several modification strategies to improve the photocatalytic performance are described such as doping, heterojunction construction, and defect engineering, with special emphasis on anchoring single atom catalyst. Moreover, extensive efforts should be made to in-depth understand the photodegradation mechanism by monitoring key intermediates. Our perspectives on the key challenges and future directions of developing high-performance semiconductor-based photocatalysts for pesticide degradation are elaborated.

Keywords: photocatalysis, degradation, semiconductor, pesticide

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Publication history
Copyright
Acknowledgements

Publication history

Received: 01 November 2022
Revised: 15 December 2022
Accepted: 17 December 2022
Published: 21 March 2023
Issue date: May 2023

Copyright

© Tsinghua University Press 2023

Acknowledgements

Acknowledgements

This work was financially supported by the National Natural Science Foundation of China (Nos. 21902157 and 51702004), Starting Fund for Scientific Research of High-Level Talents, Anhui Agricultural University (No. rc382108), the Open Fund of the State Key Laboratory of Catalysis in Dalian Institute of Chemical Physics, Chinese Academy of Sciences (DICP, CAS) (No. N-21-12), the Open Fund of the State Key Laboratory of Molecular Reaction Dynamics in DICP, CAS (No. SKLMRD-K202223), Key Research and Development Plan of Anhui Province (No. 2022e07020037), Health Research Project of Anhui Province (No. AHWJ2022b014), Shen-Nong Scholar Program of Anhui Agricultural University (No. rc382101), and Innovation and Entrepreneurship Plan for College Students (Nos. X202210364252, X202210364274, and X202210364532).

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